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61. 发明公开

KR1020130008033A 지지된 가스 분리 멤브레인을 형성하는 방법 및 장치 无效
标题翻译：用于形成支持气体分离膜的方法和装置
公开(公告)号：KR1020130008033A
公开(公告)日：2013-01-21
申请号：KR1020127025066
申请日：2011-03-24
申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
发明人： 사우카이티스존찰스
IPC分类号： B01D53/22 , B01D69/12 , B01D71/02 , B01D67/00
CPC分类号： C23C18/18 , B01D53/228 , B01D67/0055 , B01D69/105 , B01D71/022 , B01D2323/42 , B01D2325/06 , C01B3/503 , C01B3/505 , C23C18/1644 , C23C18/1648 , C23C18/1692 , C23C18/1806 , C23C18/1855 , C23C18/31 , C25D5/10 , Y10T156/10 , Y10T156/17
摘要： 본 발명에 따르면, 금속 멤브레인 층을 그 상에 피착한 다공성 지지체 재료(12)를 제공하는 단계 그리고 후속 금속 멤브레인 층의 배치를 향상시키는 표면 활성화를 제공하는 일부 표면 특성을 그 특정한 패턴(40)으로 표면(16) 상에 도입하는 단계에 의해 가스 분리 멤브레인 시스템을 제조하는 특정한 패턴(40)으로의 방법이 제공된다. 가스 분리 멤브레인 시스템은 수소-함유 가스 스트림으로부터의 수소의 분리에서 유용하다.

62. 发明授权

KR101166911B1 향상된 선택도를 갖는 수소 분리막 제조방법 및 그 방법으로 제조된 수소분리막 有权
标题翻译：生产具有改进选择性的氢分离膜和生产氢分离膜的方法
公开(公告)号：KR101166911B1
公开(公告)日：2012-07-19
申请号：KR1020110014555
申请日：2011-02-18
申请人： 한국에너지기술연구원
发明人： 박종수 , 이신근 , 황경란 , 김동국 , 김태환 , 이춘부 , 이성욱
IPC分类号： B01D69/10 , B01D69/12 , B01D71/02
CPC分类号： C01B3/505 , B01D69/02 , B01D69/10 , B01D71/022 , B01D2325/02
摘要： PURPOSE: A method for manufacturing a hydrogen separating membrane and the hydrogen separating membrane manufactured by the same are provided to both keep hydrogen permeation and improve selectivity. CONSTITUTION: A method for manufacturing a hydrogen separating membrane includes the following: a metal separating membrane is formed on a porous support based on palladium or palladium alloy; and the metal separating membrane on the porous support is polished. The polishing process is a slurry-based polishing process or a lapping film-based polishing process. A plasma-based surface treating process is implemented with respect to the porous support before the formation of the metal separating membrane.
摘要翻译：目的：提供一种氢分离膜的制造方法和由其制造的氢分离膜，以保持氢气渗透并提高选择性。构成：氢分离膜的制造方法包括以下：金属分离膜基于钯或钯合金形成在多孔载体上; 抛光多孔载体上的金属分离膜。抛光工艺是基于浆料的抛光工艺或研磨膜基抛光工艺。在形成金属分离膜之前，相对于多孔载体实施等离子体表面处理工艺。

