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    • 7. 发明专利
    • Manufacturing method of positive electrode active material, and positive electrode active material
    • 正极活性材料的制造方法和正极电极活性材料
    • JP2010009960A
    • 2010-01-14
    • JP2008168473
    • 2008-06-27
    • Sony Corpソニー株式会社
    • WATANABE HARUOOYAMA YUUDAIAZUMA HIDETOFUJITA SHIGERU
    • H01M4/525C01G53/00H01M4/36
    • Y02P70/54
    • PROBLEM TO BE SOLVED: To provide a positive electrode active material which has a high charge current capacity and superior charge/discharge efficiency. SOLUTION: The positive electrode active material is made, by making a sulfate adhere on a composite oxide particle which is mainly composed of lithium nickelate. In a secondary battery that uses the positive electrode active material fabricated by such a method and containing carbonate ions whose content is made 0.15 wt.% or lower, gas generation in the battery can be suppressed. A heat treatment is carried out at a temperature of 150°C or higher and 1,200°C or lower. The sulfate to be used is ammonium sulfate, lithium sulfate or a mixed salt thereof. The sulfate of 0.01 pt.wt. or higher and 20 pts.wt. or lower with respect to 100 pts.wt. of the composite oxide particle is made to adhere and is heat treated. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供具有高充电电流容量和优异的充电/放电效率的正极活性材料。 解决方案:通过使硫酸盐粘附在主要由镍酸锂组成的复合氧化物颗粒上而制成正极活性物质。 在使用由这种方法制造并含有0.15重量%以下的碳酸根离子的正极活性物质的二次电池中,可以抑制电池中的气体产生。 在150℃以上且1200℃以下的温度下进行热处理。 所使用的硫酸盐是硫酸铵,硫酸锂或其混合盐。 硫酸盐为0.01重量份 或更高和20重量 或更低,相对于100重量份 的复合氧化物颗粒被粘附并进行热处理。 版权所有(C)2010,JPO&INPIT