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    • 1. 发明专利
    • Chemical thermal storage air-conditioning system
    • 化学热储存空调系统
    • JP2014180979A
    • 2014-09-29
    • JP2013057968
    • 2013-03-21
    • Denso Corp株式会社デンソーToyota Central R&D Labs Inc株式会社豊田中央研究所
    • HAYASE TOMOHIROFUSE TAKUYAKOMAKI KATSUYAMITSUI HIROYUKISHIMAZU TAKASHIWAKASUGI TOMOHISAMOCHIZUKI MIYO
    • B60H1/20B60H1/03B60H1/14F28D20/00
    • Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a chemical thermal storage air-conditioning system capable of flexibly responding to both of the case where heat is stored in a chemical thermal storage medium of a reactor by dehydration reaction and the case where heat is released from the chemical thermal storage medium of the reactor by hydration reaction.SOLUTION: A chemical thermal storage air-conditioning system 4 is used in an energy operation device 1 including energy conversion means 2 and energy storage means 3. The chemical thermal storage air-conditioning system 4 includes: a reactor 6 in which a chemical thermal storage medium 61 is incorporated: and air-conditioning piping 5 that accommodates the reactor 6 therein for passing air A. The reactor 6 includes: a first reaction unit 6A enabling dehydration reaction of the chemical thermal storage medium 61 by using exhaust energy X by the energy conversion means 2; and a second reaction unit 6B enabling dehydration reaction of the chemical thermal storage medium 61 by using either of the exhaust energy X or stored energy by the energy storage means 3.
    • 要解决的问题:提供一种能够灵敏地响应于通过脱水反应将热量存储在反应器的化学热存储介质中的情况和从化学品释放热量的情况的化学热存储空调系统 反应器的热存储介质通过水合反应。解决方案:化学热存储空调系统4用于包括能量转换装置2和储能装置3的能量操作装置1中。化学热存储空调系统4包括 :组装有化学蓄热介质61的反应器6和容纳反应器6的空气调节配管5,使空气A通过。反应器6包括:第一反应单元6A,其能够进行化学热存储器的脱水反应 介质61通过能量转换装置2使用废气能量X; 以及第二反应单元6B,其能够通过利用能量存储装置3中的任一种排放能量X或存储的能量来实现化学热存储介质61的脱水反应。
    • 2. 发明专利
    • Reactor
    • 反应堆
    • JP2012220101A
    • 2012-11-12
    • JP2011086229
    • 2011-04-08
    • Toyota Central R&D Labs IncDenso Corp株式会社デンソー株式会社豊田中央研究所
    • SHIMAZU TAKASHIWAKASUGI TOMOHISASAEGUSA HIROSHIFUSE TAKUYA
    • F28D20/00F28F23/00
    • Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a reactor capable of improving performance in water vapor generation.SOLUTION: A first reactor 10 includes a chemical heat storage material 30 which generates water vapor with a reaction heat generated during a reaction with water and stores the heat obtained by separation from water and a heat exchanger 40 which incorporates the chemical heat storage material 30. The heat exchanger 40 includes a heat storage material housing space 42 which houses the chemical heat storage material 30, a water flow path 44 which has a plurality of discharge ports 50 communicating with the heat storage material housing space 42, a main pipe 52 connected with an outside water supply part, and a branch pipe 54 for communicating the main pipe 52 with the plurality of discharge ports 50, and a heat medium flow path 46 which circulates a heat medium for heating the chemical heat storage material 30. The heat storage material housing space 42 is extended in a vertical direction and has a discharge port 48 for discharging the water vapor generated by the chemical heat storage material 30 to the outside at the upper side end in the vertical direction, in which the direction of the water flow supplied to the branch pipe 54 matches the direction of discharging the water vapor from the discharge port 48.
