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    • 10. 发明专利
    • Production of cycloalkanecarboxylic acid salt compound
    • 环烷基羧基酸盐化合物的生产
    • JPS61122243A
    • 1986-06-10
    • JP24418884
    • 1984-11-19
    • Nippon Zeon Co Ltd
    • OKUMURA KINICHINAKANO MUNETOSHI
    • C07C61/00C07C51/00C07C61/06C07C67/00
    • PURPOSE: To obtain the titled substance economically in high yield, by using a mixture of an alcohol and other organic solvent as a reaction solvent, in contacting a 2-halogenocycloalkanone compound with an alkali metal hydroxide.
      CONSTITUTION: The titled compound can be produced by reacting a 2- halogenocycloalkanone compound (e.g. 2-chlorocyclohexane) with anhydrous alkali metal hydroxide in a mixture of an alcoholic solvent and other organic solvent (preferably a hydro-carbon such as benzene, xylene, hexane, etc.) at 10W150°C, preferably 40W120°C under atmospheric pressure. The amount of the alkali metal hydroxide is preferably 2W4 equivalent based on the above raw material. The amount of the mixed solventis usually 0.5W20pts.wt. per 1pt. of the raw materal, and the ratio of the alcohol to the other organic solvent is 50W97wt% to 3W50wt%.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过使用醇和其他有机溶剂的混合物作为反应溶剂,以高收率经济地获得标题物质,使2-卤代环烷酮化合物与碱金属氢氧化物接触。 构成:标题化合物可以通过2-卤代环烷酮化合物(例如2-氯环己烷)与无水碱金属氢氧化物在醇溶剂和其它有机溶剂(优选苯,二甲苯,己烷 等),在大气压下在10-150℃,优选40-120℃。 基于上述原料,碱金属氢氧化物的量优选为2-4当量。 混合溶剂的用量通常为0.5-20pts.wt。 每1pt。 的原料,醇与其他有机溶剂的比例为50-97重量%至3-50重量%。