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    • 2. 发明授权
    • 폐고분자 물질의 액상분해용 촉매의 제조방법 및 이를이용한 분해방법
    • 폐고분자물질의액상분해용촉매의제조방법및이를이용한해방폐
    • KR100381563B1
    • 2003-05-12
    • KR1020000075515
    • 2000-12-12
    • 서곤
    • 서곤김종호
    • B01J37/08B01J37/00B01J29/06
    • PURPOSE: Provided are preparation method of liquid phase degradation catalyst, a hydrogen exchanged MFI zeolite, for waste polymer and its polymer degradation method into low molecular hydrocarbons. The catalyst is prepared by treating zeolite in proper manner so that its surface area is increased, making the catalyst highly active and slowing down the carbon deposit. It degrades polymer fast into low molecular materials and increases the high yield of liquid products. CONSTITUTION: The preparation of catalyst comprises: making a synthetic mother liquid of 3-16(K2O, Na2O)·0.25-1.0Al2O3·50-100SiO2·2150-3000H2O without an organic template; adding 0.5-4g of MFI zeolite, as a core, per kg of the above mother liquid and synthesizing at 175-205°C for 1-3 days; and exchanging hydrogen by treating with 0.2-3N aqueous hydrogen chloride solution. The degradation device by the above MFI zeolite catalyst includes: delivery equipment of the reactant which slowly introduces, at a certain speed, molten polyolefin waste polymer heated, at the end of the hopper, to 200-350°C into the batch reactor; a reactor stirring the reactant and the alkali treated zeolite at 50-500rpm and the temperature of its exterior wall is controlled within ±2°C; a final reactor which increases the yield of the liquid products and converts the olefin into aromatic compounds by filling in the gallium exchanged MFI or BEA zeolite; and a separator of liquid products which separates the products continuously into different grades by the two step separator of different temperatures.
    • 目的:提供一种液相降解催化剂,一种氢交换MFI沸石,用于废聚合物及其聚合物降解方法制备低分子量烃的方法。 该催化剂通过以适当的方式处理沸石以使其表面积增加而制备,使得催化剂具有高活性并减缓碳沉积。 它将聚合物快速降解成低分子材料,并增加液体产品的高产量。 构成:催化剂的制备包括:制备不含有机模板的3-16(K 2 O,Na 2 O)→0.25-1.0Al 2 O 3→50-100SiO 2& 2150-3000H 2 O的合成母液; 每千克上述母液加入0.5-4克MFI沸石作为核心,并在175-205℃下合成1-3天; 并通过用0.2-3N氯化氢水溶液处理来交换氢气。 上述MFI沸石催化剂的降解装置包括:反应物的输送设备,其以一定的速度缓慢地将在料斗末端加热到200-350℃的熔融聚烯烃废料聚合物引入间歇反应器 ; 以50-500rpm搅拌反应物和碱处理过的沸石的反应器,其外壁温度控制在±2℃以内; 最终反应器,其通过填充镓交换的MFI或BEA沸石来提高液体产物的收率并将烯烃转化为芳族化合物; 以及通过不同温度的两步分离器将产物连续分离成不同等级的液体产物分离器。
    • 5. 发明公开
    • 농작물 선도 유지용 복합 흡착제
    • 用于维护农业作物新鲜的复合吸收剂
    • KR1020040026953A
    • 2004-04-01
    • KR1020020058610
    • 2002-09-27
    • 서곤방영정
    • 서곤방영정
    • A23B7/157
    • PURPOSE: A composite absorbent remarkably maintaining the freshness of agricultural crops for a long time is provided, which is composed of calcinated zeolite, zeolite impregnated with silver and calcium chloride and activated carbon . CONSTITUTION: A composite absorbent for maintaining the freshness of agricultural crops characteristically comprises: natural zeolite impregnated with silver; natural zeolite impregnated with calcium chloride; and activated carbon or activated carbon impregnated with silver in a weight ratio of 20 to 40:30 to 50:20 to 40.
    • 目的:提供长期保持农作物新鲜度的复合吸收剂,其由煅烧沸石,浸渍有银和氯化钙的沸石和活性炭组成。 构成:用于保持农作物新鲜度的复合吸收剂特征在于包括:用银浸渍的天然沸石; 用氯化钙浸渍的天然沸石; 和活性炭或浸渍有银的活性炭,其重量比为20至40:30至50:20至40。
    • 7. 发明公开
    • 타이어용 구리박막코드의 제조방법
    • 铜箔薄膜生产方法
    • KR1020000065495A
    • 2000-11-15
    • KR1019990011832
    • 1999-04-06
    • 서곤
    • 서곤조평래전경수
    • C23C22/52
    • B60C9/0007B60C2009/0014C23C18/1803C23C18/38D07B1/066
    • PURPOSE: A production method of a copper thin film cord is provided to save production time by rapidly forming an adhesive layer, to promote stability and to delay adhesive deterioration. CONSTITUTION: In producing a copper thin film cord, zinc or tin is plated on a wire surface. After the wire surface is drawn in a wire strand, the wire surface is metathesis-plated with a copper salt solution. Herein, the thickness of the copper plating is 20 to 90mm. The metathesis plating is performed by using the copper salt solution selected from a group consisted of copper sulfate, copper chloride, nitric acid copper and ascetic acid copper.
