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1. 发明专利

JPH04253763A FLAME-RETARDANT POLYESTER COMPOSITION 失效
公开(公告)号：JPH04253763A
公开(公告)日：1992-09-09
申请号：JP3342191
申请日：1991-02-04
申请人： TEIJIN LTD
发明人： OSHINO HIROJI , SUZUOKA AKIHIRO , SHIMOMA AKIRA
IPC分类号： C08K5/02 , C08K9/00 , C08L67/00 , C08L67/02
摘要： PURPOSE:To provide the title composition which has an excellent flame retardation and well-balanced properties, is superb in melt stability in molding, is neither thickened nor gels, has improved moldability (fluidity, prevention of mold staining and mold corrosion, etc.) and further can produce flame-retardant moldings excellent in flame retardation, heat resistance and mechanical strengths by employing, as a flame-retardant assistant, an antimony compound treated with a basic compound and hence reduced in its acidity. CONSTITUTION:A flame-retardant polyester composition comprising a thermoplastic polyester, an organohalogen compound, and an antimony compound treated with a basic compound.

2. 发明专利

JPH04175367A POLYESTER RESIN COMPOSITION 失效
公开(公告)号：JPH04175367A
公开(公告)日：1992-06-23
申请号：JP30245690
申请日：1990-11-09
申请人： TEIJIN LTD
发明人： HATAYAMA TOSHIO , SUZUOKA AKIHIRO , SHIMOMA AKIRA
IPC分类号： C08L67/02 , C08L67/00
摘要： PURPOSE:To improve wet-heat resistance, impact strength, and flexibility by compounding polybutylene naphthalenedicarboxylate with a specific copolymer. CONSTITUTION:100 pts.wt. resin compsn. comprising 60-99.5wt.% polybutylene naphthalenedicarboxylate (e.g. polybutylene 2, 6-naphthalenedicarboxylate) and 0.5-40wt.% copolymer consisting of 70-99.5 pts.wt. alpha-olefin, 0.5-20 pts.wt. glycidyl methacrylate, and 0-30 pts.wt. vinyl acetate (the sum being 100 pts.wt.) is compounded with 0-150 pts.wt. inorg. filler (e.g. carbon black).

3. 发明专利

JPS6161028B2 失效
公开(公告)号：JPS6161028B2
公开(公告)日：1986-12-23
申请号：JP522080
申请日：1980-01-22
申请人： TEIJIN LTD
发明人： OKUDAIRA TOSHIBUMI , SUZUOKA AKIHIRO
IPC分类号： F26B17/12

4. 发明专利

JPS5911705B2 JPS5911705B2 - 失效
公开(公告)号：JPS5911705B2
公开(公告)日：1984-03-17
申请号：JP599479
申请日：1979-01-24
申请人： Teijin Ltd
发明人： SUZUOKA AKIHIRO , TAKANO HIROSHI
IPC分类号： H05B6/14 , D02J1/22 , D02J13/00

