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1. 发明专利

JP2014063592A Dye-sensitized photoelectric conversion element and dye-sensitized solar cell 有权
标题翻译：透明感光元件和透明光敏元件
公开(公告)号：JP2014063592A
公开(公告)日：2014-04-10
申请号：JP2012206966
申请日：2012-09-20
申请人： Peccell Technologies Inc , ペクセル・テクノロジーズ株式会社
发明人： IKEGAMI KAZUSHI , KOJIMA AKIHIRO , KURAKI YASUO
IPC分类号： H01M14/00 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521
摘要： PROBLEM TO BE SOLVED: To provide a dye-sensitized photoelectric conversion element that is small in output variation to illuminance, in a conductive substrate of the dye-sensitized photoelectric conversion element consisting of a plastic conductive substrate.SOLUTION: In a dye-sensitized photoelectric conversion element 1 and a dye-sensitized solar cell having a photoelectrode layer 15 consisting of semiconductor particles dye-sensitized on a conductive photoelectrode substrate, an electrolyte layer 16, a catalyst layer 17, and conductive counter electrode substrate, in this order, an electrode substrate resistance of any one of the conductive photoelectrode substrate and the conductive counter electrode substrate is less than 100 Ω, and a substrate resistance of the other is 100-500 Ω. A ratio (Pmax/Pmax) of a power generation amount (Pmax) at a quantity of light of 100,000 lux to a power generation amount (Pmax) at a quantity of light of 25,000 lux is 1.0-1.5, more preferably, 1.0-1.2.
摘要翻译：要解决的问题：提供由塑料导电基材构成的染料敏化光电转换元件的导电性基板中的输出变化小的染料敏化光电转换元件。解决方案：在染料敏化光电转印元件1和染料敏化太阳能电池，其具有由导电性光电极基板，电解质层16，催化剂层17和导电性对电极基板上染色敏化的半导体粒子构成的光电极层15，依次是电极导电性光电极基板和导电性对电极基板中的任一方的基板电阻小于100Ω，另一方的基板电阻为100〜500Ω。在25万勒克司林的光量为100,000勒克司的光的发电量（Pmax）与发光量（Pmax）的比（Pmax / Pmax）为1.0-1.5，更优选为1.0-1.2 。

2. 发明专利

JP2014056962A Photoelectric conversion element using perovskite compound and method of manufacturing the same 有权
标题翻译：使用PEROVSKITE化合物的光电转换元件及其制造方法
公开(公告)号：JP2014056962A
公开(公告)日：2014-03-27
申请号：JP2012201456
申请日：2012-09-13
申请人： Peccell Technologies Inc , ペクセル・テクノロジーズ株式会社
发明人： KOJIMA AKIHIRO , KISHIMOTO SHINZO , MUKUNOKI YASUO , TESHIMA KENJIRO , IKEGAMI KAZUSHI
IPC分类号： H01L51/42 , H01L31/06
CPC分类号： Y02E10/542 , Y02E10/549 , Y02P70/521
摘要： PROBLEM TO BE SOLVED: To provide a solid-junction solar cell as an alternative to a dye-sensitized solar cell inferior in durability and an organic thin-film solar cell inferior in light resistance and moisture resistance.SOLUTION: A solid-junction photoelectric conversion element has a photoelectric conversion layer between a pair of transparent electrode substrates each comprising a transparent substrate and a transparent electrode layer formed on the transparent substrate. In the photoelectric conversion layer, a first semiconductor layer comprising a carbon nanotube layer on which an organic-inorganic hybrid perovskite compound A is deposited or adsorbed and a second semiconductor layer comprising a carbon nanotube layer on which an inorganic perovskite compound B and/or an organic-inorganic hybrid perovskite compound C is deposited or adsorbed are joined onto the electrode substrates.
摘要翻译：要解决的问题：提供一种固体太阳能电池作为耐久性劣化的染料敏化太阳能电池的替代品以及耐光性和耐湿性差的有机薄膜太阳能电池。解决方案：固体结光电转换元件在一对透明电极基板之间具有光电转换层，每个透明电极基板包括透明基板和形成在透明基板上的透明电极层。在光电转换层中，包含其上沉积或吸附有机 - 无机杂化钙钛矿化合物A的碳纳米管层的第一半导体层和包含碳纳米管层的第二半导体层，其上添加无机钙钛矿化合物B和/或有机 - 无机混合钙钛矿化合物C沉积或吸附在电极基板上。

