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1. 发明专利

JP2007151433A Method for pretreatment of lignocellulose and method for producing ethanol 审中-公开
标题翻译：纤维素纤维素预处理方法及生产乙醇的方法
公开(公告)号：JP2007151433A
公开(公告)日：2007-06-21
申请号：JP2005348982
申请日：2005-12-02
申请人： Tsukishima Kikai Co Ltd , 月島機械株式会社
发明人： OKUDA NAOYUKI , ONO YUICHI , SUZUKI KENJI , HAYAKAWA TOMOMOTO
IPC分类号： C12P19/14 , C12P7/10 , C12P19/02
CPC分类号： Y02E50/16
摘要： PROBLEM TO BE SOLVED: To provide a method for pretreatment of lignocellulose for obtaining a syrup enabling efficient ethanol fermentation at low cost using a lignocellulose-containing feedstock such as waste construction materials, and to provide a method for producing ethanol.
SOLUTION: The method for the pretreatment of lignocellulose comprises the following process: A lignocellulose-containing feedstock is subjected to hydrolysis treatment in dilute sulfuric acid at 140-220°C for 3-20 min, the resultant hydrolyzate is subjected to solid/liquid separation into a primary syrup and a solid. The solid is incorporated with 0.5-20 mass% of quicklime on a dry basis heated at 90-200°C for 10-120 min to have calcification. Subsequently, cellulase is added to the resulting reaction product to be subjected to an enzymatic hydrolysis treatment to obtain a secondary syrup.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种木质纤维素的预处理方法以获得可以使用含有木质素纤维素的原料如废建筑材料以低成本进行有效的乙醇发酵的糖浆，并提供生产乙醇的方法。解决方案：用于木质纤维素预处理的方法包括以下方法：将含木素纤维素的原料在140-220℃的稀硫酸中进行水解处理3-20分钟，所得水解产物经固体 /液体分离成初级糖浆和固体。在干燥的基础上加入0.5-20质量％的生石灰，加热到90-200℃，持续10-120分钟，使钙化。随后，将所得反应产物加入纤维素酶进行酶水解处理，得到二次浆。版权所有（C）2007，JPO＆INPIT

2. 发明专利

JP2007124933A Pretreatment method of lignocellulose 审中-公开
标题翻译：纤维素的预处理方法
公开(公告)号：JP2007124933A
公开(公告)日：2007-05-24
申请号：JP2005319536
申请日：2005-11-02
申请人： Tsukishima Kikai Co Ltd , 月島機械株式会社
发明人： OKUDA NAOYUKI , ONO YUICHI , SUZUKI KENJI , HAYAKAWA TOMOMOTO
IPC分类号： C12P7/08
摘要： PROBLEM TO BE SOLVED: To provide a pretreatment method of lignocellulose which is used when enzymically hydrolyzing a lignocellulose raw material, and by which the treatment can be carried out at a low cost while keeping input energy low, and a sugar can be obtained at a low cost in good yield by suppressing the excess degradation of the sugar. SOLUTION: The pretreatment method of the lignocellulose by enzymic hydrolysis comprises an acid-treating step for subjecting the lignocellulose raw material to acid treatment, a neutralizing step for neutralizing the reaction product of the acid-treating step, and a pulverizing step for subjecting the reaction product of the neutralizing step to wet pulverization treatment. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：提供一种木质纤维素的预处理方法，其在酶水解木素纤维素原料时使用，并且可以以低成本进行处理，同时保持输入能量较低，并且糖可以通过抑制糖的过量降解，以低成本获得良好的产率。解决方案：通过酶水解的木质纤维素的预处理方法包括使木素纤维素原料进行酸处理的酸处理步骤，中和酸处理步骤的反应产物的中和步骤和用于对中和步骤的反应产物进行湿式粉碎处理。版权所有（C）2007，JPO＆INPIT

3. 发明专利

JP2006281037A Continuously-feedable reaction apparatus and method thereof 有权
标题翻译：连续反应反应装置及其方法
公开(公告)号：JP2006281037A
公开(公告)日：2006-10-19
申请号：JP2005101890
申请日：2005-03-31
申请人： Tsukishima Kikai Co Ltd , 月島機械株式会社
发明人： HAYAKAWA TOMOMOTO , ONO YUICHI , SUZUKI KENJI
IPC分类号： B01J4/00 , C13K1/02
摘要： PROBLEM TO BE SOLVED: To provide a continuously-feedable reaction apparatus which is provided with a reactor and a feeder for continuously feeding a raw material consisting of liquid content and solid content to the reactor while removing the liquid content and in which the yield of a reaction product is restrained from being decreased owing to fluctuations of the liquid content of the raw material to be fed to stabilize the yield of the reaction product.
SOLUTION: Woody biomass such as a wood chip (including waste building material) is thrown in an agitation tank 1 together with excess amount of dilute sulfuric acid and mixed with dilute sulfuric acid. The liquid content of the obtained mixture is removed by a belt filter 2. The liquid content-removed mixture is thrown in the reactor 5 through a material-sealed screw feeder 4. A saccharide is produced by hydrolyzing woody biomass in the mixture by using dilute sulfuric acid as a catalyst while replenishing dilute sulfuric acid and keeping the temperature of the reactor by steam. The current of a motor 4m of the feeder 4 is detected by a detector 4d. The amount (concentration) of the sulfuric acid-containing liquid content of the raw materials to be thrown in the reactor is calculated in an arithmetic controller 6 by using the correlation between the current detected by the detector and the liquid content. A shortage is calculated by subtracting the calculated amount (concentration) of the sulfuric acid-containing liquid content from the amount (concentration) of sulfuric acid to be required to advance a hydrolysis reaction. The calculated shortage is supplied to the reactor 5 by controlling the opening degree of a sulfuric acid supply valve 7.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种可连续供给的反应装置，其具有反应器和进料器，用于在除去液体内容物的同时，将由液体含量和固含量组成的原料连续地供给反应器，其中由于待进料的原料的液体含量的波动，反应产物的产率被抑制，以稳定反应产物的产率。解决方案：将木质生物质如木屑（包括废建筑材料）与过量的稀硫酸一起投入搅拌槽1中并与稀硫酸混合。通过带式过滤器2除去所获得的混合物的液体含量。通过材料密封的螺旋进料器4将含有液体的物质排出的混合物投入反应器5中。通过使用稀释剂水解混合物中的木质生物质来生产糖硫酸作为催化剂，同时补充稀硫酸并通过蒸汽保持反应器的温度。进料器4的马达4m的电流由检测器4d检测。通过使用由检测器检测的电流与液体含量之间的相关性，在运算控制器6中计算要投入反应器中的原料的含硫酸液体含量的量（浓度）。通过从推进水解反应所需的硫酸量（浓度）中减去计算含硫酸液体含量的量（浓度）来计算短缺。通过控制硫酸供给阀7的开度，将计算出的短缺供给反应器5.（C）2007，JPO＆INPIT

