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    • 1. 发明专利
    • BLOCK TYPE AND MULTI-TUBE TYPE GRAPHITE-MADE HEAT EXCHANGER
    • JPH07225095A
    • 1995-08-22
    • JP5436694
    • 1994-02-15
    • TOYO TANSO CONIPPON HYDROGENE KOGYO
    • NOGAMI AKIRABANSHO TAKASHI
    • F28F21/02
    • PURPOSE:To obtain a graphite-made heat exchanger which can be repeatedly used without abrasion while the characteristics of graphite base material and others are kept in the best use, by a method wherein graphite-made heat exchanger elements are molded of isotropic graphite material and the surface layer of the isotropic graphite material is converted to silicone carbide up to a specified depth below the surface. CONSTITUTION:A block type or multi-tube type graphite-made heat exchanger is used in exchanging heat with a fluid containing abrasive particles and its elements are made of isotropic graphite material. In this case, at least the surface layer of the isotropic material which comes in contact with process fluid is converted to silicon carbide up to a depth of 0.2-2.0mm below the surface. Thereby, the graphite-made heat exchanger, which can be repeatedly used without abrasion by fluid containing salt crystals having a low solubility or slurry while the excellent chemical resistant properties of the graphite base material and silicone carbide and the good heat transfer coefficient and workability of the graphite base material are kept in the best use, can be obtained.
    • 3. 发明专利
    • COOKWARE
    • JPH11128084A
    • 1999-05-18
    • JP29434397
    • 1997-10-27
    • TOYO TANSO CO
    • TOJO TETSURONOGAMI AKIRA
    • A47J37/06A47J27/00A47J36/02
    • PROBLEM TO BE SOLVED: To prevent a breakage from easily occurring by joining a porous body to a joining layer with larger joining force even when large thermal expansion difference occurs by heating at the time of cooling or a load is given by the contact of cooking utensils, etc. SOLUTION: A cookware is provided with a black lead base body 2 consisting of a porous body which is formed in a prescribed shape so as to hold cooked food 1 and the joining layer 3 which is formed at a cooking surface 9 side being brought into contact with cooked food 1 in the black lead base body 2 and which consists of a low molcular weight fluororesin which intrudes to gaps 10 exposed on a cooking surface 9. On the front surface of the joining layer 3, projecting and recessed shapes are formed and an intermediate layer 7 consisting of a high molcular weight flororesin, a buffering layer 5 consisting of the high molcular weight fluororesin containing a buffering member 4 and a front surface layer 6 consisting of the low molcular weight and high molcular weight fluororesins are formed in order.
    • 4. 发明专利
    • PURIFICATION OF SILICON CARBIDE-BASED MOLDED PRODUCT
    • JPH10245266A
    • 1998-09-14
    • JP5003697
    • 1997-03-05
    • TOYO TANSO CO
    • KIKU HIDEKINOGAMI AKIRA
    • C04B41/80C04B35/565
    • PROBLEM TO BE SOLVED: To efficiently remove impurities in a molded product without causing the deterioration in strength of the molded product itself according to a simple method by forming an Si membrane on the surface of a silicon carbide-based molded product according to a chemical vapor deposition(CVD) method, then heat-treating the formed membrane, diffusing and adsorbing the impurities into the Si membrane and removing the whole membrane by an etching method. SOLUTION: The surface of a silicon carbide-based molded product having the surface comprising silicon carbide is coated with an Si membrane according the a CVD method and the formed membrane is then heat-treated at >=1,000 deg.C for several to some ten hr to diffuse and adsorb impurities in the interior of the molded product into the Si membrane. The whole Si membrane into which the impurities are diffused and adsorbed is subsequently removed by a dry or a wet etching method. A mixed gas containing a halogen is preferably used as a washing medium in the dry etching method and a solution containing the halogen is preferably used as a washing medium in the wet etching method. The silicon carbide-based molded product obtained by the method is suitably used as a constituent member for producing semiconductors.