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    • 22. 发明公开
    • 신규의 알루미늄 알콕사이드 화합물 및 그 제조 방법
    • 新型烷氧基铝复合物及其制备方法
    • KR1020100054317A
    • 2010-05-25
    • KR1020080113192
    • 2008-11-14
    • 한국화학연구원
    • 정택모김창균이영국안기석이선숙윤혜정
    • C01F7/00
    • C07F5/06
    • PURPOSE: Novel aluminum alkoxide compounds and a preparing method thereof are provided, which can obtain heat stability and excellent volatility and enable manufacture of a film of the high purity containing aluminum. CONSTITUTION: An aluminium alkoxide compound is represented as the chemical formula 1, Al(O-A-NR^1R^2)_x(R^3)_3-x. In the chemical formula 1, A is alkylene of C2-C5 and is substituted for linear or branched alkyl of one or more C1-C5, R^1 to R^3 are independently linear or branched alkyl of C1-C5, and X is fixed number of 1 to 3. The manufacturing method of the aluminium alkoxide compound is to react aluminum compound of the chemical formula 3, AlR^3_3 and alcohol of the chemical formula 4, HO-A-NR^1R^2.
    • 目的:提供新的烷氧基铝化合物及其制备方法,其可以获得热稳定性和优异的挥发性,并且能够制造含有高纯度的铝的膜。 构成:烷氧化铝化合物表示为化学式1,Al(O-A-NR 1 R 1)2(X 3)3-x。 在化学式1中,A是C 2 -C 5的亚烷基并且被一个或多个C 1 -C 5的直链或支链烷基取代,R 1至R 3独立地是C1-C5的直链或支链烷基,X是 固定数量为1〜3。烷氧基铝化合物的制造方法是使化学式3的铝化合物,AlR 3 3 3和化学式4的醇HO-A-NR 1 1R 2。
    • 23. 发明公开
    • 새로운 하프늄 알콕사이드 화합물 및 이의 제조 방법
    • 新型高效烷氧化铝化合物及其制备方法
    • KR1020100054300A
    • 2010-05-25
    • KR1020080113164
    • 2008-11-14
    • 한국화학연구원
    • 정택모김창균이영국안기석이선숙윤혜정류병환
    • C01G27/00
    • PURPOSE: A novel hafnium alkoxide compounds and a preparing method thereof are provided, in which compounds are thermally stable, have high volatility, and enhance reactivity with the ozone. CONSTITUTION: A novel hafnium alkoxide compound is represented as the chemical formula 1, HF(OCR^1R^2R^3)_4. In the chemical formula 1, R^1 and R2 are independently the linear or branched alkyl group of C1-C5, R^3 is linear alkenyl or alkynyl group of C2-C5. R^1 and R2 are independently selected from CH_3, C2H5, and CH(CH_3)2 or C(CH_3)3, and R^3 is C≡CH, CH_2C≡CH, CH_2CH_2C≡CH, C≡CCH_3, CH_2C≡CCH_3 or CH_2CH_2C≡CCH_3. The manufacturing method of the hafnium alkoxide compound of the chemical formula 1 is to react hafnium amide compound of the chemical formula 2, Hf(NR^4R^5)_4 and alcohol compound of the chemical formula 3, HOCR^1R^2R^3.
    • 目的:提供一种新型的铪醇盐化合物及其制备方法,其中化合物是热稳定的,具有高挥发性,并增强与臭氧的反应性。 构成:一种新的铪醇盐化合物以化学式1表示,HF(OCR 1 R 1 R 2 R 3)4。 在化学式1中,R 1和R 2独立地是C 1 -C 5的直链或支链烷基,R 3是C 2 -C 5的直链烯基或炔基。 R 1和R 2独立地选自CH 3,C 2 H 5和CH(CH 3)2或C(CH 3)3,R 3是C≡CH,CH 2C≡CH,CH 2 CH 2C≡CH,C≡CCH3,CH 2C≡CCH3 或CH 2 CH 2C≡CCH3。 化学式1的铪醇盐化合物的制造方法是使化学式2的铪酰胺化合物,Hf(NR 4 4R 5)4和化学式3的HO化合物HOCR 1 1R 2 2R 3 。
    • 25. 发明公开
    • 신규한 카드뮴 아미노알콕사이드 화합물 및 이의 제조 방법
    • 新型氨基脲氧化物复合物及其制备方法
    • KR1020090073289A
    • 2009-07-03
    • KR1020070141190
    • 2007-12-31
    • 한국화학연구원
    • 김창균정택모이영국안기석이선숙류병환장세진
    • C07F3/08C07F3/00B82B3/00
    • C07F3/08B82B3/00C01G11/00C01P2004/64C22B17/00C23C16/18
    • A cadmium aminoalkoxide compound is provided to manufacture the nano size of cadmium, cadmium oxide, and cadmium chalcogenide at low temperature. A method for manufacturing the cadmium aminoalkoxide compound of chemical formula 1 is reacting an alkyl cadmium compound of the chemical formula 2 and amino alcohol of the chemical formula 3. The chemical formulas 1, 2, and 3 are denoted by [R3-Cd-(O-A-NR1R2)]4, Cd(R3)2, and HO-A-NR1R2, respectively. In the chemical formula 1,2 and 3, the A is linear or branched (C2-C10) alkylene group which is non-substituted or substituted with a halogen. The R1 and R2 is each linear or branched (C1-C7) alkyl group which is non-substituted or substituted with the halogen. Or a hetero ring is formed by binding R1 and R2 with (C4-C6) alkylene. The R3 is linear or branched (C1-C7) alkyl group.
