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    • 1. 发明专利
    • Apparatus for pulling up single crystal silicon
    • 用于拉出单晶硅的装置
    • JPS58181797A
    • 1983-10-24
    • JP6509982
    • 1982-04-19
    • Toshiba Ceramics Co LtdToshiba Corp
    • MATSUO HIDEYASUNAGASHIMA HIDEOWATANABE MASAHARUUSAMI TOSHIROUMURAOKA HISASHI
    • C30B15/10C30B15/14C30B29/06H01L21/208
    • C30B15/10
    • PURPOSE:To inhibit increase in the concns. of carbon and oxygen in single crystal Si and to prevent deterioration in the characteristics of a semiconductor device, by specifying the materials of the crucible, the protector and the heat insulating tubes of an apparatus for manufacturing single crystal Si by the CZ method. CONSTITUTION:A crucible 2 is supported in a chamber 1 by a freely rotatable rod 4 through a protector 3 covering the outside of the crucible 2, and a cylindrical carbon heater 5 and heat insulating tubes 6, 7 are arranged around the protector 3 in order. A pulling shaft 9 holding a seed crystal 8 at the lower end is rotatably suspended from the upper opening of the chamber 1. The crucible 2, the protector 3 and the tubes 6, 7 are made of silicon nitride, silicon carbide or quartz glass. For example, the crucible 2 is made of quartz, and the protector 3 and the tubes 6, 7 are made of a sintered silicon nitride body. Gaseous SiO2 produced by the reaction of molten Si 10 with the crucible 2 does not react with those members, so no gaseous CO is produced, and the concns. of C and O in pulled single crystal Si can be reduced.
    • 目的:抑制浓度增加 的单晶Si中的碳和氧,并且通过用CZ方法指定用于制造单晶Si的装置的坩埚,保护器和隔热管的材料来防止半导体器件的特性的劣化。 构成:坩埚2通过可自由转动的杆4通过覆盖坩埚2的外部的保护器3支撑在腔室1中,并且圆筒形碳加热器5和隔热管6,7依次布置在保护器3的周围 。 保持下端的晶种8的拉动轴9从室1的上开口可旋转地悬挂。坩埚2,保护器3和管6,7由氮化硅,碳化硅或石英玻璃制成。 例如,坩埚2由石英制成,保护器3和管6,7由氮化硅烧结体构成。 通过熔融Si 10与坩埚2的反应产生的气态SiO 2与这些部件不反应,因此不产生气体CO。 的拉伸单晶Si中的C和O可以减少。
    • 3. 发明专利
    • Apparatus for heating specimen in vacuum
    • 用于在真空中加热样品的装置
    • JPS5939348A
    • 1984-03-03
    • JP14877382
    • 1982-08-27
    • Toshiba Ceramics Co LtdToshiba Corp
    • MIKATA HIROICHIWATANABE MASAHARUINOUE TOMOYASUTAKAHASHI SHIYOUICHI
    • H05B3/20B01L7/00G01N25/00
    • PURPOSE: To make it possible to uniformly heat a specimen, by a method wherein a heat transfer plate is formed of a sapphire plate and a thin film heater comprising tungsten or the like is formed on the rear surface of the sapphire plate.
