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    • 1. 发明专利
    • Formation of conductor circuit by electroless silver plating
    • 通过电镀银镀层形成导体电路
    • JPS59129764A
    • 1984-07-26
    • JP513383
    • 1983-01-14
    • Nagase Screen Insatsu Kenkyusho:KkToyobo Co Ltd
    • ABE SHIYUNZOUMIYAKE HIDEO
    • C23C18/44C23C18/42H01L21/205H05K1/09H05K3/24
    • C23C18/42H05K1/095H05K3/245
    • PURPOSE:To form a conductor circuit with high adhesive strength by electroless silver plating by sticking a composition contg. a specified amount of fine copper powder and having specified specific resistance to the surface of an insulator and by selectively depositing silver by electroless plating. CONSTITUTION:A composition contg. 70-95% fine copper powder and a binder as essential components is stuck to the surface of an electrically insulating substance by coating or other method so as to regulate the specific resistance of the stuck composition to >=10 OMEGA.cm. The insulating substance is immersed in an electroless silver plating bath, and silver is selectively deposited to form a conductor circuit. By this method a conductor circuit with superior reliability is obtd.
    • 目的:通过粘附组合物通过无电镀银形成具有高粘合强度的导体电路。 规定量的细铜粉末,并且具有对绝缘体的表面具有特定的电阻率,并且通过无电镀选择性地沉积银。 构成: 70-95%的细铜粉末和作为必需成分的粘合剂通过涂布或其它方法粘附到电绝缘物质的表面上,以将粘着组合物的电阻率调节至> = 10 2欧米加。 将绝缘物质浸入无电镀银浴中,并且选择性地沉积银以形成导体电路。 通过这种方法,可以获得具有优异可靠性的导体电路。
    • 2. 发明专利
    • Amorphous solar battery
    • 非晶太阳能电池
    • JPS594179A
    • 1984-01-10
    • JP11340882
    • 1982-06-30
    • Sharp CorpToyobo Co Ltd
    • YAMAUCHI YUTAKAMATSUNAMI MITSUOKATAYAMA MIKIOMIYAKE HIDEOFUJIMOTO HIROSHI
    • H01L31/04H01L23/28H01L31/0392
    • H01L31/03921Y02E10/50
    • PURPOSE:To reduce the production cost of an amorphous solar battery by covering the front surface of a light receiving surface with a light transmission ultraviolet curable resin layer, thereby enhancing the productivity. CONSTITUTION:An amorphous silicon layer 6 of one or more layers of any of P type region, a true region and an N type region is formed suitably with gas such as monosilane, fluorided silicon, hydrogen, phosphine or diborane by CVD glow discharge on a substrate 5 made of stainless steel, ceramic or glass or the like. Then, a transparent conductive layer 7 made or In2O3, SnO2 or the like is formed in a desired pattern to effectively operate as a photovoltaic unit on the layer 6. Subsequently, a light transmissive ultraviolet ray curable resin 9 is covered wider than the profile of the layer 7 on the layer 7 of the prescribed pattern.
    • 目的:通过用透光性紫外线固化型树脂层覆盖受光面的表面来降低非晶质太阳能电池的制造成本,提高生产率。 构成:通过CVD辉光放电,适当地用诸如单硅烷,氟化硅,氢,膦或乙硼烷的气体形成P型区域,真实区域和N型区域中的任何一个或多个层的非晶硅层6 基板5由不锈钢,陶瓷或玻璃等制成。 然后,以所需的图案形成制成的透明导电层7或In2O3,SnO2等,以在层6上作为光电单元有效地起作用。随后,透光紫外线固化树脂9被覆盖得比 层7上的规定图案的层7。
    • 3. 发明专利
    • Transfer paper for painting to ceramic surface
    • 转印到陶瓷表面
    • JPS5782082A
    • 1982-05-22
    • JP15803280
    • 1980-11-10
    • Toyobo Co Ltd
    • FUJIMOTO HIROSHISUGINO MASAHIROMIYAKE HIDEO
    • B44C1/16B41M3/12B44C1/165B44C1/175
    • PURPOSE: To obtain the titled transfer paper having excellent baking property and superior reproducibility in minute printing by forming a pattern ink layer optically cured with specified ultraviolet curing type ink and a cover coating layer onto a layout sheet.