5. 发明专利

JPS5945107A Storing of polyester grnule 失效
标题翻译：聚酯树脂的储存
公开(公告)号：JPS5945107A
公开(公告)日：1984-03-13
申请号：JP15451382
申请日：1982-09-07
申请人： Teijin Ltd
发明人： SUZUOKA AKIHIRO , YAMAUCHI SHINICHI , SOGA AKIRA
IPC分类号： B29B15/00 , B29B9/00 , B29B13/00 , B29B13/06
CPC分类号： B29B13/065
摘要： PURPOSE:To prevent the moisture content rate of granules during in-stock from increasing, when polyester granules having alkilene terephthalate as the main recurring unit are stored, by a method wherein directly after polymerized polyester is formed into granules, the skin at least of the granules is crystallized. CONSTITUTION:Polyethylene terephthalate obtained by melt-polymerizing dimethyl terephthalate and ethylene glycol is discharged, cooled and then cut to obtain cylindrical pellets having a diameter 3mm. and a length 4mm. each. These pellets are divided into units of 300g. These units are brought into crystallizing treatment at 110-180 deg.C, in heated steam for 2-5sec. Then, each sample is put in a beaker of 500cc, the upper portion of the beaker is kept open, left for a prescribed time in a room with a relative humidity 65%, a temperature 23 deg.C and then the hygroscopic amount is measured. After being stored for seven more days, pellets are dried for 3hr on a fluidized bed in hot air of 150 deg.C, the moisture rate of the pellets is maeasured to obtain always good results of approx. 0.005%.
摘要翻译：目的：为了防止原料中颗粒的水分含量增加，当以对苯二甲酸对苯二甲酸酯为主要重复单元的聚酯颗粒储存时，通过聚合聚酯直接形成颗粒的方法，至少在颗粒结晶。组成：将通过熔融聚合对苯二甲酸二甲酯和乙二醇酯得到的聚对苯二甲酸乙二醇酯进行排出，冷却，然后切割，得到直径为3mm的圆柱形颗粒。长度4mm。每。这些颗粒分为300g的单位。将这些单元在110-180℃，加热蒸汽中进行结晶处理2-5秒。然后，将各样品放入500cc的烧杯中，将烧杯的上部保持打开，在相对湿度65％，温度23℃的室内放置规定时间，然后测量吸湿量。再储存7天后，将颗粒在150℃的热空气中在流化床上干燥3小时，使颗粒的水分率达到约为 0.005％。

6. 发明专利

JPS5945106A Crystallized polyester granule and preparation thereof 失效
标题翻译：结晶聚酯纤维及其制备
公开(公告)号：JPS5945106A
公开(公告)日：1984-03-13
申请号：JP15451282
申请日：1982-09-07
申请人： Teijin Ltd
发明人： SUZUOKA AKIHIRO , YAMAUCHI SHINICHI , SOGA AKIRA
IPC分类号： B29B15/00 , B29B9/00 , B29B13/00 , B29B13/06
CPC分类号： B29B13/065
摘要： PURPOSE:To prevent mutual gluing of granules that appear at the drying time and the solid state polymerizing time of the granules by a method wherein a crystallized layer with a thickness 20omega or more is prepared only on the surface area of the granules composed of polyester having alkilene terephthalate as the main recurring unit and treated under a condition satisfying the specific relation formula by heated steam of 110 deg.C or higher. CONSTITUTION:The specific relation formula in the heated steam treatment is as follows: 300>=H>=A/T (wherein H: treating time in sec, T: temperaure in deg.C, A: coefficient about crystal layer thickness t, indicated by formula A=exp(at+b) wherein a is 0.01-0.05 and b is 1.0-5.0). Dimethyl terephthalate and ethylene glycol are molten polymer to obtain granules of polyethlene terephthalate. They are exposed to the atmosphere of heated steam for a short time under the above-mentioned relational condition. Then, they are heated and dried from 180 deg.C to 230 deg.C for three hours under reduced pressure and polymerized in solid state to obtain polyester chips the hang-up rate thereof is almost zero.
摘要翻译：目的：为了防止在干燥时出现的颗粒和颗粒的固态聚合时间相互粘合，其中仅在由聚酯构成的颗粒的表面积上制备厚度为20μm以上的结晶层，以对苯二甲酸对苯二酸酯为主要重复单元，在满足特定关系式的条件下，通过加热蒸汽为110℃以上进行处理。构成：加热蒸汽处理中的具体关系式如下：300> = H> = A / T（其中H：处理时间（秒），T：温度℃，A：关于晶体层厚度t的系数，由式A = exp（at + b）表示，其中a为0.01-0.05，b为1.0-5.0）。对苯二甲酸二甲酯和乙二醇是熔融聚合物，以获得聚对苯二甲酸乙二醇酯的颗粒。在上述关系条件下，它们在短时间内暴露于加热蒸汽的气氛中。然后，将它们从180℃加热至230℃，减压干燥3小时，并以固态聚合得到聚酯切片，其悬挂速率几乎为零。

