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    • 1. 发明专利
    • Electrode for dye-sensitized solar cell and its manufacturing method
    • 用于染料敏化太阳能电池的电极及其制造方法
    • JP2008181685A
    • 2008-08-07
    • JP2007012427
    • 2007-01-23
    • Teijin Dupont Films Japan LtdTeijin Ltd帝人デュポンフィルム株式会社帝人株式会社
    • NISHIO REIKUBO KOJIKOMURA NOBUYAMIYOSHI TAKANORI
    • H01M14/00H01L31/04
    • Y02E10/542Y02P70/521
    • PROBLEM TO BE SOLVED: To provide an electrode for a dye-sensitized solar cell that can obtain high charge transport efficiency by adsorbing a sufficient amount of dye while using a plastic base-material as a support, and also, can manufacture a dye-sensitized solar cell in which a porous oxide film is excellently laminated on a base material while having high photovoltaic performance. SOLUTION: The electrode for a dye-sensitized solar cell is formed of a porous semiconductor layer (A) comprising the total 100 pts wt. which is composed of 10-70 wt.% of a particle-containing short-fiber-like metal oxide and 30-90 wt.% of metal-oxide particles having a particle size of 2-500 nm, and 0.1-40 pts.wt. of a binder, a transparent conductive layer (B), and a plastic film (C). The particle-containing short-fiber-like metal oxide has an average fiber diameter of 50-1,000 nm, a fiber length/a thin-part fiber diameter of ≥5, and a bead shape. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种用于染料敏化太阳能电池的电极,其可以通过在使用塑料基材作为载体的同时吸附足够量的染料而获得高电荷传输效率,并且还可以制造 染料敏化太阳能电池,其中多孔氧化物膜优良地层压在基材上,同时具有高的光伏性能。 解决方案:用于染料敏化太阳能电池的电极由包含总共100重量份的多孔半导体层(A)形成。 其由10-70重量%的含微粒的短纤维状金属氧化物和30-90重量%的粒径为2-500nm的金属氧化物颗粒和0.1-40个聚合物组成。 重量。 的粘合剂,透明导电层(B)和塑料膜(C)。 含微粒的短纤维状金属氧化物的平均纤维直径为50〜1000nm,纤维长度/薄壁纤维直径≥5,以及珠状。 版权所有(C)2008,JPO&INPIT
    • 5. 发明专利
    • Electrode for dye-sensitized solar cell
    • 用于染料敏化太阳能电池的电极
    • JP2008186659A
    • 2008-08-14
    • JP2007017718
    • 2007-01-29
    • Teijin Dupont Films Japan LtdTeijin Ltd帝人デュポンフィルム株式会社帝人株式会社
    • NISHIO REIKUBO KOJIKOMURA NOBUYAMIYOSHI TAKANORI
    • H01M14/00H01L31/04
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a dye-sensitized solar cell electrode capable of adsorbing a sufficient amount of dye, and moreover, of obtaining high electrification transportation efficiency in a metal oxide layer. SOLUTION: The dye-sensitized solar cell electrode is consisting of a transparent base material having a transparent electroconductive layer and a porous semiconductor layer laminated on the transparent electroconductive layer. This is the dye-sensitized solar cell electrode in which the porous semiconductor layer contains a fibrous metal oxide of the average fiber diameter of 50 to 1,000 nm and the fiber length/the fiber diameter 5 or more for 15 wt.% or more of the total weight of the porous semiconductor layer, and contains metal oxide particulates of the average particle diameter of 2 to 500 nm for 15 wt.% or more of the total weight of the porous semiconductor layer. Furthermore, this is the dye-sensitized solar cell electrode in which, as for the porous semiconductor layer, intensity ratio of a crystal phase (rutile phase/anatase phase) in X-ray diffraction is 0.0 to 0.25, and crystallite size in the anatase phase is 10 to 300 nm. COPYRIGHT: (C)2008,JPO&INPIT
    • 解决的问题:提供能够吸附足够量染料的染料敏化太阳能电池电极,此外,在金属氧化物层中获得高的起电输送效率。 解决方案:染料敏化太阳能电池电极由具有透明导电层的透明基材和层叠在透明导电层上的多孔半导体层组成。 这是染料敏化太阳能电池电极,其中多孔半导体层含有平均纤维直径为50〜1000nm的纤维状金属氧化物,纤维长度/纤维直径为5以上,15重量%以上 多孔半导体层的总重量,并且包含平均粒径为2〜500nm的金属氧化物微粒,多孔半导体层的总重量为15重量%以上。 此外,这是染料敏化太阳能电池电极,其中对于多孔半导体层,X射线衍射中的结晶相(金红石相/锐钛矿相)的强度比为0.0〜0.25,锐钛矿的微晶尺寸 相为10〜300nm。 版权所有(C)2008,JPO&INPIT
    • 7. 发明专利
    • Electrode for dye-sensitized solar cell
    • 用于染料敏化太阳能电池的电极
    • JP2011086449A
    • 2011-04-28
    • JP2009237292
    • 2009-10-14
    • Teijin Dupont Films Japan Ltd帝人デュポンフィルム株式会社
    • NISHIO REIYOSHIDA TETSUO
    • H01M14/00B32B9/00H01L31/04
