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    • 2. 发明专利
    • Reversible thermal color developing composition and reversible thermal recording medium using it
    • 可反射的热色发展组合物和可逆的热记录介质
    • JP2008036934A
    • 2008-02-21
    • JP2006213217
    • 2006-08-04
    • Ricoh Co Ltd株式会社リコー
    • FURUYA HIROMIYAMAMOTO SATOSHIOKADA NORITOMO
    • B41M5/337B41M5/333
    • PROBLEM TO BE SOLVED: To provide a reversible thermal recording medium having high speed erasing properties capable of corresponding to a thermal head erasing and having a high utility. SOLUTION: The reversible thermal color developing composition capable of forming relatively a color developing condition and a color erasing condition based on the differences of heating temperatures and/or cooling speeds after heating by using an electron-donating coloring compound and an electron-accepting compound, is characterized by comprising at least one kind of Zwitter ion-containing compounds in which the total electric charge in the molecule is 0 as a color developing/color erasing controlling agent, and a hetero-group-containing aliphatic hydrocarbon compound having at least one hetero-group consisting of a 6-24C aliphatic hydrocarbon group and carbonyl group, amino group, ether group, thioether group, sulfoxide group, sulfonyl group alone or a combination thereof. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供具有能够对应于热头擦除并且具有高效用的高速擦除特性的可逆热记录介质。 解决方案:通过使用给电子着色化合物和电子发射化合物,能够基于加热温度和/或冷却速度的差异形成相对于显色条件和消色条件的可逆热色彩显影组合物, 其特征在于,包含至少一种含有Zwitter离子的化合物,其中分子中的总电荷为0,作为显色/消色控制剂,以及含杂基的脂族烃化合物,其具有 由6-24C脂族烃基和羰基,氨基,醚基,硫醚基,亚砜基,单独的磺酰基或其组合组成的至少一个杂基。 版权所有(C)2008,JPO&INPIT
    • 3. 发明专利
    • Reversible multi-color thermal recording medium
    • 可反复多色热记录介质
    • JP2007098735A
    • 2007-04-19
    • JP2005290635
    • 2005-10-04
    • Ricoh Co Ltd株式会社リコー
    • FURUYA HIROMIOKADA NORITOMOYAMAMOTO SATOSHITSUTSUI KYOJI
    • B41M5/34B41M5/28B41M5/30B41M5/333B41M5/337B41M5/46
    • B41M5/305
    • PROBLEM TO BE SOLVED: To provide a reversible multi-color thermal recording medium which has high color developing/decoloring sensitivity and excellent image uniformity. SOLUTION: This reversible multi-color thermal recording medium 1 is composed of an electron-donative coloring compound and an electron-receptive compound formed on a support 10. In addition, the recording medium 1 has a reversible thermal recording layer which can relatively create a state of color development and a state of decoloration, depending on the difference in a heating temperature and/or a cooling rate after heating. The thermal recording layers 11, 12 and 13 contain a photothermal conversion material which absorbs a light of a specific wavelength range and develops a heat, and further, contains a fine particle of zinc oxide with 10 nm or above and 100 nm or below particle diameter. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供具有高显色/脱色灵敏度和优异图像均匀性的可逆多色热记录介质。 解决方案:该可逆多色热记录介质1由形成在载体10上的给电子着色化合物和电子接受性化合物构成。此外,记录介质1具有可逆热记录层,其可以 根据加热温度的差异和/或加热后的冷却速度,相对地形成显色状态和脱色状态。 热敏记录层11,12,13含有吸收特定波长范围的光并发热的光热转换材料,并且还含有10nm以上且100nm以下的粒径的氧化锌微粒 。 版权所有(C)2007,JPO&INPIT
    • 4. 发明专利
    • Reversible thermal recording medium
    • 可逆热记录介质
    • JP2006289958A
    • 2006-10-26
    • JP2006061885
    • 2006-03-07
    • Ricoh Co Ltd株式会社リコー
    • YAMAMOTO SATOSHITSUTSUI KYOJIFURUYA HIROMIOKADA NORITOMO
    • B41M5/333B41M5/28B41M5/30B41M5/337B41M5/40G09F3/02
