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    • 10. 发明专利
    • NONAQUEOUS ELECTROLYTE SECONDARY BATTERY
    • JPH03233870A
    • 1991-10-17
    • JP2689990
    • 1990-02-06
    • SANYO ELECTRIC CO
    • FURUKAWA SANEHIRONOMA TOSHIYUKIYAMAMOTO YUJI
    • H01M4/02H01M4/36H01M4/505H01M10/05H01M10/052H01M10/0566
    • PURPOSE:To enhance a cycle characteristic of a nonaqueous electrolyte secondary battery by using as the active material of a positive electrode an active material of large discharge capacity at the center portion, and an active material of small discharge capacity at the peripheral portion of the electrode. CONSTITUTION:A nonaqueous electrolyte secondary battery has a negative electrode 2 made from lithium or lithium alloy, a positive electrode 1 and a separator 3 interposed between the positive and negative electrodes, and as the active material of the positive electrode 1 an active material of large discharge capacity is used at the center portion and an active material of small discharge capacity is used at the peripheral portion thereof. The discharge capacity per unit area of the positive electrode 1 is smaller at the peripheral portion than at the center portion and so the utilization factor of active material in the negative electrode 2 is smaller at the peripheral portion than at the center portion of the electrode 2. the utilization factor of the active material is thus reduced at the peripheral portion of the negative electrode where current tends to be concentrated by edge effect and so the growth of dendritic crystals of lithium or conversion of the lithium alloy into powder at the peripheral portion of the negative electrode is restrained. The cycle characteristic of the battery is thereby enhanced.