      CONSTITUTION: The ultraviolet curing type ink is obtained by compounding (C) a 0.01W20wt% photosensitizer (such as benzoin methylether) and (D) a 40W 70wt% pigment for china-painting to ceramics (such as magnesia) to a mixture of (A) a 90W20wt% polymerizing compound (such as styrene) and (B) a 10W 80wt% saturated copolymerizing polyester having 1,000W15,000 molecular weight soluble to the component A. Said ultraviolet curing type ink is printed onto the layout sheet in a pattern form and ultraviolet rays are irradiated, the ink is cured and the pattern ink layer is shaped, ultraviolet curing type resin consisting of (meth) acrylate ester group resin, the component A and the component C are printed on a pattern ultraviolet rays are irradiated and the resin is cured, and the overcoating layer is formed.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:通过将特定的紫外线固化型油墨和覆盖层光学固化的图案油墨层形成到布局板上,获得具有优异的烘烤性能和优异的再现性的标题转印纸。 构成:通过将(C)0.01-20重量%的光敏剂(例如苯偶姻甲醚)和(D)40-70重量%的中国涂料用陶瓷(例如氧化镁)的颜料混合到混合物中,得到紫外线固化型油墨 的(A)90-20重量%的聚合化合物(如苯乙烯)和(B)10至80重量%的饱和的共聚聚酯,其分子量为1000-15,000,可溶于组分A.所述紫外线固化型油墨印刷到布局上 照射图案形式的紫外线和紫外线,油墨固化并且图案油墨层成形,由(甲基)丙烯酸酯基树脂,组分A和组分C组成的紫外线固化型树脂印刷在图案紫外线 照射光线,树脂固化,形成外涂层。
    • 4. 发明专利
    • Ultraviolet curing coating resin composition having improved solvent resistance and adhesive property
    • 具有改善耐溶剂性和粘合性的ULTRAVIOLET固化涂料组合物
    • JPS5753572A
    • 1982-03-30
    • JP12892780
    • 1980-09-16
    • Toyobo Co Ltd
    • FUJIMOTO HIROSHISUGINO MASAHIROMIYAKE HIDEO
    • C08F2/00C08F2/48C08F20/00C08F20/10C08F20/20C08F283/00C08F283/02C08F290/00C08F299/00C09D4/00C09D5/00C09D11/00C09D11/10
    • PURPOSE: The titled composition, consisting of a specific polymerizable compound, a saturated copolyester and a photosensitizer, and capable of giving a coating film with improved adhesive property and solvent resistance.
      CONSTITUTION: A composition consisting of (A) a saturated copolyester, soluble in a polymerizable compound (component B), and having a molecular weight of 1,000W15,000, (B) the polymerizable compound and (C) a photosensitizer at a weight ratio between the components (A) and (B) of 20/80W70/30. 20mol% or more saturated polyfunctional carboxylic acid component in the component (A) is an aromatic carboxylic acid, and at least one of the polyhydric alcohol component in the copolyester (A) is ethylene glycol. The component (B) consists of (a) 10W 75wt%, based on the total weight of the component (B), monofunctional (meth) acrylate, (b) 5W50wt% bi- or polyfunctional (meth)acrylate having a molecular weight
    • 目的:由特定的可聚合化合物,饱和共聚酯和光敏剂组成的标题组合物,并且能够提供具有改善的粘合性能和耐溶剂性的涂膜。 构成:由(A)可溶于可聚合化合物(组分B)的饱和共聚酯,分子量为1,000-15,000,(B)可聚合化合物和(C)光敏剂组成的组合物,其重量比为 20 / 80-70 / 30的组分(A)和(B)。 组分(A)中的20mol%或更多饱和的多官能羧酸组分是芳族羧酸,共聚酯(A)中的至少一种多元醇组分是乙二醇。 基于组分(B),单官能(甲基)丙烯酸酯,(b)5-50重量%的双(或多官能)(甲基)丙烯酸酯的总重量,组分(B)由(a)10-75重量% 分子量<500和(c)20-70wt%分子量> 500的双官能(甲基)丙烯酸酯。
    • 5. 发明专利
    • Strippable coating material
    • 可剥涂层材料
    • JPS5744679A
    • 1982-03-13
    • JP12008280
    • 1980-08-29
    • Toyobo Co Ltd
    • KODERA NOBUKAZUMIZUMURA YUTAKAMIYAKE HIDEO
    • C09D5/20C08G63/68C09D167/00C09D175/06
    • PURPOSE: A strippable coating material containing a specific polyester resin, polyurethane resin and water, and having a suitable adhesivity to a surface, e.g., metal, and strippable completely and readily on removal thereof.