3. 发明专利

JP2014049631A Photoelectric conversion element using perovskite compound and method of manufacturing the same 有权
标题翻译：使用PEROVSKITE化合物的光电转换元件及其制造方法
公开(公告)号：JP2014049631A
公开(公告)日：2014-03-17
申请号：JP2012191835
申请日：2012-08-31
申请人： Peccell Technologies Inc , ペクセル・テクノロジーズ株式会社
发明人： KOJIMA AKIHIRO , KISHIMOTO SHINZO , TESHIMA KENJIRO , IKEGAMI KAZUSHI
IPC分类号： H01L51/42 , H01L31/06
CPC分类号： Y02E10/542 , Y02E10/549
摘要： PROBLEM TO BE SOLVED: To provide a solid-junction solar cell as an alternative to a dye-sensitized solar cell inferior in durability and an organic thin-film solar cell inferior in light resistance and moisture resistance.SOLUTION: A solid-junction photoelectric conversion element has a photoelectric conversion layer between a pair of transparent electrode substrates each comprising a transparent substrate and a transparent electrode layer formed on the transparent substrate. In the photoelectric conversion layer, a first semiconductor layer obtained by depositing or adsorbing an organic-inorganic hybrid perovskite compound A onto the surface of a porous semiconductor fine particle layer formed on the electrode substrates and a second semiconductor layer formed as a film comprising an inorganic perovskite compound B and/or an organic-inorganic hybrid perovskite compound C are joined together.
摘要翻译：要解决的问题：提供一种固体太阳能电池作为耐久性劣化的染料敏化太阳能电池的替代品以及耐光性和耐湿性差的有机薄膜太阳能电池。解决方案：固体结光电转换元件在一对透明电极基板之间具有光电转换层，每个透明电极基板包括透明基板和形成在透明基板上的透明电极层。在光电转换层中，通过将有机 - 无机混合钙钛矿化合物A沉积或吸附在形成于电极基板上的多孔半导体微粒层的表面上形成的第一半导体层和形成为膜的第二半导体层，所述膜包含无机钙钛矿化合物B和/或有机 - 无机混合钙钛矿化合物C连接在一起。

4. 发明专利

JP2012059613A Method for manufacturing photoelectric conversion element, photoelectric conversion element and photocell 审中-公开
标题翻译：光电转换元件，光电转换元件和光电二极管的制造方法
公开(公告)号：JP2012059613A
公开(公告)日：2012-03-22
申请号：JP2010203189
申请日：2010-09-10
申请人： Peccell Technologies Inc , ペクセル・テクノロジーズ株式会社
发明人： KOJIMA AKIHIRO , IKEGAMI KAZUYUKI
IPC分类号： H01M14/00 , H01L31/04
CPC分类号： Y02E10/542 , Y02E10/549 , Y02P70/521
摘要： PROBLEM TO BE SOLVED: To provide a dye-sensitized solar cell capable of suppressing deterioration in photoelectric conversion characteristics due to generation of a reverse current to exhibit excellent photoelectric conversion efficiency and also excellent in adhesion between a conductive support and a porous semiconductor layer comprising a metal oxide.SOLUTION: In a photoelectrode 1 for a dye-sensitized photoelectric conversion element, a conductive support, an undercoat layer 13, and a metal oxide semiconductor fine particle layer 14 supporting dyes are laminated in the order, and the undercoat layer is formed of a coating film comprising an organic titanium oligomer. The metal oxide semiconductor fine particle layer is formed by laminating a coating film comprising a metal oxide semiconductor fine particle on the undercoat layer when a surface energy of the undercoat layer is less than 50 mN/m.
摘要翻译：解决的问题：提供一种能够抑制由于反向电流的产生而导致的光电转换特性劣化的染料敏化太阳能电池，以显示优异的光电转换效率，并且导电性载体和多孔半导体之间的粘附性优异层包含金属氧化物。解决方案：在用于染料敏化光电转换元件的光电极1中，依次层叠支撑染料的导电性载体，底涂层13和金属氧化物半导体微粒子层14，形成底涂层包含有机钛低聚物的涂膜。当底涂层的表面能小于50mN / m时，通过在底涂层上层叠包含金属氧化物半导体微粒的涂膜来形成金属氧化物半导体微粒层。版权所有（C）2012，JPO＆INPIT

