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1. 发明专利

JP2004517989A Polymerizable luxury diamond-like bodies derivative 审中-公开
公开(公告)号：JP2004517989A
公开(公告)日：2004-06-17
申请号：JP2002557884
申请日：2002-01-17
申请人：シェブロンユー.エス.エー. インコーポレイテッド
发明人：カールソン、ロバート、エム , ダール、ジェレミー、イー , リウ、シェンガオ
IPC分类号： C07C4/00 , C07C7/04 , C07C7/12 , C07C7/135 , C07C13/64 , C07C17/10 , C07C17/16 , C07C17/383 , C07C17/395 , C07C23/20 , C07C23/46 , C07C35/44 , C07C39/17 , C07C47/347 , C07C49/423 , C07C61/29 , C07C69/00 , C07C69/08 , C07C69/753 , C07C205/05 , C07C211/19 , C07C211/50 , C07C217/90 , C07C233/06 , C07C255/06 , C08G61/00 , C08G61/02 , C08G83/00 , C08G85/00 , C08L65/00
CPC分类号： B82Y30/00 , B82Y10/00 , C07C4/00 , C07C7/04 , C07C7/12 , C07C7/135 , C07C13/64 , C07C17/10 , C07C17/16 , C07C17/383 , C07C17/395 , C07C23/20 , C07C29/124 , C07C29/143 , C07C29/149 , C07C29/48 , C07C31/137 , C07C31/278 , C07C37/20 , C07C39/17 , C07C41/16 , C07C43/188 , C07C45/28 , C07C47/347 , C07C49/423 , C07C51/353 , C07C67/08 , C07C67/14 , C07C69/08 , C07C69/38 , C07C69/54 , C07C69/604 , C07C205/05 , C07C211/38 , C07C211/50 , C07C217/90 , C07C233/58 , C07C2603/54 , C07C2603/90 , C08G61/00 , C08G61/02 , C08G83/00 , C08L65/00 , C07C69/608 , C07C61/125
摘要：重合反応に参加することができる高級ダイヤモンド様体誘導体が、これらの誘導体への中間体として、これらの誘導体から形成された重合体として、そしてそれらの重合体を造るための方法として開示される。

2. 发明专利

JPH07179449A HIRSUTENE DERIVATIVE AND ANTICANCER AGENT CONTAINING THE SAME DERIVATIVE 失效
公开(公告)号：JPH07179449A
公开(公告)日：1995-07-18
申请号：JP32178293
申请日：1993-12-21
申请人： MITSUI TOATSU CHEMICALS
发明人： FUKUMOTO KEIICHIRO , TOYODA SHINKO
IPC分类号： C07D307/93 , A61K31/045 , A61K31/12 , A61K31/34 , A61K31/343 , A61P35/00 , C07C35/44 , C07C49/423 , C07C49/617
摘要： PURPOSE:To provide a new derivative effective in treating leukemia, tumors such as osteosarcoma, breast cancer and ovarioncus and an anticancer agent containing the derivative as an active ingredient. CONSTITUTION:This-derivative has a formula I (X= is CH2=, formula II or O=; R is H or a lower alkyl; the mark-represents cis or trans to bond of CH2 group whose bond is adjacent; a chain line is a single bond or a double bond). This anticancer agent is obtained by blending the derivative with a diluent or a carrier. Preferred example of the derivative is a derivative of formula III. The derivative is obtained by lactonizing, e.g. 6-methyl-3-cyclohexene-1- carboxylic acid, subjecting the resultant compound to decomposition, reduction, protection, acetylation and deprotection to afford an intermediate of formula IV, subjecting the intermediate of formula IV to ozone oxidation and Wittig reaction to give an intermediate of formula V, cyclizing the intermediate of formula V by conjugaion-addition reaction using an acid catalyst, hydrolyzing the cyclized compound, introducing a double bond into the compound to afford an intermediate of formula VI and further, reacting the intermediate with a silyl ether and palladium acetate.

3. 发明专利

JPH06504981A 失效
公开(公告)号：JPH06504981A
公开(公告)日：1994-06-09
申请号：JP50455691
申请日：1991-02-12
IPC分类号： C07C1/207 , C07C2/82 , C07C13/615 , C07C13/64 , C07C49/423 , C08G61/00