      CONSTITUTION: A coating material, consisting of (A) 5W60pts.wt. resin, having a molecular weifht ≥8,000, and selected from (a) a polyester resin consisting of an aromatic dicarboxylic acid e.g. sulfoterephthalic acid, containing 0.5W50mol% metallic salt groups of sulfonic acid in the polycarboxylic acid component and/or a polyurethane resin obtained by reacting the polyester resin in the component (a) with a polyisocyanate compound and (B) 67W0pts.wt. organic compound, compatible with water, and having a boiling point of 60W200°C, e.g. isopropanol, and (C) 12W95pts.wt. water as principal components.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:一种可剥离的涂料,其含有特定的聚酯树脂,聚氨酯树脂和水,并且对表面例如金属具有合适的粘合性,并可完全去除并且易于除去。 构成:涂料,由(A)5-60pts.wt。 树脂,其分子量≥8,000,并且选自(a)由芳族二羧酸组成的聚酯树脂,例如 在聚羧酸组分中含有0.5-50mol%的磺酸金属盐基团和/或通过使组分(a)中的聚酯树脂与多异氰酸酯化合物反应获得的聚氨酯树脂的磺基对苯二甲酸酯和(B)67-0pts.wt 。 有机化合物,与水相容,沸点为60-200℃。 异丙醇,(C)12-95pts.wt。 水为主要成分。
    • 6. 发明专利
    • Ultraviolet-curable resin composition having excellent pigment dispersibility and adhesiveness
    • 具有优异色素分散性和粘合性的超紫外线固化树脂组合物
    • JPS5738803A
    • 1982-03-03
    • JP11529580
    • 1980-08-20
    • Toyobo Co Ltd
    • FUJIMOTO HIROSHISUGINO MASAHIROMIYAKE HIDEO
    • C08F2/00C08F2/44C08F2/48C08F2/50C08F283/00C08F283/02C09D5/00
    • PURPOSE: To impart improved pigment dispersibility and enhanced adhesiveness to a saturated copolyester composition, by using a metal sulfonate group-containing aromatic dicarboxylic acid as an acid component of a saturated copolyester.
      CONSTITUTION: Titled resin composition comprises (A) a saturated copolyester, MW 1,000W15,000, soluble in the below-specified component (B), comprising a saturated polycarboxylic acid component consisting of (i) 0W80mol% aliphatic or alicyclic dicarboxylic acid, e.g., succinic acid, (ii) 99.5W19.5mol% metal sulfonate group-free aromatic dicarboxylic acid, e.g., terephthalic acid and (iii) 0.5W20mol% metal sulfonate group-containing aromatic dicarboxylic acid, e.g., 5-sodiosulfoisophthalic acid, and a polyhydric alcohol component, e.g., ethylene glycol, (B) a polymerizable compound component at least part of which has at least two polymerizable double bond, e.g., 1,6-hexanediol diacrylate, and (C) a photosensitizer, e.g., benzoin ethyl ether.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:通过使用含金属磺酸酯基的芳族二羧酸作为饱和共聚酯的酸成分,赋予饱和共聚酯组合物改善的颜料分散性和增强的粘合性。 构成:标题树脂组合物包含(A)可溶于下述规定组分(B)的饱和共聚多酯(MW)1000-15,000,其包含饱和多元羧酸组分,其由(i)0-80mol%脂族或脂环族二羧酸, 例如琥珀酸,(ii)99.5-19.5mol%无金属磺酸盐基团的芳族二羧酸,例如对苯二甲酸和(iii)0.5-20mol%的含金属磺酸盐基团的芳族二羧酸,例如5-硫代磺基间苯二甲酸, 和多元醇组分,例如乙二醇,(B)其至少一部分具有至少两个可聚合双键的可聚合化合物组分,例如1,6-己二醇二丙烯酸酯,和(C)光敏剂,例如苯偶姻 乙醚。
    • 7. 发明专利
    • Sealed ic module or element
    • 密封IC模块或元件
    • JPS6146054A
    • 1986-03-06
    • JP16855784
    • 1984-08-10
    • Toyobo Co Ltd
    • SAKAMOTO JUNICHIMIYAKE HIDEO
    • C08G59/00C08G59/40H01L23/29H01L23/31
    • H01L23/293H01L2924/0002H01L2924/09701H01L2924/00
    • PURPOSE:To seal an IC module and an element in an extremely short time by using a cured type resin composition consisting of an epoxy compound and a photopolymerizable compound, molecules thereof have carboxyl groups. CONSTITUTION:An IC module or an element is sealed by employing a cured type resin composition containing an epoxy compound (A) with two epoxy groups and a photopolymerizable compound (B) with carboxyl groups or a mixture of the compound (B) and another photopolymerizable compound (C). There are a bisphenol A type epoxy compound, a phenol novolac type polyepoxy compound, etc. as preferable compounds in said epoxy compounds (A). There are unsaturated carboxylic acid group compounds, etc., such as acrylic acid, methacrylic acid, etc. as the photopolymerizable compounds (B). The load of the photopolymerizable compound (B) occupying in photopolumerizable compounds consisting of the photopolymerizable compound (B) and another photopolymerizable compound (C) extends over a value such as 10-100wt%.