    • 要解决的问题:提供能够提高水蒸气产生性能的反应器。 解决方案:第一反应器10包括化学蓄热材料30,该化学蓄热材料30在与水反应期间产生的反应热产生水蒸汽,并且储存通过与水分离而获得的热量,以及热交换器40,其结合了化学储热 热交换器40包括容纳化学蓄热材料30的蓄热材料容纳空间42,具有与蓄热材料容纳空间42连通的多个排出口50的水流路44,主管 52与外部供水部分连接,以及用于使主管52与多个排出口50连通的分支管54,以及使用于加热化学蓄热材料30的热介质循环的热介质流路46。 蓄热材料容纳空间42沿垂直方向延伸,并且具有用于排出由化学热存储器产生的水蒸汽的排出口48 e材料30在垂直方向上的上侧端部的外侧,其中供给到分支管54的水流的方向与从排出口48排出水蒸气的方向一致。COPYRIGHT :(( C)2013,JPO&INPIT
    • 3. 发明专利
    • Air-conditioning system
    • 空调系统
    • JP2014180978A
    • 2014-09-29
    • JP2013057967
    • 2013-03-21
    • Denso Corp株式会社デンソーToyota Central R&D Labs Inc株式会社豊田中央研究所
    • OKAMURA TORUFUSE TAKUYAKOMAKI KATSUYAMOCHIZUKI MIYOSHIMAZU TAKASHIWAKASUGI TOMOHISAMITSUI HIROYUKI
    • B60H1/20B60H1/08F24F3/14F24F6/04
    • PROBLEM TO BE SOLVED: To provide an air-conditioning system that can efficiently control indoor humidity while sufficiently and effectively using heat generated from a chemical thermal storage device.SOLUTION: An air-conditioning system 1 is used for performing at least one of heating or cooling of an indoor space 4. The air-conditioning system 1 comprises: a chemical thermal storage device 2 for performing at least one of heating and cooling of air-conditioning air; and a humidity control device 3 for dehumidifying the air-conditioning air. The chemical thermal storage device 2 comprises: a reactor 21 that is constituted by filling a thermal storage medium generating heat by hydration reaction and storing heat by dehydration reaction; an evaporator 22 for generating steam supplied to the reactor 21; and a condenser 23 for condensing the steam obtained by dehydration in the reactor 21. The humidity control device 3 is operable by using heat. The air-conditioning system 1 is configured to use part of heat generated from the chemical thermal storage device 2 as driving energy of the humidity control device 3.
    • 要解决的问题:提供一种能够有效地控制室内湿度的空调系统,同时充分有效地使用由化学蓄热装置产生的热量。解决方案:空调系统1用于执行加热或 室内空间的冷却4.空调系统1包括:化学蓄热装置2,用于进行空调空气的加热和冷却中的至少一个; 以及用于对空调空气进行除湿的湿度调节装置3。 化学蓄热装置2包括:反应器21,其通过填充通过水合反应产生热并通过脱水反应储存热量的蓄热介质; 用于产生供应到反应器21的蒸汽的蒸发器22; 以及用于冷凝通过反应器21中的脱水获得的蒸汽的冷凝器23.湿度控制装置3可通过使用热量进行操作。 空调系统1被构造成使用从化学蓄热装置2产生的热量的一部分作为调湿装置3的驱动能量。
    • 4. 发明专利
    • Chemical heat pump
    • 化学热泵
    • JP2013113565A
    • 2013-06-10
    • JP2011262849
    • 2011-11-30
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所Denso Corp株式会社デンソー
    • WAKASUGI TOMOHISASHIMAZU TAKASHISAEGUSA HIROSHIKUWAYAMA KAZUTOSHIFUSE TAKUYANAKAGAWA TADAHIROKOMAKI KATSUYA
    • F25B17/08
    • Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a chemical heat pump allowing the progress of a chemical reaction even if no supply of heat from the outside and reducing a loss of reaction heat generated by the chemical reaction.SOLUTION: The chemical heat pump 10 includes a reactor 12 storing a chemical reaction material, and including a heat recovery apparatus 26 recovering reaction heat generated by the chemical reaction of the chemical reaction material, and a regenerating heat source 16 for returning the chemical reaction material after the chemical reaction into its original state; a medium storage container 14 storing a reaction medium for reacting on the chemical reaction material; and a communicating pipe 20 connecting the medium storage container 14 to the heat recovery apparatus 26 through a medium transporting means 22 for transporting the reaction medium in the medium storage container 14 to the reactor 12, and a flow regulating means 24 for regulating the flow of the reaction medium transported from the medium storage container 14 to the reactor 12, and connecting the heat recovery apparatus 26 to the reactor 12 through an external heat exchanger 28 supplying heat recovered by the heat recovery apparatus 26, to the outside.