63. 发明公开

KR20120060652A Cermet membrane for separating hydrogen gas and preparation method thereof 审中-公开
标题翻译：用于分离氢气的CERMET膜及其制备方法
公开(公告)号：KR20120060652A
公开(公告)日：2012-06-12
申请号：KR20100122260
申请日：2010-12-02
申请人： UNIV KOREA NAT TRANSP IND ACAD COOP FOUND
发明人： KIM KYEONG IL , YOO SUNG WOONG , KIM WHAN GI , UR SOON CHUL , HONG TAE WHAN
IPC分类号： B01D71/00 , C01B3/50
CPC分类号： C01B3/505 , B01D69/12 , B01D71/022
摘要： PURPOSE: A complex separating membrane for separating hydrogen gas and a method for manufacturing the same are provided to compensate the brittleness of a separating membrane and to improve hydrogen permeating characteristic. CONSTITUTION: A complex separating membrane for separating hydrogen gas is based on TiN and metals. The metals are cobalt or nickel. A method for manufacturing the complex separating membrane includes the following: TiN powder and metal powder are mixed to obtained mixed powder; the mixed powder is milled using a high energy milling unit; the milled powder is pre-molded in the form of a disk based on a cold isostatic pressing operation; the pre-molded product undergoes a hot isostatic pressing operation to obtain the complex separating membrane; and the surface of the complex separating membrane is treated to adjust the thickness of the complex separating membrane.
摘要翻译：目的：提供用于分离氢气的复合分离膜及其制造方法，以补偿分离膜的脆性并改善氢渗透特性。构成：用于分离氢气的复合分离膜是基于TiN和金属。金属是钴或镍。复合分离膜的制造方法包括：将TiN粉末和金属粉末混合，得到混合粉末; 使用高能量研磨单元研磨混合粉末; 基于冷等静压操作将研磨的粉末以盘的形式预成型; 预成型产品进行热等静压加压操作以获得复合分离膜; 处理复合分离膜的表面以调节复合分离膜的厚度。

64. 发明公开

KR1020120020334A 필터가 내장된 막 반응기 有权
标题翻译：膜内反应器安装内置过滤器
公开(公告)号：KR1020120020334A
公开(公告)日：2012-03-08
申请号：KR1020100083898
申请日：2010-08-30
申请人： 연세대학교 산학협력단
发明人： 이창하 , 한윤진
IPC分类号： C01B3/58 , C01B3/16 , B01J8/02
CPC分类号： C01B3/58 , C01B3/505 , C01B2203/0227
摘要： PURPOSE: A membrane reactor equipped with a filter is provided to reduce the contact of large molecular materials with the filter by generating resistance to the large molecular materials. CONSTITUTION: A membrane reactor equipped with a filter includes a membrane(2) and a filter(3). The filter is separately installed in the membrane. A catalyst(4) is carried in the filter. A gap between the filter and the membrane is in a range between 0.5 and 30mm. Voids of 0.5 to 100um are arranged in the filter. The filter includes a source gas inlet and a source gas outlet(6). The source gas inlet is installed at one inner side of the filter. The source gas outlet is installed at another inner side of the filter.
摘要翻译：目的：提供一种装有过滤器的膜反应器，以通过产生对大分子材料的耐受性来减少大分子材料与过滤器的接触。构成：装有过滤器的膜反应器包括膜（2）和过滤器（3）。过滤器分别安装在膜中。催化剂（4）携带在过滤器中。过滤器和膜之间的间隙在0.5和30mm之间的范围内。在过滤器中排列0.5至100um的空隙。该过滤器包括源气体入口和源气体出口（6）。源气体入口安装在过滤器的一个内侧。源气体出口安装在过滤器的另一内侧。