    • 目的:通过使用由环氧化合物和可光聚合化合物组成的固化型树脂组合物,在极短的时间内密封IC模块和元件,其分子具有羧基。 构成:通过使用含有具有两个环氧基的环氧化合物(A)和具有羧基的光聚合性化合物(B)或化合物(B)和另一种可光聚合的(B)的混合物)的固化型树脂组合物来密封IC模块或元件 化合物(C)。 所述环氧化合物(A)中优选具有双酚A型环氧化合物,酚醛清漆型聚环氧化合物等。 存在不饱和羧酸基化合物等,例如丙烯酸,甲基丙烯酸等作为光聚合性化合物(B)。 占可光聚合化合物(B)和另一种可光聚合化合物(C)的可光聚合化合物中的光聚合性化合物(B)的负载量延伸超过10-100wt%的值。
    • 8. 发明专利
    • Ultraviolet-curable resin composition for coating use
    • 用于涂料使用的超紫外线可固化树脂组合物
    • JPS5922969A
    • 1984-02-06
    • JP13278182
    • 1982-07-28
    • Toyobo Co Ltd
    • FUJIMOTO HIROSHINAKAO TOMOHIKOMIYAKE HIDEO
    • C08F2/00C08F2/48C08F2/50C08F20/00C08F20/10C08F299/00C09D4/00C09D5/00C09D5/03
    • PURPOSE: To provide titled composition of highly adhesive potential to conductive thin film, also having excellent humidity and water resistance, weatherability, etc., comprising a multicomponent polyfunctional acrylate-based polymerizable compound, a saturated copolymerized polyester, a photosensitizer and silane coupling agent.
      CONSTITUTION: The objective composition comprising (A) a multicomponent polymerizable compound with at least one component consisting of a (meth) acrylate of two or more functionality, (B) a saturated copolymerized polyester soluble to the component (A), having a molecular weight 1,000W15,000, with ≥20mol% of the saturated polycarboxylic acid component being aromatic dicarboxylic acid, (C) a photosensitizer such as benzoin methyl ether, and (D) a silane coupling agent such as γ-(2-aminoethyl)-aminopropyl methyldimethoxysilane. Where, the weight ratio A/B should the 20/80W80/20.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:提供包含多组分多官能丙烯酸酯类聚合性化合物,饱和共聚聚酯,光敏剂和硅烷偶联剂的导电性薄膜,具有优异的耐湿性,耐水性,耐气候性等的高粘合性的标题组成。 构成:包含(A)多组分可聚合化合物和至少一种由两种或多种官能团的(甲基)丙烯酸酯组成的组分的目标组合物,(B)可溶于组分(A)的饱和共聚聚酯,其分子量 1,000〜15,000,饱和多元羧酸成分为20摩尔%为芳香族二羧酸,(C)光敏剂如苯偶姻甲基醚,(D)硅烷偶联剂如γ-(2-氨基乙基) - 氨基丙基 甲基二甲氧基硅烷。 其中A / B的重量比应为20 / 80-80 / 20。
    • 9. 发明专利
    • Ultraviolet ray-curable conductive resin composition
    • 超紫外线可固化导电树脂组合物
    • JPS5920305A
    • 1984-02-02
    • JP13141182
    • 1982-07-27
    • Toyobo Co Ltd
    • FUJIMOTO HIROSHIMORI SHINICHIROUMIYAKE HIDEO
    • C08K3/00C08F2/00C08F2/44C08F2/50C08K3/02C08K3/04C08K3/08C08K3/18C08K3/22C08K5/00C08K5/51C08L7/00C08L33/00C08L33/02C08L67/00C09D11/00
    • PURPOSE: The titled composition excellent in ultraviolet ray-curability, conductivity, adhesive property, and surface smoothness, prepared by mixing a polymerizable compound with a photosensitizer, a conductive substance, and a specified phosphorus compound.
