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1. 发明专利

JP2013006833A Cerium complex and organic electronic element containing the cerium complex 审中-公开
标题翻译： CERIUM复合物和含有复合物的有机电子元件
公开(公告)号：JP2013006833A
公开(公告)日：2013-01-10
申请号：JP2012117987
申请日：2012-05-23
申请人： Sumitomo Chemical Co Ltd , 住友化学株式会社
发明人： KURAMOCHI YUSUKE , KOBAYASHI NORIFUMI , HIGASHIMURA HIDEYUKI
IPC分类号： C07F5/00 , C07D403/14 , C09K11/06 , H01L51/50
CPC分类号： C07D403/14 , C07F5/00 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1044 , C09K2211/1059 , C09K2211/185 , H01L51/0089 , H01L51/5012 , H05B33/10
摘要： PROBLEM TO BE SOLVED: To provide a cerium complex excellent in electron acceptability and hole acceptability.SOLUTION: The cerium complex is expressed by composition formula (1). In the formula, M represents a cerium ion; A represents a carbon atom, silicon atom, nitrogen atom, nitrogen cation, boron anion, phosphorus atom, or P(=O); when z is 4, m is 1 to 4 and when z is 3, m is 1 to 3; D represents a direct bond or a hydrocarbondiyl group; G represents a heterocyclyl group or a hydrogen atom; L represents a group that contains an aromatic six-membered ring having two or more nitrogen atoms; X represents a counter ion; L' represents a monodentate or bidentate ligand; a represents a number of 1 to 4; b represents a number of 0 to 5; and c represents a number of 0 to 5.
摘要翻译：要解决的问题：提供电子可接受性和孔接受性优异的铈络合物。解决方案：铈配合物由组成式（1）表示。在该式中，M表示铈离子; A表示碳原子，硅原子，氮原子，氮阳离子，硼阴离子，磷原子或P（= O）; 当z为4时，m为1至4，当z为3时，m为1至3; D表示直接键或烃基; G表示杂环基或氢原子; L表示含有具有两个以上氮原子的芳香族六元环的基团。 X表示抗衡离子; L'表示单齿或双齿配体; a代表1到4的数字; b表示0〜5的数; c代表0到5的数字。版权所有（C）2013，JPO＆INPIT

2. 发明专利

JP2012254973A Aliphatic amine-coordinated cerium complex and device containing the complex 审中-公开
标题翻译：辅助胺协调的复合物和包含复合物的装置
公开(公告)号：JP2012254973A
公开(公告)日：2012-12-27
申请号：JP2012109466
申请日：2012-05-11
申请人： Sumitomo Chemical Co Ltd , 住友化学株式会社
发明人： KURAMOCHI YUSUKE , HIGASHIMURA HIDEYUKI
IPC分类号： C07C211/14 , C07C309/06 , C07D487/08 , C07F5/00 , G03F7/11
CPC分类号： C09K11/06 , C07C211/65 , C07C309/06 , C07D487/08 , C07F5/003 , C09K2211/1466 , C09K2211/182 , H01L51/0089 , H01L51/5016
摘要： PROBLEM TO BE SOLVED: To provide a cerium complex emitting light in a visible region, whose luminescence peak locates in the visible region.SOLUTION: This cerium complex has ligands represented by formula (1), formula (2) or the like. In formulae, R is a hydrogen atom or a hydrocarbyl group which may have substituents.
摘要翻译：要解决的问题：提供在可见光区域发光的铈络合物，其发光峰位于可见光区域。解决方案：该铈络合物具有由式（1），式（2）等表示的配体。式中，R为氢原子或可具有取代基的烃基。版权所有（C）2013，JPO＆INPIT