    • 要解决的问题:即使没有从外部供应热量并且减少由化学反应产生的反应热的损失,提供允许化学反应进行的化学热泵。 解决方案:化学热泵10包括存储化学反应材料的反应器12,并且包括回收由化学反应材料的化学反应产生的反应热的热回收装置26和再生热源16 化学反应物质化学反应进入其原始状态; 存储用于对化学反应材料发生反应的反应介质的介质储存容器14; 以及连通管20,其通过用于将介质储存容器14中的反应介质输送到反应器12的介质输送装置22将介质储存容器14连接到热回收装置26;以及流量调节装置24, 反应介质从介质储存容器14输送到反应器12,并且通过供给由热回收装置26回收的热量的外部热交换器28将热回收装置26连接到反应器12到外部。 版权所有(C)2013,JPO&INPIT
    • 5. 发明专利
    • Reactor for chemical heat storage
    • 化学储热反应器
    • JP2013113564A
    • 2013-06-10
    • JP2011262847
    • 2011-11-30
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所Denso Corp株式会社デンソー
    • WAKASUGI TOMOHISASHIMAZU TAKASHIKOMAKI KATSUYAKUWAYAMA KAZUTOSHIFUSE TAKUYANAKAGAWA TADAHIROSAEGUSA HIROSHI
    • F28D20/00
    • Y02E60/142
    • PROBLEM TO BE SOLVED: To improve heat conduction/cutoff performance between a heater layer and a heat storage layer during hydration reaction, and a heat transfer promotion function between the heater layer and the heat storage layer during dehydration reaction.SOLUTION: A reactor 100 for chemical heat storage includes: a heat storage layer 110 filled with a chemical heat storage material storing heat through dehydration reaction by heating and radiating heat through hydration reaction; a heater layer 150 converting electric energy into thermal energy and heating the heat storage layer 110 during the dehydration reaction; and a heat transmission partition wall 104 making a partition between the heater layer 150 and heat storage layer 110, having a smaller coefficient of linear expansion than that of the heater layer 150, having a gap formed with the heater layer 150 during the hydration reaction, and coming into contact by thermal expansion of the heater layer 150 during the dehydration reaction, and thereby transmitting the heat of the heater layer 150 to the heat storage layer 110.
    • 要解决的问题:提高水合反应期间加热器层和储热层之间的热传导/截止性能,以及脱水反应期间加热器层和储热层之间的传热促进功能。 解决方案:用于化学蓄热的反应器100包括:储热层110,填充有通过加热和通过水合反应辐射热而通过脱水反应储存热量的化学蓄热材料; 在脱水反应期间将电能转换为热能并加热蓄热层110的加热器层150; 以及在水合反应期间具有与加热层150形成的间隙的在加热器层150和蓄热层110之间形成隔板的传热分隔壁104,其具有比加热器层150更小的线性膨胀系数, 并且在脱水反应期间通过加热层150的热膨胀而接触,从而将加热器层150的热量传递到储热层110.版权所有(C)2013,JPO&INPIT
    • 6. 发明专利
    • 化学蓄熱装置
    • 化学储热装置
    • JP2014206363A
    • 2014-10-30
    • JP2013231652
    • 2013-11-08
    • 株式会社デンソーDenso Corp株式会社豊田中央研究所Toyota Central R&D Labs Inc
    • OKAMURA TORUIMAMURA TOMONORIKOMAKI KATSUYAFUSE TAKUYAKUWAYAMA KAZUTOSHIWAKASUGI TOMOHISASHIMAZU TAKASHIMOCHIZUKI MIYOMITSUI HIROYUKI
    • F28D20/00
