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1. 发明专利

JPS60210664A Self-bonding polyorganosiloxane composition 失效
标题翻译：自粘多聚硅氧烷组合物
公开(公告)号：JPS60210664A
公开(公告)日：1985-10-23
申请号：JP6676384
申请日：1984-04-05
申请人： Toshiba Silicone Co Ltd
发明人： MATSUMOTO MAKOTO , MATSUMOTO YASUSHI , OOKAWA KAZUHIRO
IPC分类号： C08L83/00 , C08K5/54 , C08K5/549 , C08L83/05 , C08L83/07
摘要： PURPOSE: To provide the titled compsn. capable of retaining excellent adhesion under heating at a low temp. or under high temp. and humidity, by adding a cyclotetrasiloxane to a specified polyorganosiloxane mixture.
CONSTITUTION: The titled compsn. consists of 100pts. polyorganosiloxane (A) contg. at least two units of formula I (wherein R
1 is alkenyl; R
2 is a monovalent hydrocarbon group contg. no aliph. unsaturated bond; a is 1, 2, b is 0W2, and a+b=1W3) per molecule, a polyorganohydrogensiloxane (B) contg. a unit of formula II (wherein R
3 is a hydrocarbon group; c is 0W2, d is 1, 2 and c+d=1W3) and at least three H atoms attached to the Si atom per molecule is a quantity giving 0.5W4.0 H atoms attached to the Si atom for one R
2 in component A, 0.1W10pts. cyclotetrasiloxane (C) of formula III (wherein e is 1W3; f is 0W2; g is 1W3 and e+f+g=4; R
4 is H, a 1W4C monovalent hydrocarbon group; R
5 , R
6 , R
7 are each a 1W6C monovalent hydrocarbon group; h is 1W4) and 0.1W100ppm (in terms of platinum, based on the quantity of component A) platinum (compd.) catalyst (D).
COPYRIGHT: (C)1985,JPO&Japio
摘要翻译：目的：提供标题化合物。能够在低温加热下保持优异的附着力。或在高温下和湿度，通过向指定的聚有机硅氧烷混合物中加入环四硅氧烷。宪法：标题化合物包含100pts。聚有机硅氧烷（A）至少两个式I的单元（其中R 1是烯基; R 2是单价烃基，不含有不饱和键; a是1,2，b是0-2，a + b = 1-3），聚有机氢硅氧烷（B）式II的单元（其中R 3是烃基; c是0-2，d是1,2和c + d = 1-3），并且每个分子连接到Si原子上的至少三个H原子是在组分A中一个R 2连接到Si原子上的0.5-4.0个H原子的量为0.1-10pt。式III的环四硅氧烷（C）（其中e为1-3; f为0-2; g为1-3，e + f + g = 4; R 4为H，1-4C单价烃基; R 5，R 6，R 7各自为1-6C单价烃基; h为1-4）和0.1〜100ppm（以铂为单位，基于成分A的量）铂化合物）催化剂（D）。

2. 发明专利

JPS60214793A Novel cyclotetrasiloxane compound 失效
标题翻译：新型环硅氧烷化合物
公开(公告)号：JPS60214793A
公开(公告)日：1985-10-28
申请号：JP6676284
申请日：1984-04-05
申请人： Toshiba Silicone Co Ltd
发明人： MATSUMOTO MAKOTO , MATSUMOTO YASUSHI , OOKAWA KAZUHIRO
IPC分类号： C08L83/00 , C07F7/21 , C08K5/54 , C08K5/549 , C08L83/07
摘要： NEW MATERIAL:A compound of formula I (R
1 WR
3 are 1W3C alkyl; a is 1W3).
EXAMPLE: The compound of formula II.
USE: A tackifier for addition-reaction type of silicone rubber: it can give good adhesion by low-temperature heating and the adhesion is satisfactorily sustained even when exposed to high temperature and high humidity conditions or hot water.
PREPARATION: For example, the reaction between a compound of formula IIIand another compound of formula IV is carried out, preferably in the absence of a solvent, using a catalyst such as chloroplatinic acid and the resultant intermediate is allowed to react with cyclotetrasiloxane.
COPYRIGHT: (C)1985,JPO&Japio
摘要翻译：新材料：式I化合物（R 1 -R 3为1-3 C烷基; a为1-3）。实施例：式II化合物。用途：用于加成反应型硅橡胶的增粘剂：通过低温加热可以提供良好的粘合性，即使暴露在高温高湿条件或热水下也能令人满意地保持粘合性。制备：例如，使用催化剂如氯铂酸，使式III化合物与另一种式IV化合物之间的反应优选在不存在溶剂的情况下进行，并使所得中间体与环四硅氧烷反应。

3. 发明专利

JPS59126465A Pressure-sensitive electrically conductive silicone rubber composition 失效
标题翻译：压敏电导电硅橡胶组合物
公开(公告)号：JPS59126465A
公开(公告)日：1984-07-21
申请号：JP146883
申请日：1983-01-08
申请人： Toshiba Silicone Co Ltd
发明人： OOKAWA KAZUHIRO
IPC分类号： C08L83/00 , C08K9/02 , C08L83/04 , H01B1/24 , H01H1/025 , H01H1/027 , H01H1/029
CPC分类号： H01H1/029 , H01H1/027
摘要： PURPOSE:To provide the titled highly sensitive composition exhibiting large difference of electrical resistance between the pressurized state and the unpressurized state, by forming an electrically insulating ceramic film to the surface of granulated carbon black, and compounding the carbon black to a silicone rubber. CONSTITUTION:Granulated carbon black having electrically insulating ceramic film on the surface is mixed in a silicone rubber composition. The particle diameter of carbon black is 50-2,000mum, and the amount of the ceramic film (silicon carbide or silicon nitride) is 1-50wt% based on the carbon black. The amount of carbon black having the ceramic film is 1-80wt% based on the silicone rubber composition.
摘要翻译：目的：提供在加压状态和非加压状态之间显示出很大的电阻差的标题高灵敏度组合物，通过在粒状炭黑的表面形成电绝缘陶瓷膜，并将炭黑复合到硅橡胶上。构成：表面上具有电绝缘陶瓷膜的颗粒炭黑在硅橡胶组合物中混合。炭黑的粒径为50〜200μm，陶瓷膜（碳化硅或氮化硅）的量为碳黑的1-50重量％。具有陶瓷膜的炭黑的量相对于硅橡胶组合物为1-80重量％。

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