3. 发明专利

JP2012124252A Element including metal complex 有权
标题翻译：元素包括金属复合物
公开(公告)号：JP2012124252A
公开(公告)日：2012-06-28
申请号：JP2010272417
申请日：2010-12-07
申请人： Sumitomo Chemical Co Ltd , 住友化学株式会社
发明人： KURAMOCHI YUSUKE , HIGASHIMURA HIDEYUKI
IPC分类号： H01L51/50 , C07D403/14 , C07F5/00 , C09K11/06
摘要： PROBLEM TO BE SOLVED: To provide a cerium complex having a luminescence peak in a visible light region and sufficiently emitting light in the visible light region, and further to provide an element that includes the complex, thereby sufficiently emitting light in the visible light region.SOLUTION: The present invention provides an element including a metal complex of cerium and a nitrogen atom-containing cyclic compound represented by formula (1). (In the formula, Arepresents a hydrocarbon diyl group that may have a substituent, n represents an integer of 3 or more, Zrepresents a group of -O-, -S-, -NR- or -PR-, while at least one group is a -NR- group, and Rand Rrepresent a hydrocarbyl group that may have a hydrogen atom or a substituent.)
摘要翻译：要解决的问题：提供在可见光区域具有发光峰并在可见光区域中充分发光的铈络合物，并且还提供包含该络合物的元素，从而充分发射可见光的光光区域。解决方案：本发明提供了包含铈的金属配合物和由式（1）表示的含氮原子的环状化合物的元素。（式中，A 1 表示可以具有取代基的烃二基，n表示3以上的整数，Z 1 < / SP>表示-O - ， - S-，-NR 1 - 或-PR 2 至少一个组是-NR 1 - 组，R 1 和R 2 表示可具有氢原子或取代基的烃基）。版权所有（C）2012，JPO＆INPIT

4. 发明专利

JP2010270113A Metal complex containing nitrogen-containing aromatic ring ligand 有权
标题翻译：含金属复合物的含氮的芳族环配体
公开(公告)号：JP2010270113A
公开(公告)日：2010-12-02
申请号：JP2010097602
申请日：2010-04-21
申请人： Sumitomo Chemical Co Ltd , 住友化学株式会社
发明人： KURAMOCHI YUSUKE , HIGASHIMURA HIDEYUKI , KOBAYASHI NORIFUMI
IPC分类号： C07D213/16 , C07D471/04 , C07D471/10 , C07F1/08 , C07F1/10 , C09K11/06 , H01L51/50
CPC分类号： C07D213/16 , C07D471/04 , C07D471/10 , C07F1/005 , C07F9/5022 , C07F9/5325 , C07F9/5765 , C07F9/582 , C07F9/60 , C07F9/62 , C07F9/65068 , C07F9/65335 , C07F9/65515 , C07F9/65517 , C07F9/65522 , C07F9/65683 , C07F9/6596 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/188 , H01L51/0091 , H01L51/0095 , H01L51/5016 , H05B33/14
摘要： PROBLEM TO BE SOLVED: To provide a metal complex useful for synthesizing compounds, as a material for additives, modifiers, batteries, catalysts, sensors, etc., and as a material for organic EL devices, organic transistor devices, organic photoelectric transform devices, etc., and in particular, having high durability (heat resistance) as a light-emitting material. SOLUTION: The metal complex has a conjugate system excellent in charge transferring ability, and includes: a nitrogen-containing aromatic ring ligand having a dendric molecular chain containing a symmetrically or asymmetrically dendrically branched dendron structure or hyperbranched structure; and cuprous (I) ion(s) or silver (I) ion(s). A device containing the metal complex is also provided. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供可用于合成化合物的金属络合物，作为添加剂，改性剂，电池，催化剂，传感器等的材料，以及作为有机EL器件的材料，有机晶体管器件，有机光电转换装置等，特别是具有作为发光材料的高耐久性（耐热性）。解决方案：金属络合物具有优异的电荷转移能力的共轭体系，并且包括：具有包含对称或不对称树枝状枝状结构或超支化结构的树枝状分子链的含氮芳环配体; 和亚铜（I）离子或银（I）离子。还提供了含有金属络合物的装置。版权所有（C）2011，JPO＆INPIT