    • PROBLEM TO BE SOLVED: To provide a reversible thermal recording medium which exhibits good color developing sensitivity and is excellent in heat-resistant shelf stability of an image part. SOLUTION: The reversible thermal recording medium having a reversible thermal recording layer capable of relatively forming a color developing condition and a color erasing condition by using an electron-donating color developing compound and an electron-accepting compound on a substrate and depending on a difference between heating temperature and/or cooling speed after heating, uses a phenol compound expressed by formula (1) (wherein l is an integer of 1-3 and m is an integer of at least 23) as the electron-accepting compound. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供显示出良好的显色灵敏度并且具有优异的图像部分的耐热储存稳定性的可逆热记录介质。 解决方案:具有能够相对形成彩色显影条件的可逆热记录层的可逆热记录介质和通过在基板上使用给电子显色化合物和电子接受性化合物的颜色消除条件,并且取决于 加热后的加热温度和/或冷却速度的差别使用由式(1)表示的酚化合物(其中l为1-3的整数,m为至少23的整数)作为电子接受性化合物。 版权所有(C)2007,JPO&INPIT
    • 5. 发明专利
    • Reversible thermosensitive recording medium, member with information recording part, reversible thermosensiitve recording label and their image processing method
    • 具有信息记录部分的可反复记录记录介质,可逆温度记录标签及其图像处理方法
    • JP2006076120A
    • 2006-03-23
    • JP2004262286
    • 2004-09-09
    • Ricoh Co Ltd株式会社リコー
    • FURUYA HIROMITSUTSUI KYOJIOKADA NORITOMOYAMAMOTO SATOSHIHAYAKAWA KUNIOKAWAHARA MASAYASHINPO HITOSHI
    • B41M5/337B41M5/333G09F3/02
    • PROBLEM TO BE SOLVED: To provide a reversible thermosensitive recording medium with a reversible thermosensitive recording layer, which has high color developing properties, is excellent in high-speed erasability and can cope with the high-speed decoloration under low temperature and low humid environments, a member such as a card having an information recording part including the reversible thermosensitive recording layer, a reversible thermosensitive recording label and these image processing method. SOLUTION: In the reversible thermosensitive recording medium having the reversible thermosensitive recording layer, in which an electron donative coloring compound and an electron accepting compound are employed on a support so as to allow to form states relatively color-developed and decolorized due to the difference in heating temperature and/or in the cooling speed after heating, as the electron accepting compound, a phenolic compound expressed by general formula (1), wherein n is an integer of at least 8 and m is an integer larger than 1/3 of n, is employed. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了提供具有高显色性的可逆热敏记录层的可逆热敏记录介质,具有优异的高速擦除性,并且可以在低温低温下应对高速脱色 潮湿环境,诸如具有包括可逆热敏记录层的信息记录部分的卡的成员,可逆热敏记录标签和这些图像处理方法。 解决方案:在具有可逆热敏记录层的可逆热敏记录介质中,其中在载体上使用给电子着色化合物和电子接受性化合物,以便允许形成相对发色和脱色的状态,由于 加热温度和/或加热后的冷却速度的差异作为电子接受性化合物,由通式(1)表示的酚类化合物,其中n为至少8的整数,m为大于1 / 3的n,被雇用。 版权所有(C)2006,JPO&NCIPI
    • 6. 发明专利
    • Ink composition for writing in reversible recording medium, method for rewriting in the same, and rewritable recording device
    • 用于写入可逆记录介质的墨水组合物,用于在其中记录的方法和可记录记录装置
    • JP2004269669A
    • 2004-09-30
    • JP2003061763
    • 2003-03-07
    • Mitsubishi Pencil Co LtdRicoh Co Ltd三菱鉛筆株式会社株式会社リコー
    • TSUTSUI KYOJIFURUYA HIROMISHIBUYA TAKESHIHATTORI HITOSHIOKUMA TAKASHIIDENAWA HIROYUKIYOSHIOKA YASUSHI
    • B41J2/32B41M5/337C09D11/02C09D11/033C09D11/037C09D11/16C09D11/17
    • PROBLEM TO BE SOLVED: To obtain an ink composition for printing an image in a reversible recording medium, not to be easily removed when the image is to be kept in a document but to be assuredly removed for the erasure of the image when rewriting is required, and capable of rewriting.