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide an electrode for dye-sensitized solar cell in which a porous semiconductor layer is laminated on a base material, in proper adhesion without exfoliating. SOLUTION: The electrode for dye-sensitized solar cell constituted of a plastic film and a transparent conductive layer installed on its one side; a porous semiconductor layer B, which is installed in contact with the transparent conductive layer and contains metal oxide particulates of an average particle size of 3-100 nm 70-100 wt.%; and a porous semiconductor layer A, which is installed in contact with the porous semiconductor layer B and contains short fiber-like metal oxide 30-100 wt.%. The short fiber-like metal oxide has an average fiber diameter of 50-1,000 nm. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供其中多孔半导体层层压在基材上的染料敏化太阳能电池的电极,在没有去角质的情况下具有适当的粘附性。 解决方案:用于染料敏化太阳能电池的电极由塑料膜和安装在其一侧的透明导电层构成; 多孔半导体层B,其与透明导电层接触地安装,并且含有平均粒度为3〜100nm,70〜100重量%的金属氧化物微粒; 以及多孔半导体层A,其与多孔半导体层B接触并且含有30-100重量%的短纤维状金属氧化物。 短纤维状金属氧化物的平均纤维直径为50〜1000nm。 版权所有(C)2011,JPO&INPIT
    • 8. 发明专利
    • Reflection-proof electroconductive film
    • 防反射电磁膜
    • JP2008168488A
    • 2008-07-24
    • JP2007002510
    • 2007-01-10
    • Teijin Dupont Films Japan Ltd帝人デュポンフィルム株式会社
    • NISHIO REIKUBO KOJI
    • B32B27/36B32B7/02B32B9/00G02B1/11G02B1/111H01B5/14H01L31/0216H01L31/0392H01L31/042
    • Y02E10/50
    • PROBLEM TO BE SOLVED: To provide a transparent reflection-proof electroconductive film which uses a polyester film as a base film and has high rate of light beam permeability and excellent reflection proofness while featuring dimensional stability, especially the usefulness as a solar cell base film. SOLUTION: This reflection-proof electroconductive film comprises a biaxially oriented polyester film, a reflection-proof layer formed on the biaxially oriented polyester film and a transparent electroconductive layer formed on the reflection-proof layer. In addition, the reflection-proof layer contains a metallic compound and has a refractive index and a thickness which can meet the conditions of the following formulae (1) and (2): (1) 105-40.0×N≤d≤180-40.0×N, (2) 1.75≤N≤2.0 (in the formulae (1) and (2), N is the refractive index of the reflection-proof layer and d is the thickness (nm) of the reflection-proof layer). COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种透明的防反射导电膜,其使用聚酯膜作为基膜,并且具有高的光束透过率和优异的防反射性,同时具有尺寸稳定性,特别是作为太阳能电池的有用性 底片 解决方案:该防反射导电膜包括双轴取向聚酯膜,形成在双轴取向聚酯膜上的防反射层和形成在防反射层上的透明导电层。 另外,防反射层含有金属化合物,其折射率和厚度可满足下述式(1)和(2)的条件:(1)105-40.0×N≤d≤180〜 40.0×N,(2)1.75≤N≤2.0(式(1)和(2)中,N为防反射层的折射率,d为防反射层的厚度(nm) 。 版权所有(C)2008,JPO&INPIT
    • 10. 发明专利
    • Base material for solar cell
    • 太阳能电池基材
    • JP2011181892A
    • 2011-09-15
    • JP2010266543
    • 2010-11-30
    • Teijin Dupont Films Japan Ltd帝人デュポンフィルム株式会社
    • NAKAHIRO TAKASHINISHIO REI
    • H01L31/04B32B27/00
    • Y02E10/50
    • PROBLEM TO BE SOLVED: To provide a base material for a solar cell capable of enduring a stress during a process of manufacturing a solar cell at a high temperature, has a surface capable of obtaining a light confinement effect, and is useful for manufacturing a solar cell that exhibits superior photoelectric conversion efficiency, when it is used as a base material for a flexible solar cell.
      SOLUTION: The base material for a solar cell, includes a base film constituted of thermoplastic crystalline resin and a coating layer provided on at least one surface thereof, wherein the coating layer is composed of a hardened material of a composition containing an inert particle and an ultraviolet curable resin; a glass transition point of the hardened material constituting the coating layer is 180 °C or higher; volume fraction of the inert particle relative to the entire volume of the coating layer is 5-20%; an average surface roughness Ra of the center plane of the outer surface of the coating layer is 5 to 150 nm; and an average spacing S between peaks of parts of the outer surface is 100-2,500 nm.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供一种在高温下制造太阳能电池的过程中能承受应力的太阳能电池的基材,具有能够获得光限制效果的表面,并且可用于 当将其用作柔性太阳能电池的基材时,制造出具有优异的光电转换效率的太阳能电池。 解决方案:太阳能电池用基材包括由热塑性结晶性树脂构成的基膜和在其至少一个表面上设置的涂层,其中,涂层由含有惰性的组合物的硬化材料构成 颗粒和紫外线固化树脂; 构成涂层的硬化材料的玻璃化转变点为180℃以上; 相对于涂层的整个体积,惰性颗粒的体积分数为5-20%; 涂层外表面的中心平面的平均表面粗糙度Ra为5〜150nm; 并且外表面的部分的峰之间的平均间隔S为100-2,500nm。 版权所有(C)2011,JPO&INPIT