      CONSTITUTION: The titled composition prepared by mixing (A) a polymerizable compound (e.g., styrene or methyl (meth)-acrylate) with (B) a photosensitizer (e.g., 2-hydroxy-2-methylpropiophenone, or benzil dimethyl ketal), (C) a conductive substance (e.g., Ag, Cu, or Al), and (D) a phosphorus compound of formulas I or/and II [wherein R
      1 , R
      2 , and R
      3 , and R
      3 are each H, (substituted) alkyl, or (substituted) alkyl], e.g., photphorus acid, triethyl phosphite, phosphoric acid, or dimethyl phosphate. Because of the absence of any volatile solvent, there can be obtained effects of forming a circuit in good reproducibility without any change in viscosity during printing or coating; and of improving working efficiency without restriction of a pot life otherwise encountered in thermosetting resins, and by the addition of compound D, compound C can be dispersed uniformly, with consequent improvement in conductivity.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过将可聚合化合物与光敏剂,导电性物质和特定的磷化合物混合而制备的紫外线固化性,导电性,粘合性,表面平滑性优异的标题组合物。 构成:通过混合(A)可聚合化合物(例如苯乙烯或(甲基)丙烯酸甲酯)与(B)光敏剂(例如2-羟基-2-甲基苯丙酮或苯偶酰二甲基缩酮)( C)导电物质(例如Ag,Cu或Al)和(D)式I或/和II的磷化合物[其中R 1,R 2和R 3和R 3各自为H,(取代的)烷基, 或(取代的)烷基],例如,光辉酸,亚磷酸三乙酯,磷酸或磷酸二甲酯。 由于不存在任何挥发性溶剂,可以获得在印刷或涂布期间粘合性没有任何改变的情况下以良好的再现性形成电路的效果; 并且提高工作效率而不限制热固性树脂中的适用期,并且通过添加化合物D,可以使化合物C均匀分散,从而提高导电性。
    • 10. 发明专利
    • Aqueous treating agent for glass fiber
    • 玻璃纤维水处理剂
    • JPS58223646A
    • 1983-12-26
    • JP10794682
    • 1982-06-22
    • Toyobo Co Ltd
    • KODERA YOSHIICHIMIYAKE HIDEO
    • C03C25/10C08J5/08
    • PURPOSE: The titled treating agent, containing an aqueous dispersion of a polyester resin, and/or an aqueous emulsion of a polyester resin and a coupling agent as essential components, and capable of providing improved molded glass-reinforced resin articles.
      CONSTITUTION: An aqueous treating agent for glass fibers prepared by incorporating (A) an aqueous dispersion of a polyester resin dispersed in a system consisting of water and a water-soluble organic solvent, e.g. methanol or isopropanol, and (or) (B) an aqueous emulsion of a polyester resin emulsified in a system consisting of water and a surfactant, e.g. a monocarboxylic acid ester of polyethylene glycol, and (C) a coupling agent, e.g. γ-aminopropyltriethoxysilane. Glass fibers to be used in a reinforced plastic are treated with the resultant treating agent to give molded articles having a prevented whitening phenomenon and improved transparency.
      COPYRIGHT: (C)1983,JPO&Japio
    • 目的:将含有聚酯树脂的水性分散体和/或聚酯树脂和偶联剂的水性乳液作为必需成分的标题处理剂,能够提供改良的成型玻璃增强树脂制品。 构成:通过掺入(A)分散在由水和水溶性有机溶剂组成的体系中的聚酯树脂的水性分散体制备的玻璃纤维的水处理剂,例如, 甲醇或异丙醇,和(或)(B)在由水和表面活性剂组成的体系中乳化的聚酯树脂的水乳液,例如, 聚乙二醇的单羧酸酯,和(C)偶联剂,例如 γ-氨基丙基三乙氧基硅烷。 用所得处理剂处理用于增强塑料的玻璃纤维,得到具有防止白化现象和提高透明度的模塑制品。