5. 发明专利

JP2012246230A Cerium complex and organic electronic element containing the same 审中-公开
标题翻译：含有复合物和有机电子元件
公开(公告)号：JP2012246230A
公开(公告)日：2012-12-13
申请号：JP2011117424
申请日：2011-05-25
申请人： Sumitomo Chemical Co Ltd , 住友化学株式会社
发明人： KURAMOCHI YUSUKE , KOBAYASHI NORIFUMI , HIGASHIMURA HIDEYUKI
IPC分类号： C07F5/00 , C07D401/14 , C09K11/06
摘要： PROBLEM TO BE SOLVED: To provide a cerium complex having emission colors in a range of green to yellow and excellent oxygen durability.SOLUTION: The cerium complex is represented by formula (1). In formula (1), M is a cerium ion; L is a ligand represented by formula (2); X is a counter ion; L' is a monodentate or bidentate ligand; (a) is 1 or 2; b is an integer of 0-5; c is an integer of 0-5. In formula (2), Ais a carbon atom or boron atom; Ris a hydrogen atom or substituent; ring A is a five-membered ring containing two nitrogen atoms or ring obtained by condensation of a five-membered ring containing two nitrogen atoms and an aromatic hydrocarbon ring; ring D is a five-membered ring containing one nitrogen atom, a ring obtained by condensation of a five-membered ring containing one nitrogen atom and aromatic hydrocarbon ring, a six-membered ring containing one nitrogen atom or a ring obtained by condensation of a six-membered ring containing one nitrogen atom and an aromatic hydrocarbon ring; ring A and ring D each independently may contain a heteroatom in addition to a nitrogen atom; ring A and ring D each independently may contain a substituent.
摘要翻译：要解决的问题：提供具有绿色至黄色范围内的发光颜色和优异的氧气耐久性的铈络合物。解决方案：铈络合物由式（1）表示。在式（1）中，M为铈离子; L是由式（2）表示的配体; X是抗衡离子; L'是单齿或双齿配体; （a）为1或2; b为0-5的整数; c是0-5的整数。在式（2）中，A 1 是碳原子或硼原子; R 1 是氢原子或取代基; 环A是含有两个氮原子的五元环或通过含有两个氮原子和芳族烃环的五元环缩合获得的环; 环D是含有一个氮原子的五元环，通过含有一个氮原子的五元环和芳族烃环缩合得到的环，含有一个氮原子的六元环或通过含有一个氮原子和芳香烃环的六元环; 环A和环D各自独立地可以含有氮原子以外的杂原子; 环A和环D各自独立地可以含有取代基。版权所有（C）2013，JPO＆INPIT

6. 发明专利

JP2011211142A Thin film, and compound used therein 有权
标题翻译：薄膜及其使用的化合物
公开(公告)号：JP2011211142A
公开(公告)日：2011-10-20
申请号：JP2010122762
申请日：2010-05-28
申请人： Hiroshima Univ , Sumitomo Chemical Co Ltd , Yamaguchi Univ , 住友化学株式会社 , 国立大学法人山口大学 , 国立大学法人広島大学
发明人： OSHITA JOJI , MURAFUJI TOSHIHIRO , KURAMOCHI YUSUKE , HIGASHIMURA HIDEYUKI , KAIKO KEI
IPC分类号： H01L51/50 , C07F9/94 , C08G61/12 , C09K11/06
CPC分类号： C07F9/94 , C09K2211/1029 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/188 , H01L51/0077 , H01L51/5016 , H05B33/145
摘要： PROBLEM TO BE SOLVED: To provide a novel material that uses heavy metal elements having comparatively abundant amounts of resources and exhibits superior light emission properties.SOLUTION: This invention relates to a thin film containing a compound represented by formula (1). In the formula (1), Arand Arare each independently a C3-30 aromatic ring. Rand Rare substituents. (a) and (b) are each independently an integer of 0-12, and when (a) is ≥2, respective R's may be mutually different and two R's may be bonded to form a ring structure. When (b) is ≥2, respective R's may be different from each ther, and two R's may be bonded to form a ring structure. Arepresents any of direct bonds, -O-, -S-, -S(=O)-, -S(=O)-, -PR-, -NR- and -C(-R)-. Eis a C≤50 monovalent group. Lis a C≤50 ligand, and (c) is an integer of 0-3.
摘要翻译：要解决的问题：提供使用具有相对丰富的资源并且具有优异的发光性质的重金属元素的新型材料。解决方案：本发明涉及含有式（1）表示的化合物的薄膜。在式（1）中，Arand Arare各自独立地为C3-30芳环。兰德稀有取代基。（a）和（b）各自独立地为0-12的整数，并且当（a）≥2时，各R可以相互不同，并且两个R可以键合以形成环结构。当（b）≥2时，各R可以不同于每一个，并且两个R可以键合形成环结构。表示直接键合-O - ， - S - ， - S（= O） - ， - S（= O） - ， - PR-，-NR-和-C（-R） - 。 Eis是C≤50的单价组。 Lis为C≤50配体，（c）为0-3的整数。