4. 发明专利

JPH05221623A METHOD FOR SYNTHESIZING FULLEREN DERIVATIVE 失效
公开(公告)号：JPH05221623A
公开(公告)日：1993-08-31
申请号：JP5977592
申请日：1992-02-14
申请人： DORYOKURO KAKUNENRYO
发明人： FUNASAKA HIDEYUKI , YAMAMOTO KAZUNORI
IPC分类号： C01B31/02 , C07C45/27 , C07C49/423 , C07D307/77 , C07D311/94
摘要： PURPOSE:To directly synthesize a fulleren derivative by packing lanthanum oxide in the interior of a graphite crucible, heating the crucible by resistance to produce ultra-fine particles and then extracting these particles using toluene. CONSTITUTION:Granular lanthanum oxide (La2O3) 40 is packed in the interior of a graphite crucible 12 and the crucible 12 is placed in a producing furnace 10. Then alternating current is fed from a an electric current device 30 to the space between the upper electrode 14 and the lower electrode 16 in a state of pulse. In this time, helium gas is passed through the crucible 12. The inside and outside of the graphite crucible is raised until about 3000 deg.C to produce ultra-fine particles in large amounts. These ultra-fine particles are carried together with a carrier gas to a dust filter 28, where these particles are captured. The produced ultra-fine particles are led to a dissolving tank 32, where these particles are brought into contact with toluene. 200-500cc toluene based on 1g ultra-fine particles containing about 10% fulleren is used. The ultra-fine particles are immersed in the toluene at room temperature for about 24hr to provide a solution having wine color. A fulleren derivative containing a CO group and a carboxyl group in C60 is contained in the resultant solution.

5. 发明专利

JPS61277644A PRODUCTION OF 5-MEMBERED CYCLIC KETONE 失效
公开(公告)号：JPS61277644A
公开(公告)日：1986-12-08
申请号：JP11669085
申请日：1985-05-31
申请人： NIPPON OIL CO LTD
发明人： KOBORI YOSHIHIRO , TAKESONO TETSUYA
IPC分类号： C07C45/49 , B01J31/00 , B01J31/02 , B01J31/20 , C07C45/00 , C07C49/395 , C07C49/423 , C07C49/597 , C07C67/00 , C07C69/533 , C07C69/716
摘要： PURPOSE:To obtain a 5-membered cyclic ketone useful as a raw material of pharmaceuticals, perfumery, etc., economically, by reacting a nonconjugated diene with a 3-10C saturated secondary alcohol with carbon monoxide in the presence of a catalyst consisting of a cobalt compound and a tertiary aromatic amine. CONSTITUTION:A 5-membered cyclic ketone, especially a polycyclic ketone can be produced easily by reacting (A) a nonconjugated diene with (B) a 3-10C saturated secondary alcohol (preferably isopropanel, etc.) preferably at 100-200 deg.C under carbon monoxide pressure of 100-400kg/cm in the presence of (C) a catalyst consisting of (i) a cobalt compound and (ii) a tertiary aromatic amine. The amounts of the cobalt compound and the tertiary aromatic amine are preferably 0.005-0.1mol (in terms of cobalt atom) and 0.05-0.5mol per 1mol (in terms of cobalt atom) and 0.05-0.5mol per 1mol of the diene, respectively. The present process has advantages over the conventional processes using a palladium compound as the catalyst in view of the cost and stability of the catalyst and the selectivity and productivity of the objective compound. It can be applied to the production of various kinds of nonconjugaed dienes.

6. 发明专利

JP2017528455A 神経保護特性を有する両親媒性化合物审中-公开
公开(公告)号：JP2017528455A
公开(公告)日：2017-09-28
申请号：JP2017511948
申请日：2015-08-25
申请人：ウスタフオルガニッケヘミエアービオヘミエアカデミエヴェドツェーエル,ヴェー.ヴェー.イー , ウスタフオルガニッケヘミエアービオヘミエアカデミエヴェドツェーエル,ヴェー.ヴェー.イー , フィズィオロギッキウスタフアーヴェーツェーエル,ヴェー.ヴェー.イー , フィズィオロギッキウスタフアーヴェーツェーエル,ヴェー.ヴェー.イー
发明人：グドヴァ，エヴァ , ホドウンスカ，ハナ , カプラス，ヴォイテフ , ヴィクリツキー，ラディスラフ , ヴァレス，カレル , ヤーン，ウルリフ
IPC分类号： C07C305/20 , A23L33/10 , A61K8/46 , A61K31/19 , A61K31/215 , A61K31/255 , A61K31/56 , A61K31/568 , A61K31/5685 , A61K31/57 , A61K31/575 , A61K31/58 , A61P9/10 , A61P23/00 , A61P25/00 , A61P25/04 , A61P25/08 , A61P25/14 , A61P25/18 , A61P25/20 , A61P25/22 , A61P25/24 , A61P25/28 , A61P25/30 , A61P35/00 , A61Q19/08 , A61Q90/00 , C07C35/42 , C07C35/44 , C07C43/13 , C07C49/423 , C07C49/453 , C07C49/523 , C07C69/40 , C07C69/757 , C07C271/22 , C07J1/00 , C07J3/00 , C07J7/00 , C07J9/00 , C07J13/00 , C07J21/00 , C07J41/00 , C07J43/00 , C07J63/00 , C07J71/00
CPC分类号： C07J43/003 , C07C59/80 , C07C305/20 , C07C2603/26 , C07D209/36 , C07D213/18 , C07D317/72 , C07J1/0007 , C07J1/0011 , C07J9/00 , C07J9/005 , C07J13/007 , C07J31/006 , C07J41/0005 , C07J41/0033 , C07J41/0038 , C07J53/001 , C07J63/008 , C07J71/0005
摘要：本発明は、神経保護効果を示す、テトラデカヒドロフェナントレン骨格を有する、両親媒性化合物およびそのエナンチオマー、CNSの虚血性障害、CNSの神経変性の、変化および障害、情動障害、うつ病、外傷後ストレス障害、並びにストレス、不安、統合失調症、並びに精神異常に関連している疾患、痛み、中毒、多発性硬化症、癲癇、神経膠腫等の、グルタミン酸作動性神経伝達物質系の不均衡に関連している神経精神医学的障害を処置するための医薬としてのその使用、並びに上記化合物を含んでいる医薬組成物を提供する。