65. 发明公开

KR1020110014463A 이중층 분리막을 이용한 탈수소화반응을 통한 탄화수소계 가스 제조 시스템 有权
标题翻译：通过使用双层膜进行脱氢的烃油生产系统
公开(公告)号：KR1020110014463A
公开(公告)日：2011-02-11
申请号：KR1020090072144
申请日：2009-08-05
申请人： 전남대학교산학협력단
发明人： 송선주 , 김재국 , 이종숙 , 문종하
IPC分类号： B01D53/22 , C10L3/06
CPC分类号： C01B3/505 , B01D53/228 , B01D69/12 , B01D71/022
摘要： PURPOSE: A hydrocarbon gas producing system using a dehydrogenation reaction with a bi-layer separation film is provided to obtain a system capable of producing ethylene from ethane. CONSTITUTION: A hydrocarbon gas producing system comprises the following: a bi-layer separation film(110); an oxygen supplier supplying oxygen(122) on one surface of the bi-layer separation film; a steam collector collecting steam(124) from the bi-layer separation film; a first hydrocarbon gas supplier supplying first hydrocarbon gas(132) to the other surface(114) of the bi-layer separation film; and a second hydrocarbon gas collector collecting second hydrocarbon gas(134) from the bi-layer separation film.
摘要翻译：目的：提供一种使用与双层分离膜进行脱氢反应的烃气体生产系统，以获得能够从乙烷生产乙烯的体系。构成：碳氢化合物气体生成系统包括：双层分离膜（110）; 在双层分离膜的一个表面上供氧（122）的供氧供应商; 从双层分离膜收集蒸汽（124）的蒸汽收集器; 将第一烃气体（132）供应到双层分离膜的另一个表面（114）的第一烃气供应器; 和从双层分离膜收集第二烃气体（134）的第二烃类气体收集器。

66. 发明公开

KR1020100049297A 수소 정제 모듈 失效
标题翻译：氢气净化模块
公开(公告)号：KR1020100049297A
公开(公告)日：2010-05-12
申请号：KR1020080108401
申请日：2008-11-03
申请人： 인베니아 주식회사
发明人： 김정호
IPC分类号： C01B3/00 , C01B3/50
CPC分类号： Y02E60/324 , C01B3/503 , C01B3/505 , C01B2203/0405
摘要： PURPOSE: A hydrogen purification module is provided to uniformly disperse pressure applied to a hydrogen separation membrane, and to prevent deformation of the hydrogen separation membrane such as bending etc. CONSTITUTION: A hydrogen purification module includes the following: a housing(100) offering a first inner space blocked from the outside; an inflow line(102) supplying mixed gas to the first inner space, and is connected to the housing; a separation membrane(110) having a second inner space, which is filled with hydrogen; and an exhaust line(118) discharging the penetrated hydrogen to the outside, and is connected to the separation membrane. The hydrogen purification module includes a connection part(116) connected to the exhaust line.
摘要翻译：目的：提供氢气净化模块，以均匀分散施加到氢分离膜上的压力，并防止氢分离膜的变形，如弯曲等。构成：氢气净化模块包括以下：一个壳体（100）第一个内部空间从外面阻挡; 将混合气体供给到所述第一内部空间并且连接到所述壳体的流入管线（102）具有填充有氢的第二内部空间的分离膜（110）; 以及排出管线（118），将穿透的氢气排出到外部，并连接到分离膜。氢气净化模块包括连接到排气管线的连接部分（116）。

67. 发明公开

KR1020090118940A 마이크로파 보조 촉매 상 메탄 플라즈마 분해를 이용한 수소 농후 연료의 제조 방법 및 시스템 无效
标题翻译：使用微波辅助甲烷等离子体分解在催化剂上生产氢化物燃料的方法和系统
公开(公告)号：KR1020090118940A
公开(公告)日：2009-11-18
申请号：KR1020097017643
申请日：2008-01-13
申请人： 에덴 이노베이션즈 리미티드 , 더 유니버서티 어브 퀸슬랜드
发明人： 주,종후아,존 , 첸,지우링 , 루,가오칭,맥스 , 솔로몬,그레고리
IPC分类号： C01B3/26 , B01J23/755
CPC分类号： C01B3/26 , B01J19/088 , B01J19/126 , B01J23/755 , B01J23/78 , B01J37/18 , B01J37/349 , B01J2219/0869 , B01J2219/0875 , B01J2219/0892 , B82Y30/00 , C01B3/505 , C01B2203/0277 , C01B2203/041 , C01B2203/048 , C01B2203/0855 , C01B2203/0861 , C01B2203/1041 , C01B2203/1058 , C01B2203/1076 , C01B2203/1241 , C01B2203/1676 , C01B2203/169 , D01F9/1272 , Y02E60/324
摘要： A method for producing a hydrogen enriched fuel includes the steps of providing a flow of methane gas at a selected flow rate, providing a catalyst (56), producing a methane plasma at a negative pressure using microwave irradiation at a selected microwave power, directing the methane plasma over the catalyst (56), and controlling the flow of methane gas and the microwave power to produce a product gas having a selected composition. A system (10) for producing a hydrogen enriched fuel includes a methane gas source (16), a reactor (12) having a reaction chamber (22) containing a catalyst (56), a microwave power source (14) configured to form a methane plasma, and a vacuum pump (78) configured to maintain the reaction chamber (22) at a negative pressure.
摘要翻译：一种生产富氢燃料的方法包括以选定的流速提供甲烷气流的步骤，提供催化剂（56），在选定的微波功率下使用微波照射在负压下产生甲烷等离子体，催化剂（56）上的甲烷等离子体，并且控制甲烷气体和微波功率的流动以产生具有所选组成的产物气体。用于生产富氢燃料的系统（10）包括甲烷气体源（16），具有包含催化剂（56）的反应室（22）的反应器（12），微波功率源（14）甲烷等离子体和被配置为将反应室（22）保持在负压下的真空泵（78）。