7. 发明专利

JP2011116748A Metal polydentate ligand complex 有权
标题翻译：金属聚合物配体复合物
公开(公告)号：JP2011116748A
公开(公告)日：2011-06-16
申请号：JP2010238408
申请日：2010-10-25
申请人： Sumitomo Chemical Co Ltd , 住友化学株式会社
发明人： KURAMOCHI YUSUKE , ISHIYAMA TAKESHI , HIGASHIMURA HIDEYUKI
IPC分类号： C07F5/00 , C07D235/14 , C09K11/06 , H01L51/50
CPC分类号： C07D233/64 , C07D235/14 , C07D417/12 , C07F5/003 , C07F5/022 , C07F9/65583 , C09K11/06 , C09K2211/1011 , C09K2211/1014 , C09K2211/1044
摘要： PROBLEM TO BE SOLVED: To provide a metal complex exhibiting excellent durability, and to develop elements exhibiting excellent durability formed using such a metal complex. SOLUTION: There are provided a metal complex containing (a) a polydentate ligand having a denticity of at least five and having a heteroaromatic ring containing at least two atoms selected from the group consisting of nitrogen atoms, oxygen atoms and sulfur atoms, and (b) a metal complex including an ion of a metal selected from the group consisting of cerium, praseodymium, ytterbium, and lutetium; a composition containing the metal complex and a charge transport material; an organic thin film formed using the metal complex or the composition; and an element formed using the metal complex, the composition or the organic thin film. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供显示出优异的耐久性的金属络合物，并且开发出使用这种金属络合物形成的具有优异耐久性的元素。解决方案：提供一种金属络合物，其含有（a）具有至少五个牙齿的牙齿的多齿配体，并具有含有至少两个选自氮原子，氧原子和硫原子的原子的杂芳环，和（b）包括选自铈，镨，镱和镥的金属离子的金属络合物; 含有金属络合物和电荷输送材料的组合物; 使用金属络合物或组合物形成的有机薄膜; 以及使用金属络合物，组合物或有机薄膜形成的元素。版权所有（C）2011，JPO＆INPIT

8. 发明专利

JP2012207018A Metal complex and organic electronic element containing the same 有权
标题翻译：金属复合物和有机电子元件
公开(公告)号：JP2012207018A
公开(公告)日：2012-10-25
申请号：JP2012058381
申请日：2012-03-15
申请人： Sumitomo Chemical Co Ltd , 住友化学株式会社
发明人： KURAMOCHI YUSUKE , HIGASHIMURA HIDEYUKI
IPC分类号： C07D235/14 , C07F5/00 , C09K11/06 , H01L51/50
CPC分类号： C09K11/06 , C07F9/65583 , C09K2211/1029 , C09K2211/1044 , C09K2211/182 , H01L51/0089 , H01L51/5012 , H01L2251/308
摘要： PROBLEM TO BE SOLVED: To provide a metal complex having high solubility with a non-polar solvent and as a result, easily formable of a film by a coating process.SOLUTION: This metal complex is expressed by formula (1) [wherein, M is a cerium ion, praseodymium ion, ytterbium ion or lutetium ion; L is a ligand expressed by formula (2) (wherein, A, Aand Aare each a hydrocarbon-diyl group which may have a substituent, or a direct bond; L, Land Lare each H or a coordinating group, provided that at least one of L, Land Lis a heterocyclyl group which may have a substituent, as the coordinating group); X is a counterion; L' is a mono- or bidentate ligand; (a) is a positive number; and (b) and (c) are each a ≥0 number].
摘要翻译：要解决的问题：提供一种与非极性溶剂具有高溶解度的金属络合物，结果可以通过涂布方法容易地形成膜。解决方案：该金属络合物由式（1）表示[其中，M为铈离子，镨离子，镱离子或镥离子; L是由式（2）表示的配体（其中，A 1 ，A 2 和A 3 分别是可以具有取代基或直接键的烃 - 二基; L 1 ，L 2 和L 3 分别为H或协调组，只要L 1 ，L < SP POS =“POST”> 2 和L 3 是可以具有取代基的杂环基作为配位基团）; X是抗衡离子 L'是单或双齿配体; （a）是正数; 和（b）和（c）各自为≥0数]。版权所有（C）2013，JPO＆INPIT

