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    • 2. 发明专利
    • Polymer and organic thin film and organic thin film element using the same
    • 聚合物和有机薄膜和有机薄膜元件
    • JP2012193338A
    • 2012-10-11
    • JP2011256446
    • 2011-11-24
    • Sumitomo Chemical Co LtdOsaka Univ住友化学株式会社国立大学法人大阪大学
    • IE HIROTAKAKO TATEAKIKARAKAWA MAKOTOASO YOSHIOUEDA MASAHITO
    • C08G61/12H01L21/337H01L21/338H01L29/786H01L29/808H01L29/812H01L31/10H01L51/05H01L51/30H01L51/42
    • H01L51/0043C08G2261/3243C08G2261/344C08G2261/91C08G2261/92C08G2261/95H01L51/0036H01L51/0094H01L51/0541H01L51/0545H01L51/055H01L51/0554Y02E10/549
    • PROBLEM TO BE SOLVED: To provide a polymer having excellent hole transporting property.SOLUTION: The polymer includes a structural unit expressed by formula (1) and a structural unit expressed by formula (2). In the formulas, Xand Xeach independently represent an oxygen atom, a sulfur atom or a group expressed by =C(A)(where A represents a hydrogen atom, a halogen atom or a monovalent organic group optionally having a substituent, and two of A may be the same or different from each other); Y represents a carbon atom, silicon atom, germanium atom, titanium atom or tin atom; R, R, Rand Reach independently represent a hydrogen atom, a halogen atom, a linear, branched, or cyclic alkyl group having 1 to 30 carbon atoms (however, a part of or all of hydrogen atoms in the alkyl group may be substituted with halogen atoms), or a group other than alkyl groups and containing a linear, branched or cyclic alkyl group having 1 to 30 carbon atoms; and Arand Areach independently represents a trivalent aromatic hydrocarbon group having 6 to 60 carbon atoms and optionally having a substituent, or a trivalent aromatic heterocyclic group having 4 to 60 carbon atoms and optionally having a substituent. However, when Y is a carbon atom, Arand Arare trivalent aromatic heterocyclic groups.
    • 要解决的问题:提供具有优异的空穴传输性的聚合物。 聚合物包括由式(1)表示的结构单元和由式(2)表示的结构单元。 在该式中,X 1 和X 2 各自独立地表示氧原子,硫原子或由= C (A) 2 (其中A表示氢原子,卤素原子或任选具有取代基的一价有机基团,并且A中的两个可以彼此相同或不同 ); Y表示碳原子,硅原子,锗原子,钛原子或锡原子; R 1 ,R 2 ,R 3 ,R 4 各自独立地表示氢原子,卤素原子,具有1至30个碳原子的直链,支链或环状烷基(然而,烷基中的一部分或全部氢原子 可以被卤素原子取代)或除烷基以外的基团,并且含有具有1至30个碳原子的直链,支链或环状烷基; 和Ar 2 ,Ar 3 各自独立地表示具有6至60个碳原子并且任选具有取代基的三价芳族烃基, 或碳原子数为4〜60的任选具有取代基的3价芳香族杂环基。 然而,当Y是碳原子时,Ar 2 和Ar 3 是三价芳族杂环基。 版权所有(C)2013,JPO&INPIT