68. 发明公开

KR1020090114408A 마이크로파 보조 촉매 상 메탄 분해를 이용한 수소 농후 연료 제조 방법 및 시스템 无效
标题翻译：使用微波辅助甲烷分解在催化剂上生产氢化物燃料的方法和系统
公开(公告)号：KR1020090114408A
公开(公告)日：2009-11-03
申请号：KR1020097017541
申请日：2008-01-13
申请人： 에덴 이노베이션즈 리미티드 , 더 유니버서티 어브 퀸슬랜드
发明人： 주,종후아,존 , 첸,지우링 , 루,가오칭,맥스 , 솔로몬,그레고리
IPC分类号： C01B3/46 , C01B3/26 , B01J19/08
CPC分类号： C01B3/26 , C01B3/505 , C01B2203/0277 , C01B2203/0405 , C01B2203/041 , C01B2203/048 , C01B2203/0855 , C01B2203/1058 , C01B2203/1076 , C01B2203/1241 , C01B2203/16 , C01B2203/1619 , C01B2203/1671 , C01B2203/168 , C01B2203/169
摘要： A method for producing a hydrogen enriched fuel includes the steps of providing a flow of methane gas, and providing a catalyst (56). The method also includes the steps of heating the catalyst (56) instead of the reactor walls and the methane gas using microwave irradiation at a selected microwave power, directing the flow of methane gas over the catalyst (56), and controlling the microwave power to produce a product gas having a selected composition. A system (10) for producing a hydrogen enriched fuel includes a methane gas source (16), a reactor (12) containing a catalyst (56), and a microwave power source (14) configured to heat the catalyst (56).
摘要翻译：一种生产富氢燃料的方法包括提供甲烷气流并提供催化剂（56）的步骤。该方法还包括以选定的微波功率使用微波照射加热催化剂（56）代替反应器壁和甲烷气体的步骤，引导甲烷气体流过催化剂（56），并将微波功率控制在产生具有选定组成的产物气体。用于生产富氢燃料的系统（10）包括甲烷气体源（16），含有催化剂（56）的反应器（12）和构造成加热催化剂（56）的微波功率源（14）。