7. 发明专利

JPH0420560A POLYESTER RESIN COMPOSITION 失效
公开(公告)号：JPH0420560A
公开(公告)日：1992-01-24
申请号：JP12300990
申请日：1990-05-15
申请人： TEIJIN LTD
发明人： HATAYAMA TOSHIO , SHIMOMA AKIRA , SUZUOKA AKIHIRO
IPC分类号： C08K7/14 , C08L67/00 , C08L67/02
摘要： PURPOSE:To prepare the title compsn. giving a molded article excellent in resistance to wet heat aging, dimensional stability, etc., by mixing a polybutylene naphthalenedicarboxylate with glass fibers having a specified mean length in a specified wt. ratio. CONSTITUTION:95-50wt.% polybutylene naphthalenedicarboxylate (e.g. polybutylene 2, 6-naphthalenedicarboxylate) is mixed with 5-50wt.% glass fibers having a mean length of 0.1mm or higher to give the title compsn., which is suitably used for preparing an electric, electronic, or mechanical part. The polybutylene naphthalenedicarboxylate is prepd. by reacting naphthalenedicarboxylic acid with 1, 4-butanediol, and, if necessary, an acid component other than naphthalenedicarboxylic acid, such as isophthalic acid or terephthalic acid, may be added to the reaction system.

8. 发明专利

JPH01261453A RESIN COMPOSITION 失效
公开(公告)号：JPH01261453A
公开(公告)日：1989-10-18
申请号：JP8815288
申请日：1988-04-12
申请人： TEIJIN LTD
发明人： ONODERA TAMIO , SUZUOKA AKIHIRO
IPC分类号： C08L67/00 , C08K3/22 , C08K5/02
摘要： PURPOSE:To make it possible to form a flame-retarding resin composition markedly decreased in coloring (blackening) when molten by heating and excellent in heat stability, by mixing a thermoplastic polyester with an organohalogen compound and antimony trioxide subjected to a specified treatment. CONSTITUTION:This composition comprises a thermoplastic polyester (A), an organohalogen compound (B) and antimony trioxide (C), wherein the antimony trioxide is one subjected to heat treatment in an oxygen-containing stream. It is preferable that this heat treatment be performed at 350-500 deg.C in a gas stream containing at least 5vol% oxygen. This composition comprises 100 pts.wt. component A, 1-30 pts.wt. (in terms of the halogen atoms) component B and 1-20 pts.wt. (in terms of the antimony atoms) component C.

9. 发明专利

JPS61266428A PRODUCTION OF POLYESTER 失效
公开(公告)号：JPS61266428A
公开(公告)日：1986-11-26
申请号：JP10706785
申请日：1985-05-21
申请人： TEIJIN LTD
发明人： KONO TAKATERU , SUZUOKA AKIHIRO
IPC分类号： C08G63/00 , C08G63/16
摘要： PURPOSE:To decrease scale which deposits inside a polyester production apparatus, by irradiating the apparatus with ultrasonic waves during esterification or transesterification of a dicarboxylic acid with a glycol. CONSTITUTION:In a process for producing a polyester by subjecting a dicarboxylic acid and/or its derivative and a glycol to esterification or transesterification and polycondensing the product, the reaction zone is irradiated with ultrasonic waves during, among all of the steps of this process, at least an esterification or transesterification step. Said irradiation with ultrasonic waves may be performed throughout the entire process of the polyester production process and, especially, it is preferable that such irradiation is performed during both of an esterification or transesterification step and a prepolymerization step. It is preferable to perform such irradiation continuously from the start of esterification or transesterification. As the ultrasonic waves for irradiation, those having a frequency of 10-200kHz and a power of 0.5-10kW are desirable.

10. 发明专利

JPS5927211B2 JPS5927211B2 - 失效
公开(公告)号：JPS5927211B2
公开(公告)日：1984-07-04
申请号：JP9090778
申请日：1978-07-27
申请人： Teijin Ltd
发明人： SUZUOKA AKIHIRO
IPC分类号： B01D39/12 , B01D39/14 , B01D39/20 , D01D1/10

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