    • Y02E60/142
    • 【課題】目標とする反応率を得るための時間を早くすることができ、COPの低下を抑制可能な化学蓄熱装置を提供する。【解決手段】化学蓄熱装置1は、流体状態の反応媒体20が器内に流入、器外に流出可能に構成され、反応媒体20と可逆的な熱化学反応を生じさせる反応物21と、器内外との間で熱を授受可能な熱交換部22とを備えた反応器2を有する。化学蓄熱装置1は、反応器2内に流入した反応媒体20と反応物21との反応により化合物を生成させる発熱反応の反応熱を反応器2外に放出する放熱モードと、反応器2外から供給された熱にて化合物を反応媒体20と反応物21とに分解する吸熱反応による反応媒体20を反応器2外に流出させる蓄熱モードとを動作可能である。化学蓄熱装置1は、放熱モードの発熱反応及び/又は蓄熱モードの吸熱反応の反応速度を制御するよう構成されている。【選択図】図2
    • 要解决的问题:提供一种能够缩短获得目标反应速度所需时间并抑制COP降解的化学蓄热装置。解决方案:化学蓄热装置1包括构造成能够流动的反应器2 反应器2中的流体状态的反应介质20,其包括反应物21,其与反应性介质20产生可逆的热化学反应,热交换器22向反应器2的外部转移和接收热量 化学蓄热装置1可以以放热模式工作,其中通过流入反应器2的反应介质20和反应物21之间的反应产生化合物的放热反应的热反应热到 反应器2或储热模式,其中通过用于将化合物分解成反应性介质的吸热反应使反应性介质20从反应器2流出 20和反应物21通过从反应器2的外部供应的热量。化学蓄热装置1被配置为控制放热模式中的放热反应和/或热量中的吸热反应的反应速度 存储模式。
    • 7. 发明专利
    • Chemical thermal storage air-conditioning system
    • 化学热储存空调系统
    • JP2014180980A
    • 2014-09-29
    • JP2013057969
    • 2013-03-21
    • Denso Corp株式会社デンソーToyota Central R&D Labs Inc株式会社豊田中央研究所
    • AKITA KENJIKOMAKI KATSUYAGOTO YOSUKEKUWAYAMA KAZUTOSHIWAKASUGI TOMOHISASHIMAZU TAKASHIMITSUI HIROYUKIMOCHIZUKI MIYO
    • B60H1/08C09K5/16F25B17/08F25B27/02F28D20/00
    • Y02A30/274Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a chemical thermal storage air-conditioning system that enables indoor air-conditioning by an extremely simple configuration using a reactor having a built-in chemical thermal storage medium and evaporation/condensation means.SOLUTION: A chemical thermal storage air-conditioning system 1 comprises: a reactor 3 having a built-in chemical thermal storage medium 31; evaporation/condensation means 4 for evaporating water W used for hydration reaction of the chemical thermal storage medium 31 and condensing water W generated by dehydration reaction of the chemical thermal storage medium 31; and air-conditioning piping 2 through which air A coming into contact with at least one of the reactor 3 and the evaporation/condensation means 4 passes. In the chemical thermal storage air-conditioning system 1, the evaporation/condensation means 4 is made to function as an evaporator 41, and when water W evaporated by the evaporator 41 is supplied to the reactor 3, the air A passing through the air-conditioning piping 2 is heated or cooled by using at least one of heat generated during the hydration reaction of the chemical thermal storage medium 31 and heat deprived of by the evaporation/condensation means 4 during the hydration reaction, so as to perform air-conditioning.