69. 发明公开

KR1020090110897A 수소 정제 방법, 수소 분리막 및 수소 정제 장치 无效
标题翻译：氢气净化方法，氢分离膜和氢气净化装置
公开(公告)号：KR1020090110897A
公开(公告)日：2009-10-23
申请号：KR1020097016659
申请日：2007-12-18
申请人： 미츠비시 가스 가가쿠 가부시키가이샤
发明人： 오카다에이지 , 요시하라준 , 이코마후토시 , 다케마사노보루 , 다야마다츠노리 , 오츠카겐지
IPC分类号： C01B3/58 , B01D53/04
CPC分类号： B01D71/022 , B01D53/228 , B01D67/0044 , B01D67/0069 , B01D67/0072 , B01D69/02 , B01D2256/16 , B01D2257/102 , B01D2257/502 , B01D2257/504 , B01D2257/7022 , B01D2257/80 , B01D2325/06 , C01B3/32 , C01B3/505 , C01B2203/0233 , C01B2203/0244 , C01B2203/025 , C01B2203/0266 , C01B2203/0405 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/1211 , C01B2203/1217 , C01B2203/1235 , Y02C10/10 , Y02P20/152
摘要： Disclosed are: a method for separating/purifying hydrogen from a hydrogen-containing gas which contains 1% or more of at least one component selected from water, carbon monooxide, carbon dioxide, methane and nitrogen besides hydrogen with a high degree of efficiency, while maintaining a high hydrogen permeation ability; a hydrogen separation membrane for use in the method; and a hydrogen purification apparatus. Specifically disclosed are: a hydrogen purification method which can separate/purify hydrogen from a hydrogen-containing gas which contains 1% or more of at least one component selected from water, carbon monooxide, carbon dioxide, methane and nitrogen by using a hydrogen separation membrane comprising a palladium alloy membrane and a palladium microparticle attached on the surface of the palladium alloy membrane; a hydrogen separation membrane for use in the method; and a hydrogen purification apparatus.
摘要翻译：本发明公开了一种从含氢气体中分离纯化氢的方法，其特征在于，除了具有高效率的氢以外，还含有选自水，一氧化碳，二氧化碳，甲烷和氮中的至少一种成分的1％以上的氢，保持高氢渗透能力; 用于该方法的氢分离膜; 和氢气净化装置。具体公开的是：通过使用氢分离膜，可以从含有1％以上选自水，一氧化碳，二氧化碳，甲烷和氮中的至少一种成分的含氢气体中分离/纯化氢气的氢气净化方法包括钯合金膜和附着在钯合金膜表面上的钯微粒; 用于该方法的氢分离膜; 和氢气净化装置。

70. 发明授权

KR100908096B1 수소 정제 필터 및 그 제조 방법 失效
标题翻译： 수소정제필터및그제조방법
公开(公告)号：KR100908096B1
公开(公告)日：2009-07-16
申请号：KR1020067017620
申请日：2005-10-18
申请人： 다이니폰 인사츠 가부시키가이샤
发明人： 마에다다카노리 , 야기히로시 , 하라야마아사코
IPC分类号： B01D71/02 , B01D53/22 , B01D69/10 , B01D69/12
CPC分类号： B01D69/02 , B01D53/228 , B01D67/0062 , B01D71/022 , B01D2325/021 , C01B3/505 , C01B2203/041 , C01B2203/047 , C23F1/02 , C23F1/28 , C25D7/00 , Y10S55/05 , Y10T428/12951 , Y10T428/249953
摘要： A hydrogen-purification membrane comprises a Pd alloy film joined to one surface of a porous support substrate. Each pore in the porous support substrate is such that between the thickness T of the porous support substrate, the opening diameter D1 of the pore on the side joined to the Pd alloy film and the opening diameter D2 of the pore on the opposite side, there are relations represented by 1.0
摘要翻译：氢净化膜由与多孔质支撑基材的一面接合的Pd合金膜构成。多孔质支撑基材中的各孔的厚度在多孔质支撑基材的厚度T与Pd合金膜接合侧的孔的开口直径D1和相反侧的孔的开口直径D2之间，是由1.0≤D1/T≤5.0,1.0≤D2/T≤5.0所表示的关系，且在与Pd合金膜接合的一侧的细孔的开口直径D1与开口直径D2之间相反侧的孔和孔的最窄部分的开口直径D3具有由D3 / D1 <0.8，D3 / D2 <0.9和D3 <250μm表示的关系。此外，与Pd合金膜接合的一侧的孔的总开口面积占多孔支撑基板面积的20-80％。

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