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    • 8. 发明专利
    • MANUFACTURE OF CERAMIC FORMED BODY
    • JPH10217212A
    • 1998-08-18
    • JP2487097
    • 1997-02-07
    • TORAY INDUSTRIES
    • OGATA TOMOHIKOYOSHIDA FUMIOSUZUKI MASANARI
    • C04B35/632B28B1/00C04B35/48C08G59/50C08L101/14
    • PROBLEM TO BE SOLVED: To settle the apprehension regarding the influence of flying an organic solvent to exhaust facilities and human bodies by a method wherein a crosslinkable water-soluble binder is employed. SOLUTION: As the crosslinkable water-soluble binder used for the slip casting of ceramic, a binder, which crosslinks ceramic casting slip through crosslinking reaction to a hardness enough high and substantially has a water solubility, is employed. The preferable solubility (= the weight of solute/the weight of a solution) is about 10%. The preferable binder is a mixture of a crosslinkable component and a crosslinker. As the crosslinkable component, a water-soluble epoxy-based resin such as glycidyl ether or the like is exampled. As the crosslinker, an amine-based compound is exampled. By employing a binder mainly made of a crosslinked body including the water-soluble epoxy- based resin and the amine-based compound, there is no apprehension regarding the exhaustion of an organic solvent and the influence to human bodies and a formation, in which no crack or the like develops even after the hardening through reaction and after the baking of a ceramic formed body.
    • 9. 发明专利
    • SOLID ELECTROLYTE ELEMENT AND OXYGEN CONCENTRATION MEASURING DEVICE
    • JPH10213563A
    • 1998-08-11
    • JP1504997
    • 1997-01-29
    • TORAY INDUSTRIES
    • YOSHIDA FUMIOKAWAKITA SUSUMUSUZUKI MASANARI
    • G01N27/411C04B35/48
    • PROBLEM TO BE SOLVED: To accurately measure a low oxygen concentration of a ppm level by including a solid electrolyte having ion conductivity and low electron conductivity in a solid electrolyte layer where a heat resistant impact temperature has the ion conductivity of a specified temperature. SOLUTION: For oxygen measuring, an oxygen ion conductive solid electrolyte, for instance yttria zirconium is preferred, but it is weak to heat resistant impacts and therefor it is not suited for a casting sensor. Thus, a solid electrolyte layer is constructed in such a manner that a one end sealed tube 1 (Tammanin tube) is composed by using a solid electrolyte having ion conductivity where a heat resistant impact temperature is 120 deg.C or higher, for instance, magnesia zirconium, and an yttria zirconium film 5 is coated on a range of the standard pole of its inner surface having a reference material 2. Thus, since a temperature increase gradient is softer compared with the outer surface of Tammanin tube 1, the film 5 is not damaged, a sensor having small partial electron conductivity and large oxygen ion conductivity is provided and low oxygen concentration is accurately measured.
    • 10. 发明专利
    • SOLID ELECTROLYTE ENZYME SENSOR
    • JPH01176937A
    • 1989-07-13
    • JP22088
    • 1988-01-04
    • TORAY INDUSTRIES
    • MATSUDA YOSHIOKOBAYASHI KEISUKEYOSHIDA FUMIO
    • G01N27/409
    • PURPOSE:To enhance the accuracy of measurement and to increase response speed by providing porous electrodes and fine particles of a solid electrolyte, etc., and operating the title sensor at a relatively low temp. CONSTITUTION:The electromotive force based on a difference between the oxygen partial pressures of a reference gas of a known oxygen partial pressure and a gas to be measured is generated between the porous electrodes 2 and 3 when the above-mentioned reference gas is introduced into the sensor from a reference gas introducing pipe 9 and the gas to be measured is introduced into an outside pipe 8. This electromotive force is, therefore, measured by an electromotive force meter 10 to determine the oxygen partial pressure of the gas to be measured. The gaseous oxygen in closed cells 7 is discharged by the oxygen pump effect of the fine particles 5 of the solid electrolyte or the gaseous oxygen is introduced therein from the contact gas even if the closed cells 7 exist in the electrodes 2, 3 and, therefore, the oxygen partial pressure of the gas in the cells 7 equilibrates rapidly with the oxygen partial pressure of the contact gas. The sensor is operated at the relatively low temp. in such a manner. The accuracy of the measurement is thus enhanced and the response speed is increased.