      CONSTITUTION: A thin film heater 2 is deposited and formed on the whole rear surface of a heat transfer member 1 comprising a monocrystalline sapphire plate with a thickness of about 1mm. The thin film heater 2 is formed, for example, by vapor depositing tungsten under high vacuum of 10
      -5 Torr or less. A pair of rod shaped electrodes 3a, 3b are parallelly arranged to the periphery of the rear surface part of the thin film heater 2 to be attached to said thin film heater 2. By applying a voltage between the electrodes 3a, 3b, a current is supplied to the thin film heater 2 to heat the same.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过在蓝宝石板的后表面形成由蓝宝石板形成的传热板和包含钨等的薄膜加热器,可以均匀地加热试样。 构成:薄膜加热器2沉积并形成在包括厚度约1mm的单晶蓝宝石板的传热构件1的整个后表面上。薄膜加热器2例如通过气相沉积钨 在10 -5乇或更低的高真空下。 一对棒状电极3a,3b平行地布置在薄膜加热器2的后表面部分的外围,以附着到所述薄膜加热器2.通过在电极3a,3b之间施加电压,电流为 供给到薄膜加热器2以加热薄膜加热器2。
    • 5. 发明专利
    • Manufacture of single crystal silicon
    • 单晶硅的制造
    • JPS58181798A
    • 1983-10-24
    • JP6510182
    • 1982-04-19
    • Toshiba Ceramics Co LtdToshiba Corp
    • MATSUO HIDEYASUNAGASHIMA HIDEOWATANABE MASAHARUUSAMI TOSHIROUMURAOKA HISASHI
    • C30B15/14C30B15/10C30B29/06H01L21/208
    • C30B15/10
    • PURPOSE:To always obtain an Si crystal as a single crystal in the manufacture of single crystal Si by the CZ method using a silicon nitride crucible by restricting the temp. of the crucible. CONSTITUTION:A silicon nitride crucible 2 is supported in a chamber 1 by a rotating shaft 4 through a protector 3 covering the outside of the crucible 2, and a cylindrical heater 5 and heat insulating tubes 6, 7 are arranged around the protector 3 in order. Si as a starting material is put in the crucible 2 and melted with the heater 5. A seed crystal 8 attached to the lower end of a rotatable pulling shaft 9 is dipped in the molten Si 10, and the shaft 9 is pulled up. When the Si is melted, the crucible 2 is kept at
    • 目的:通过使用氮化硅坩埚通过限制温度通过CZ方法在制造单晶Si中始终获得作为单晶的Si晶体。 的坩埚。 构成:氮化硅坩埚2通过旋转轴4通过覆盖坩埚2的外部的保护器3支撑在腔室1中,并且圆筒形加热器5和隔热管6,7依次布置在保护器3的周围 。 将Si作为起始材料放入坩埚2中并用加热器5熔化。将安装在可旋转牵引轴9的下端的晶种8浸入熔融Si 10中,并将轴9拉起。 当Si熔化时,坩埚2保持在​​<= 1520℃。 坩埚2的氮化硅容易地溶解在高于温度的熔融Si中。 在Si晶体的拉伸过程中氮化硅沉积并漂浮在熔融Si的表面上。 沉积的氮化硅接触固体和液体之间的界面,阻碍了Si晶体的生长。 当硅晶体被吸收时,Si晶体被制成多晶体。
    • 6. 发明专利
    • Die for manufacturing platelike silicon crystal
    • 用于制造板状硅晶体
    • JPS58181794A
    • 1983-10-24
    • JP6510082
    • 1982-04-19
    • Toshiba Ceramics Co LtdToshiba Corp
    • MATSUO HIDEYASUNAGASHIMA HIDEOWATANABE MASAHARUUSAMI TOSHIROUMURAOKA HISASHI
    • C30B15/34C30B29/06H01L21/208
    • C30B15/34
    • PURPOSE:To efficiently obtain high-quality platelike single crystal Si having a prescribed shape, by filling Si into the hollow part of a die body made of crystalline silicon nitride. CONSTITUTION:A crystalline silicon nitride film 12 is deposited on the outer surface of a polycrystal Si substrate 11 by a CVD method. Both ends of the resulting platelike body are worked to a prescribed shape to obtain a die 14 for manufacturing a platelike Si crystal. The die 14 consists of a hollow frame- shaped die body 13 made of crystalline silicon nitride and the Si substrate 11 filled into the hollow part of the body 13. The die 14 is set on molten Si in a crucible, and pulling is carried out from the top of the die 14 using a platelike seed crystal. The Si substrate 11 in the body 13 is melted to fill the hollow part of the body 13, so the molten Si 15 in the crucible rises efficiently in the hollow part of the body 13, and platelike single crystal Si can be manufactured efficiently. Since the Si substrate 11 is not removed, no pollution is caused, and high-quality platelike single crystal Si is obtd.