7. 发明专利

JP4178030B2 Diamond in microelectronics Ido-containing materials 有权
公开(公告)号：JP4178030B2
公开(公告)日：2008-11-12
申请号：JP2002558328
申请日：2002-01-17
申请人：シェブロンユー.エス.エー. インコーポレイテッド
发明人：カールソン、ロバート、エム , ダール、ジェレミー、イー , リウ、シェンガオ
IPC分类号： H01L23/373 , C07C4/00 , C07C7/04 , C07C7/12 , C07C7/135 , C07C13/64 , C07C17/10 , C07C17/16 , C07C17/383 , C07C17/395 , C07C23/20 , C07C47/347 , C07C49/423 , C07C205/05 , C08G61/00 , C08G61/02 , C08G83/00 , C08L65/00
CPC分类号： H01J1/3048 , B82Y10/00 , B82Y30/00 , C07C4/00 , C07C7/04 , C07C7/12 , C07C7/135 , C07C13/64 , C07C17/10 , C07C17/16 , C07C17/383 , C07C17/395 , C07C23/20 , C07C47/347 , C07C49/423 , C07C205/05 , C07C2603/90 , C08G61/00 , C08G61/02 , C08G83/00 , C08L65/00 , H01J2201/30457 , H01L2224/48091 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
摘要： Novel uses of diamondoid-containing materials in the field of microelectronics are disclosed. Embodiments include, but are not limited to, thermally conductive films in integrated circuit packaging, low-k dielectric layers in integrated circuit multilevel interconnects, thermally conductive adhesive films, thermally conductive films in thermoelectric cooling devices, passivation films for integrated circuit devices (ICs), and field emission cathodes. The diamondoids employed in the present invention may be selected from lower diamondoids, as well as the newly provided higher diamondoids, including substituted and unsubstituted diamondoids. The higher diamondoids include tetramantane, pentamantane, hexamantane, heptamantane, octamantane, nonamantane, decamantane, and undecamantane. The diamondoid-containing material may be fabricated as a diamondoid-containing polymer, a diamondoid-containing sintered ceramic, a diamondoid ceramic composite, a CVD diamondoid film, a self-assembled diamondoid film, and a diamondoid-fullerene composite.

8. 发明专利

JP3079224B2 失效
公开(公告)号：JP3079224B2
公开(公告)日：2000-08-21
申请号：JP8297898
申请日：1998-03-13
IPC分类号： B01J31/22 , C07B61/00 , C07C27/12 , C07C29/50 , C07C35/08 , C07C45/33 , C07C45/79 , C07C49/403 , C07C49/413 , C07C49/423 , C07C49/443

9. 发明专利

JP2717023B2 失效
公开(公告)号：JP2717023B2
公开(公告)日：1998-02-18
申请号：JP50416390
申请日：1990-02-28
IPC分类号： B01J27/128 , B01J31/12 , C07B61/00 , C07C46/00 , C07C49/423 , C07C49/727 , C07C50/36 , C07C50/38

10. 发明专利

JPS5210252A PREPARATION OF TETRACYCLO*7*3*1*02*5*05* 10* TRIDECANN33ONES 失效
公开(公告)号：JPS5210252A
公开(公告)日：1977-01-26
申请号：JP8514175
申请日：1975-07-11
申请人： KAO CORP
发明人： INAMOTO YOSHIAKI , FUJIKURA YOSHIAKI , IKEDA HIROSHI , TAKAISHI NAOTAKE
IPC分类号： A61K31/12 , C07C45/00 , C07C49/423 , C07C49/617 , C07C67/00 , C11B9/00
摘要： PURPOSE:Tetracyclo [7,3,1,0 ' , 0 ' ] tridecan-3-one or 4,4-diphenyl deri derivative thereof of formula I (R is H, phenyl).

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