      SOLUTION: The ink composition is for writing on the surface of the reversible recording medium wherein image formation and erasure are reversible upon energy application, and it contains as its main components at least coloring matter, an alcohol-soluble resin, a nonionic surfactant, and a lower alcohol. Concerning drawn lines drawn with the ink composition and then dried on the surface of an evaluation standard surface sheet having a dynamic advance contact angle of 86.0±2.0° relative to distilled water and a dynamic rearward contact angle of 78.0±2.0° relative to the same, (1) the shrinkage rate in the width of the drawn lines is
    • 要解决的问题:为了获得用于在可逆记录介质中打印图像的油墨组合物,当图像保持在文档中时不容易去除,而是为了擦除图像而被确实地去除, 需要重写,并能重写。 解决方案:油墨组合物用于在可逆记录介质的表面上书写,其中成像和擦除在能量施加时是可逆的,并且其含有至少着色物质,醇溶性树脂,非离子表面活性剂 表面活性剂和低级醇。 关于用油墨组合物画出的画线,然后在相对于蒸馏水具有86.0±2.0°的动态前进接触角和相对于蒸馏水的动态向后接触角为78.0±2.0°的评价标准表面片的表面上干燥 ,(1)拉伸线宽度的收缩率比干燥前的收缩率低20%,(2)在粘接玻璃纸胶带辅助的165°剥离试验中,(a)拉伸线附着率为 以30mm / sec的速度进行剥离时为≤10%,(b)以0.3mm / sec的速度进行剥离时,拉伸线附着率≥80%。 版权所有(C)2004,JPO&NCIPI
    • 10. 发明专利
    • Reversible heat-sensitive color-developing composition and reversible heat-sensitive recording medium using the composition
    • 使用组合物的可反应的热敏颜料显影组合物和可反应的热敏记录介质
    • JP2008149633A
    • 2008-07-03
    • JP2006341731
    • 2006-12-19
    • Ricoh Co Ltd株式会社リコー
    • YAMAMOTO SATOSHIFURUYA HIROMIOKADA NORITOMO
    • B41M5/337B41M5/333
    • PROBLEM TO BE SOLVED: To provide a reversible heat-sensitive composition which has high-color development/decoloring characteristics, rapid erasability, heat-resistant shelf stability, high sensitivity characteristics and also, is almost free from texture staining, hence high visibility, and a reversible heat-sensitive recording medium. SOLUTION: This reversible heat-sensitive color-developing composition is composed of an electron donating/coloring compound and an electron accepting compound and can relatively form a color developing state and a decoloring state depending on the difference in heating temperature and/or cooling rate after heating. For the electron accepting compound, a phenol compound represented by formula (1) is used and for a color development/decoloring controlling agent, a chemical compound with Zwitter ions is added. In the formula (1), "l" is an integer of 1 to 3, and "m" is an integer of 23 or above. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供具有高显色/脱色特性,快速擦除性,耐热储存稳定性,高灵敏度特性的可逆热敏组合物,并且几乎没有纹理染色,因此高 可见度和可逆热敏记录介质。 解决方案:该可逆热敏显色组合物由给电子/着色化合物和电子接受性化合物组成,并且可以根据加热温度的差异和/或相对形成显色状态和脱色状态 加热后的冷却速度。 对于电子接受性化合物,使用由式(1)表示的酚化合物,并且对于显色/脱色控制剂,添加具有Zwitter离子的化合物。 式(1)中,“1”为1〜3的整数,“m”为23以上的整数。 版权所有(C)2008,JPO&INPIT