    • 目的:为了有效地获得具有规定形状的高品质板状单晶Si,通过将Si填充到由结晶氮化硅制成的模具体的中空部分中。 构成:通过CVD法在多晶Si衬底11的外表面上沉积结晶氮化硅膜12。 将所得板状体的两端加工成规定形状,得到板状Si晶体的制造用模具14。 模具14包括由结晶氮化硅制成的中空的框状模体13和填充到主体13的中空部分中的Si衬底11.将模具14设置在坩埚中的熔融Si上,并且进行拉伸 从模具14的顶部使用板状晶种。 主体13中的Si基板11熔化以填充主体13的中空部分,因此坩埚中的熔融Si 15有效地升高到主体13的中空部分中,并且可以有效地制造板状单晶Si。 由于Si基板11没有被去除,所以不会产生污染,并且能够获得高质量的板状单晶Si。
    • 7. 发明专利
    • Die for manufacturing platelike silicon crystal
    • 用于制造板状硅晶体
    • JPS58181795A
    • 1983-10-24
    • JP6577482
    • 1982-04-20
    • Toshiba Ceramics Co LtdToshiba Corp
    • MATSUO HIDEYASUNAGASHIMA HIDEOWATANABE MASAHARUUSAMI TOSHIROUMURAOKA HISASHI
    • C30B15/34C30B29/06H01L21/208
    • C30B15/34
    • PURPOSE:To efficiently manufacture platelike single crystal Si, by using crystalline silicon nitride as the material of the titled die. CONSTITUTION:A die 1 is set on a crucible so that the lower end part is immersed in molten Si in the crucible. A heater 2 is placed around the crucible except the upper end part of the die 1, and a heat shield 3 is mounted on the heater 2. Molten Si4 rises in the hollow part of the die 1 from the crucible by capillarity. The Si4 is pulled up by using a seed crystal 5 to obtain platelike single crystal Si. The die 1 is made of silicon nitride. Since silicon nitride does not react with molten Si, no impurities enter the molten Si, preventing the formation of polycrystal Si. Accordingly, platelike single crystal Si can be manufactured efficiently.
    • 目的:通过使用晶体氮化硅作为标题模具的材料,有效地制造板状单晶硅。 构成:将模具1放置在坩埚上,使得下端部浸入坩埚中的熔融Si中。 加热器2放置在除了模具1的上端部分之外的坩埚周围,并且隔热件3安装在加热器2上。熔融Si 4在坩埚的中空部分中通过毛细作用而上升。 通过使用晶种5将Si4拉起,得到板状单晶Si。 模具1由氮化硅制成。 由于氮化硅不与熔融Si反应,因此不会使杂质进入熔融Si,从而形成多晶Si。 因此,可以有效地制造板状单晶Si。
    • 9. 发明专利
    • Apparatus for pulling up single crystal silicon
    • 用于拉出单晶硅的装置
    • JPS58181792A
    • 1983-10-24
    • JP6509882
    • 1982-04-19
    • Toshiba Ceramics Co LtdToshiba Corp
    • MATSUO HIDEYASUNAGASHIMA HIDEOWATANABE MASAHARUUSAMI TOSHIROUMURAOKA HISASHI
    • C30B15/10C30B15/12C30B15/30C30B29/06H01L21/208
    • C30B15/305
    • PURPOSE:To prevent a change in the resistance value of single crystal Si and to uniformalize and reduce the concn. of oxygen as an impurity by immersing a silicon nitride structure in molten Si in the crucible of an apparatus for manufacturing single crystal Si by the CZ method to prevent the convection of the molten Si. CONSTITUTION:A quartz crucible 2 is supported in a chamber 1 by a freely rotatable rod 4 through a graphite protector 3 covering the outside of the crucible 2, and a cylindrical heater 5 and heat insulating tubes 6, 7 are arranged around the protector 3 in order. Si as a starting material and a dopant for controlling the resistance value of a single crystal Si ingot are put in the crucible 2 and melted with the heater 5. A seed crystal 8 attached to the lower end of a rotatable pulling shaft 9 is dipped in the molten Si10, and the shaft 9 is pulled up. In order to prevent the convection of the molten Si10 during the pulling, a crucible-shaped silicon nitride structure 11 having holes 11a... at the desired positions of the bottom is immersed in the Si10, and the upper part protruding from the surface of the melt 10 is supported on the crucible 2.
    • 目的:防止单晶硅电阻值的变化,均匀化,降低浓度。 通过用CZ法将用于制造单晶Si的装置的坩埚中的氮化硅结构浸渍在熔融Si中的氧作为杂质,以防止熔融Si的对流。 构成:石英坩埚2通过可自由旋转的棒4通过覆盖坩埚2的外部的石墨保护器3支撑在腔室1中,并且圆柱形加热器5和隔热管6,7围绕保护器3布置 订购。 将作为原料的Si和用于控制单晶Si锭的电阻值的掺杂剂放入坩埚2中并用加热器5熔化。将安装在可旋转的牵引轴9的下端的晶种8浸入 熔融的Si10和轴9被拉起。 为了防止熔融Si10在拉拔期间的对流,将具有位于底部的所需位置的孔11a ...的坩埚状氮化硅结构11浸渍在Si10中,并且从上表面突出的上部 熔体10被支撑在坩埚2上。