    • 目的:提供铜薄膜帘线的制造方法,通过快速形成粘合剂层来节省生产时间,促进稳定性和延迟粘合剂劣化。 构成:在生产铜薄膜电线时,锌或锡镀在电线表面上。 在钢丝表面被拉丝成线材之后,金属丝表面用铜盐溶液进行复分解镀。 这里,铜镀层的厚度为20〜90mm。 复分解电镀通过使用选自硫酸铜,氯化铜,硝酸铜和乙酰酸铜的铜盐溶液进行。
    • 9. 发明公开
    • FCC 공정 폐촉매로부터 폐고분자 물질의 액상 분해용촉매의 제조방법 및 이 촉매를 이용한 폐고분자 물질의분해방법
    • 用于从使用FCC(流化催化裂化)催化剂中降解废弃聚合物的液相降解催化剂的制备方法和使用其的催化降解方法
    • KR1020030035638A
    • 2003-05-09
    • KR1020010067890
    • 2001-11-01
    • 서곤
    • 서곤김종호장남표
    • B01J38/60
    • B01J38/60B01J38/64C07C4/00
    • PURPOSE: Provided are a method for fabricating catalyst for use in a liquid-phase decomposition process at low cost, and a liquid-phase decomposition process with high profitability by using the same. CONSTITUTION: The method comprises the steps of (a) reflux-heating waste catalyst of FCC process with 0.2-2.0N of hydrochloric acid, 0.1-1.0N of sodium hydroxide and potassium hydroxide at a temperature 60-80°C for 2-6 hours, and mixing the acid or base treated catalyst of the step (a) with FAU or MFI zeolite catalyst by below 100g. The liquid-phase degradation process comprises the step of degrading a polymer such as PE, PP and waste vinyl by using 10-100g of the catalyst prepared by the method above at 350-550°C to be hydrocarbon.
    • 目的:提供以低成本制造用于液相分解过程的催化剂的方法,以及通过使用该液相分解方法具有高利润率的液相分解方法。 方法:该方法包括以下步骤:(a)在温度60-80℃下,用0.2-2.0N盐酸,0.1-1.0N氢氧化钠和氢氧化钾将FCC方法的废催化剂回流加热至2-6 小时,并将步骤(a)的酸或碱处理的催化剂与FAU或MFI沸石催化剂混合低于100g。 液相分解方法包括通过使用10-100g上述方法制备的催化剂在350-550℃下使聚合物如PE,PP和废乙烯基降解为烃的步骤。
    • 10. 发明公开
    • 폐고분자 물질의 액상분해용 촉매의 제조방법 및 이를이용한 분해방법
    • 用于废弃聚合物的液相降解催化剂的制备方法及其使用的降解方法
    • KR1020020046027A
    • 2002-06-20
    • KR1020000075515
    • 2000-12-12
    • 서곤
    • 서곤김종호
    • B01J37/08B01J37/00B01J29/06
    • B01J37/0009B01J29/70B01J37/30B09B3/00C07C4/00
    • PURPOSE: Provided are preparation method of liquid phase degradation catalyst, a hydrogen exchanged MFI zeolite, for waste polymer and its polymer degradation method into low molecular hydrocarbons. The catalyst is prepared by treating zeolite in proper manner so that its surface area is increased, making the catalyst highly active and slowing down the carbon deposit. It degrades polymer fast into low molecular materials and increases the high yield of liquid products. CONSTITUTION: The preparation of catalyst comprises: making a synthetic mother liquid of 3-16(K2O, Na2O)·0.25-1.0Al2O3·50-100SiO2·2150-3000H2O without an organic template; adding 0.5-4g of MFI zeolite, as a core, per kg of the above mother liquid and synthesizing at 175-205°C for 1-3 days; and exchanging hydrogen by treating with 0.2-3N aqueous hydrogen chloride solution. The degradation device by the above MFI zeolite catalyst includes: delivery equipment of the reactant which slowly introduces, at a certain speed, molten polyolefin waste polymer heated, at the end of the hopper, to 200-350°C into the batch reactor; a reactor stirring the reactant and the alkali treated zeolite at 50-500rpm and the temperature of its exterior wall is controlled within ±2°C; a final reactor which increases the yield of the liquid products and converts the olefin into aromatic compounds by filling in the gallium exchanged MFI or BEA zeolite; and a separator of liquid products which separates the products continuously into different grades by the two step separator of different temperatures.
    • 目的:提供液相降解催化剂,氢交换的MFI沸石,废聚合物及其聚合物降解方法为低分子量烃的制备方法。 通过以适当的方式处理沸石来制备催化剂,使得其表面积增加,使得催化剂高度活跃并减缓碳沉积。 它将聚合物快速降解成低分子材料,并提高液体产品的高产量。 构成:催化剂的制备包括:制备3-16(K2O,Na2O)·0.25-1.0Al2O3·50-100SiO2·2150-3000H2O的合成母液,无有机模板; 以每kg上述母液加入0.5-4g作为核心的MFI沸石,在175〜205℃下合成1-3天; 并用0.2-3N氯化氢水溶液处理氢气。 上述MFI沸石催化剂的降解装置包括:反应物的输送设备,以一定速度将在料斗末端加热的熔融聚烯烃废物聚合物缓慢地引入200-350℃进入间歇式反应器; 将反应物和碱处理的沸石以50-500rpm搅拌并将其外壁的温度控制在±2℃以内的反应器; 最终的反应器,其通过填充镓交换的MFI或BEA沸石来提高液体产物的产率并将烯烃转化为芳族化合物; 以及通过不同温度的两步分离器将产品连续分成不同等级的液体产品分离器。