    • 提供了一种镉氨基烷氧基化合物,以在低温下制造镉,氧化镉和硫属镉的纳米尺寸。 制备化学式1的氨基二氧化镉化合物的方法是使化学式2的烷基镉化合物与化学式3的氨基醇反应。化学式1,2和3由[R 3 -CD-( OA-NR1R2)] 4,Cd(R3)2和HO-A-NR1R2。 在化学式1,2和3中,A是未被取代或被卤素取代的直链或支链(C2-C10)亚烷基。 R1和R2分别是不被卤素取代或取代的直链或支链(C1-C7)烷基。 或者通过将R 1和R 2与(C 4 -C 6)亚烷基结合形成杂环。 R3是直链或支链(C1-C7)烷基。
    • 27. 发明授权
    • 플라즈마 유기-금속 화학 증착법을 이용한 p형 산화아연박막 제조 방법
    • 通过等离子体增强金属有机化学气相沉积制备P-ZNO膜
    • KR100803950B1
    • 2008-02-18
    • KR1020060093970
    • 2006-09-27
    • 한국화학연구원
    • 김창균이영국정택모안기석이선숙
    • H01L21/205H01L21/3065
    • H01L21/02554C23C16/513H01L21/0262
    • A method for forming a p-type zinc oxide layer using plasma enhanced metal organic chemical vapor deposition is provided to adjust a doping concentration by controlling a dose of an organic metal compound of a group-V element. After a substrate(20) is put in a reactor(10) and then an oxygen source and an argon gas are inputted to the reactor, an RF power is applied to the reactor to produce a plasma in the reactor. A zinc precursor and a group-V precursor as a dopant are inputted to the reactor to form a p-type zinc oxide layer on the substrate. The heat treatment is performed on a substrate with the p-type zinc oxide layer. When the p-type zinc oxide layer is formed, a temperature of the substrate is in the range of 200 to 400 degrees centigrade.
    • 提供了使用等离子体增强金属有机化学气相沉积形成p型氧化锌层的方法,通过控制V族元素的有机金属化合物的剂量来调节掺杂浓度。 将基板(20)放入反应器(10)中,然后将氧源和氩气输入到反应器中,向反应器施加RF功率以在反应器中产生等离子体。 将锌前体和作为掺杂剂的V族前体输入到反应器中,以在衬底上形成p型氧化锌层。 在具有p型氧化锌层的基板上进行热处理。 当形成p型氧化锌层时,基板的温度在200至400摄氏度的范围内。
    • 29. 发明公开
    • 망간-주입된 산화아연 단결정의 제조방법
    • 用于制备氧化锌单晶的方法
    • KR1020070024883A
    • 2007-03-08
    • KR1020050080464
    • 2005-08-31
    • 한국화학연구원
    • 이영국
    • C30B29/22
    • A method for fabricating a manganese-implanted zinc oxide single crystal is provided to increase the quantity of manganese implanted into a zinc oxide single crystal by adding water-soluble salt of manganese to a conventional solution used to be used as a mineralizer. Under the existence of a mixed hydrothermal solution including KOH, LiOH and Mn as a mineralizer, a Mn-implanted zinc oxide single crystal is fabricated by a hydrothermal method while using manganese oxide, a zinc oxide powder sintering material and a zinc oxide seed crystal. A solution having saturated zinc oxide can be used as a mineralizer.
    • 提供了一种制造锰注入的氧化锌单晶的方法,以通过将锰的水溶性盐添加到用作矿化剂的常规溶液中来增加注入到氧化锌单晶中的锰的量。 在含有KOH,LiOH和Mn作为矿化剂的混合水热溶液的存在下,通过水热法制造Mn注入的氧化锌单晶,同时使用氧化锰,氧化锌粉末烧结材料和氧化锌晶种。 可以使用具有饱和氧化锌的溶液作为矿化剂。