    • 要解决的问题:提供一种化学热存储空调系统,其使用具有内置化学热存储介质和蒸发/冷凝装置的反应器,通过非常简单的配置实现室内空调。解决方案:化学热存储 空调系统1包括:具有内置化学蓄热介质31的反应器3; 用于蒸发水的蒸发/冷凝装置4,用于化学热存储介质31的水合反应和由化学热存储介质31的脱水反应产生的冷凝水W; 空气A与反应器3和蒸发/冷凝装置4中的至少一个接触的空调管路2通过。 在化学热存储空调系统1中,使蒸发/冷凝装置4用作蒸发器41,并且当通过蒸发器41蒸发的水W被供应到反应器3时,通过空气 - 通过在水合反应期间使用在化学蓄热介质31的水合反应期间产生的热量和被蒸发/冷凝装置4剥夺的热量中的至少一种来加热或冷却调节管道2,从而进行空气调节。
    • 8. 发明专利
    • Chemical heat accumulation system for vehicle and air conditioning system provided with the same
    • 用于车辆和空调系统的化学热量累积系统
    • JP2013112310A
    • 2013-06-10
    • JP2011262848
    • 2011-11-30
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所Denso Corp株式会社デンソー
    • WAKASUGI TOMOHISASHIMAZU TAKASHIKOMAKI KATSUYAKUWAYAMA KAZUTOSHIFUSE TAKUYANAKAGAWA TADAHIROSAEGUSA HIROSHI
    • B60H1/08B60H1/20F28D20/00
    • Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a chemical heat accumulation system for vehicle which can be used as a heat source of an air conditioning system for vehicle and an air conditioning system for vehicle provided with the same.SOLUTION: A chemical heat accumulation system 60 for vehicle includes a reactor 62, a condenser 80, an evaporator 90, and a water tank 100. In a container 64 of the reactor 62, there is provided a reaction flow passage 64A in which a chemical thermal storage medium 66 is charged. Further, in the container 64 of the reactor 62, there is provided a refrigerant flow passage 64C. A heat emission line 72 is connected to the refrigerant flow passage 64C, and heat exchange is performed between engine cooling water flowing through the heat emission line 72 and the reactor 62. As a result, heat generated along with hydration reaction of the chemical thermal storage medium 66 is emitted into the engine cooling water, so that the engine cooling water is heated. The heated engine cooling water is supplied to a heater core 22, and the heater core 22 performs heat exchange with an air conditioning air flowing through an air conditioning case 32, so that air for air conditioning is heated.
    • 要解决的问题:提供一种可用作车辆空调系统的热源的车辆用化学蓄热系统和具备该车辆的车辆用空调系统。 解决方案:用于车辆的化学热积聚系统60包括反应器62,冷凝器80,蒸发器90和水箱100.在反应器62的容器64中,设置有反应流路64A, 化学热存储介质66被充电。 此外,在反应器62的容器64中设置有制冷剂流路64C。 发热管线72与制冷剂流路64C连接,并且在流过发热管线72的发动机冷却水和反应器62之间进行热交换。结果,与化学热存储器的水合反应一起产生的热量 介质66被排放到发动机冷却水中,使得发动机冷却水被加热。 加热的发动机冷却水被供给到加热器芯22,并且加热器芯22与流过空调壳体32的空调空气进行热交换,从而加热用于空调的空气。 版权所有(C)2013,JPO&INPIT
    • 9. 发明专利
    • Chemical heat accumulator
    • 化学热收缩剂
    • JP2012215324A
    • 2012-11-08
    • JP2011079727
    • 2011-03-31
    • Toyota Central R&D Labs IncDenso Corp株式会社デンソー株式会社豊田中央研究所
    • SHIMAZU TAKASHIWAKASUGI TOMOHISAMITSUI HIROYUKISOFUGAWA HIDEOKOMAKI KATSUYASAEGUSA HIROSHINAKAGAWA TADAHIRO
    • F28D20/00C09K5/16F01N3/20F01N3/24F01N3/28
    • F28D20/003Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a chemical heat accumulator can not only generate high temperatures but also suppress the internal pressure of a sealing system low and be downsized.SOLUTION: A chemical heat accumulator 10 includes: a receptacle 12 which pools water; a first reaction vessel 14 integrating a chemical heat accumulation material 34 connected to the receptacle 12 in a sealed state to not only supply water from the receptacle 12 but also react with the water supplied from the receptacle 12 to generate steam by the heat of reaction and generate a dehydration reaction by heating; a second reaction vessel 16 integrating a chemical heat storage material 44 connected to the first reaction vessel 14 under the sealed status to not only supply steam from the first reaction vessel 14 but also generate heat by generating a hydration reaction by the steam supplied from first reaction vessel 14, store the heat by generating a dehydration reaction by heating, and thermally contact with a catalyst 46; and a condenser 18 connected to the second reaction vessel 16 in the sealed state not only to supply the steam generated from the second reaction vessel 16 in association with the dehydration reaction to condense the steam supplied from the second reaction vessel 16.