9. 发明专利

JP2012092090A Metal complex and light-emitting device using metal complex 有权
标题翻译：使用金属复合材料的金属复合和发光器件
公开(公告)号：JP2012092090A
公开(公告)日：2012-05-17
申请号：JP2011209027
申请日：2011-09-26
申请人： Hiroshima Univ , Sumitomo Chemical Co Ltd , 住友化学株式会社 , 国立大学法人広島大学
发明人： OSHITA JOJI , KURAMOCHI YUSUKE , HIGASHIMURA HIDEYUKI , KOBAYASHI NORIFUMI
IPC分类号： C07F1/12 , C07F9/6596 , C07F19/00 , C09K11/06 , H01L51/50
CPC分类号： C07F9/6561 , C07F9/65335 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1088 , C09K2211/1096 , C09K2211/188 , H01L51/0091 , H01L51/5016 , H05B33/10
摘要： PROBLEM TO BE SOLVED: To provide a light-emitting device which indicates high light-emission efficiency.SOLUTION: A metal complex is provided which has a structure represented by formula (1).

10. 发明专利

JP2010192887A Organic electroluminescent device 有权
标题翻译：有机电致发光器件
公开(公告)号：JP2010192887A
公开(公告)日：2010-09-02
申请号：JP2010010199
申请日：2010-01-20
申请人： Sumitomo Chemical Co Ltd , 住友化学株式会社
发明人： KURAMOCHI YUSUKE , KOBAYASHI NORIFUMI , HIGASHIMURA HIDEYUKI
IPC分类号： H01L51/50 , C07F1/08 , C07F1/10 , C09K11/06
CPC分类号： C07D213/18 , C07D233/58 , C08G61/02 , C08G61/10 , C08G61/12 , C08G2261/312 , C08G2261/3142 , C08G2261/3162 , C08G2261/5242 , C09K11/06 , C09K2211/1029 , C09K2211/1044 , C09K2211/1466 , C09K2211/188 , H01L51/0035 , H01L51/0037 , H01L51/004 , H01L51/0091 , H01L51/5012 , H05B33/14
摘要： PROBLEM TO BE SOLVED: To provide an organic electroluminescent device having superior durability with respect to oxygen.
SOLUTION: An organic electroluminescent device which includes a pair of electrodes consisting of an anode and a cathode and, sandwiched therebetween, an organic layer containing a metal coordination compound represented by formula (1), ML
a X
b (1). In the formula (1), the M is a metal ion in the group 11 of the periodic table, the L is a ligand represented by formula (2), and the X is an anion. The (a) is a number of 0 1 , k
1 , m
1 , A, D
1 , Q
1 and Q
2 are predetermined. In the formula (3) or the formula (4), X
1 , X
2 , X
3 , X
4 , X
5 , R
1 , R
5 , R
6 and R
9 are predetermined.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种相对于氧具有优异的耐久性的有机电致发光器件。解决方案：一种有机电致发光器件，其包括由阳极和阴极组成的一对电极，并夹在其间，含有由式（1）表示的金属配位化合物的有机层，ML a X b'/ SB>（1）。在式（1）中，M是周期表第11族中的金属离子，L是由式（2）表示的配体，X是阴离子。（a）为0 1 ，k 1 ，m 1 ，A，D 1 ，Q 1 和Q 2 。在式（3）或式（4）中，X 1 ，X 2 ，X 3 ，X SP>，X 5 ，R 1 ，R 5 ，R 6 和R SP>是预定的。版权所有（C）2010，JPO＆INPIT

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