4. 发明专利

JP2007104983A Pretreatment method of lignocellulose 有权
标题翻译：纤维素的预处理方法
公开(公告)号：JP2007104983A
公开(公告)日：2007-04-26
申请号：JP2005299883
申请日：2005-10-14
申请人： Tsukishima Kikai Co Ltd , 月島機械株式会社
发明人： OKUDA NAOYUKI , ONO YUICHI , SUZUKI KENJI , HAYAKAWA TOMOMOTO
IPC分类号： C13K1/02 , B27N1/00
摘要： PROBLEM TO BE SOLVED: To provide a pretreatment method for enzymic hydrolysis of a lignocellulose raw material, wherein the pretreatment method for the lignocellulose suppresses overdegradation of a saccharide and obtains the saccharide at a low cost, in good yield, with low power consumption and efficiently.
SOLUTION: The pretreatment method for enzymic hydrolysis of lignocellulose comprises: an acid treating step for treating the lignocellulose raw material with an acid; a solid-liquid separation step for carrying out the solid-liquid separation of the reaction product of the acid treating step; and a pulverization treatment step for subjecting the residue of the solid-liquid separation step to pulverization treatment with a beater.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：提供一种用于木质纤维素原料的酶水解的预处理方法，其中木质纤维素的预处理方法抑制糖的过度降解，以低成本，低成本，低收率地获得糖类消费高效。解决方案：木质纤维素酶水解的预处理方法包括：用酸处理木质纤维素原料的酸处理步骤; 用于进行酸处理步骤的反应产物的固液分离的固液分离步骤; 以及粉碎处理步骤，用搅拌器将固液分离步骤的残渣进行粉碎处理。版权所有（C）2007，JPO＆INPIT

5. 发明专利

JP2006068606A Treatments equipment of liquid-containing solid 有权
标题翻译：含液固体处理设备
公开(公告)号：JP2006068606A
公开(公告)日：2006-03-16
申请号：JP2004253162
申请日：2004-08-31
申请人： Tsukishima Kikai Co Ltd , 月島機械株式会社
发明人： HAYAKAWA TOMOMOTO , SUZUKI KENJI , INUI KENJI , KONDO SOICHIRO
IPC分类号： B01J4/00 , C13K1/02
CPC分类号： Y02W30/78
摘要： PROBLEM TO BE SOLVED: To provide treatment equipment of a liquid-containing solid to prevent the blocking in the treatment equipment. SOLUTION: In feeding the liquid-containing solid discharged from the funnel-shaped discharge part 6 of a reactor 3 to a solid-liquid separator 8 through a pipe 7 to subject it to solid-liquid separation, a part of the liquid component formed by the solid-liquid separation is supplied into the funnel-shaped discharge part 6 through a return passage 9. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供含液固体的治疗设备以防止治疗设备中的阻塞。解决方案：将从反应器3的漏斗状排出部分6排出的含液固体通过管7送入固液分离器8，使其进行固液分离，一部分液体通过固液分离形成的组分通过返回通道9供应到漏斗形排出部分6中。（C）2006，JPO＆NCIPI

6. 发明专利

JP2012000022A Biomass processing device and method 有权
标题翻译：生物量处理装置及方法
公开(公告)号：JP2012000022A
公开(公告)日：2012-01-05
申请号：JP2010135836
申请日：2010-06-15
申请人： Tsukishima Kikai Co Ltd , 月島機械株式会社
发明人： HAYAKAWA TOMOMOTO , SATO MASANORI , SUZUKI KENJI , TAKEMORI SHINYA
IPC分类号： C13K1/02 , C12M1/00 , C12P19/14
CPC分类号： C12M45/20
摘要： PROBLEM TO BE SOLVED: To reduce carbonization of materials in a heat-treating apparatus which performs hydrolysis of biomass or pretreatment of enzymatic saccharification and its blocking with carbonized materials.SOLUTION: The heat-treating apparatus for biomass is provided with conveying means 11A and 11B and liquid projection means 21 in a heat-treating tank 10. The biomass supplied to the heat-treating tank 10 is conveyed under heating condition. Meanwhile, the liquid projection means 21 project projection liquid (water or sugar solution) toward the conveying means 11.

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