    • 要解决的问题:提供化学蓄热器不仅可以产生高温,而且可以抑制密封系统的内部压力低并且被小型化。 解决方案:化学蓄热器10包括:容器12,其收集水; 第一反应容器14将密封状态下连接到容器12的化学蓄热材料34整合,不仅从容器12供给水,而且与从容器12供应的水反应,以通过反应热产生蒸汽, 通过加热产生脱水反应; 在密封状态下将与第一反应容器14连接的化学蓄热材料44整合在一起的第二反应容器16不仅能够从第一反应容器14供给蒸汽,而且还通过由第一反应供给的蒸汽产生水化反应而产生热量 容器14通过加热产生脱水反应并与催化剂46热接触来储存热量; 以及在密封状态下连接到第二反应容器16的冷凝器18,不仅能够提供与脱水反应相关联的从第二反应容器16产生的蒸汽,以冷凝从第二反应容器16供应的蒸汽。 (C)2013,JPO&INPIT
    • 10. 发明专利
    • Chemical thermal storage system
    • 化学储热系统
    • JP2014181879A
    • 2014-09-29
    • JP2013057966
    • 2013-03-21
    • Denso Corp株式会社デンソーToyota Central R&D Labs Inc株式会社豊田中央研究所
    • KOMAKI KATSUYAAKITA KENJIGOTO YOSUKEWAKASUGI TOMOHISASHIMAZU TAKASHIMITSUI HIROYUKIMOCHIZUKI MIYO
    • F28D20/00F02G5/02
    • F28D20/003Y02E20/14Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a chemical heat storage system capable of improving heat utilization rate more than heretofore.SOLUTION: A chemical heat storage system 1 comprises: a reactor 11 filled with a chemical heat storage substance capable of reversibly performing hydration reaction and dehydration reaction; an evaporation condenser 12 configured such that steam to be used for hydration reaction of the chemical heat storage substance can be generated and steam generated by dehydration reaction of the hydrated chemical heat storage substance can be condensed; a communication path 13 for communicating the reactor 11 and the evaporation condenser 12 and circulating steam; and a flow rate adjusting means 14 which is disposed on the communication path 13 and adjusts flow rate of steam circulated within the communication path 13. The chemical heat storage system 1 is configured such that reaction heat accompanied by hydration reaction of the chemical heat storage substance in the reactor 11 and evaporation latent heat accompanied by generation of steam in the evaporation condenser 12 can be recovered and is configured such that a part or all of recovered reaction heat can be heat-exchanged with a portion 2 of a system outer part.
    • 要解决的问题:提供一种能够比迄今为止提高热利用率的化学蓄热系统。解决方案:化学蓄热系统1包括:填充有能够可逆地进行水合反应和脱水的化学蓄热物质的反应器11 反应; 蒸发冷凝器12构成为能够产生用于化学蓄热物质的水合反应的蒸汽,并且可以冷凝由水合化学蓄热物质脱水反应而产生的蒸汽; 用于连通反应器11和蒸发冷凝器12以及循环蒸汽的连通路径13; 以及流量调节装置14,其设置在连通路径13上并调节在连通路径13内循环的蒸汽的流量。化学蓄热系统1构造成使得伴随着化学储热物质的水合反应的反应热 在反应器11中,蒸发冷凝器12中伴随蒸汽产生的蒸发潜热可以被回收,并且被构造成使得回收的反应热的一部分或全部可以与系统外部的部分2进行热交换。