5. 发明专利

JP2014078392A Electroluminescence element using perovskite compound 有权
标题翻译：电致发光元件使用PEROVSKITE化合物
公开(公告)号：JP2014078392A
公开(公告)日：2014-05-01
申请号：JP2012225267
申请日：2012-10-10
申请人： Peccell Technologies Inc , ペクセル・テクノロジーズ株式会社
发明人： KOJIMA AKIHIRO , KISHIMOTO SHINZO , KURAKI YASUO , KOGURE HIDEO , TESHIMA KENJIRO , IKEGAMI KAZUSHI
IPC分类号： H05B33/14 , C09K11/00 , C09K11/06 , C09K11/08
摘要： PROBLEM TO BE SOLVED: To provide an electric field excitation distributed inorganic EL element in which a luminous layer can be formed easily, by forming a luminous body, i.e., an organic inorganic perovskite compound, on the surface of insulating porous particulates, by self-organization using a solution.SOLUTION: In a distributed inorganic EL element where a luminous layer is interposed between a transparent electrode and a back electrode, the luminous layer is composed of porous particulates on which at least one kind of organic inorganic hybrid perovskite compound or inorganic perovskite compound is adsorbed or a film thereof is formed. The porous particulates are insulating porous particulates having a volume resistivity of 10Ω cm.
摘要翻译：要解决的问题：为了提供容易形成发光层的电场激发分布式无机EL元件，通过在绝缘多孔微粒的表面上形成发光体即有机无机钙钛矿化合物，使用溶液的组织。解决方案：在透明电极和背面电极之间插入发光层的分布式无机EL元件中，发光层由多孔微粒构成，其上至少有一种有机无机混合钙钛矿化合物或无机钙钛矿化合物被吸附或形成膜。多孔颗粒是体积电阻率为10＆OHgr的绝缘多孔微粒; 厘米。

6. 发明专利

JP2014049551A Photoelectric conversion element using perovskite compound and method of manufacturing the same 审中-公开
标题翻译：使用PEROVSKITE化合物的光电转换元件及其制造方法
公开(公告)号：JP2014049551A
公开(公告)日：2014-03-17
申请号：JP2012190223
申请日：2012-08-30
申请人： Peccell Technologies Inc , ペクセル・テクノロジーズ株式会社
发明人： KOJIMA AKIHIRO , KISHIMOTO SHINZO , TESHIMA KENJIRO , IKEGAMI KAZUSHI
IPC分类号： H01L51/42 , H01L31/06
CPC分类号： Y02E10/542 , Y02E10/549
摘要： PROBLEM TO BE SOLVED: To provide a solid-junction solar cell as an alternative to a dye-sensitized solar cell inferior in durability and an organic thin-film solar cell inferior in light resistance and moisture resistance.SOLUTION: A solid-junction photoelectric conversion element has a photoelectric conversion layer between a pair of transparent electrode substrates each comprising a transparent substrate and a transparent electrode layer formed on the transparent substrate. In the photoelectric conversion layer, a first semiconductor layer obtained by depositing or adsorbing an organic-inorganic hybrid perovskite compound onto the surface of a porous semiconductor fine particle layer formed on the electrode substrates is embedded in a second semiconductor layer comprising an inorganic perovskite compound and/or an organic-inorganic hybrid perovskite compound.
摘要翻译：要解决的问题：提供一种固体太阳能电池作为耐久性劣化的染料敏化太阳能电池的替代品以及耐光性和耐湿性差的有机薄膜太阳能电池。解决方案：固体结光电转换元件在一对透明电极基板之间具有光电转换层，每个透明电极基板包括透明基板和形成在透明基板上的透明电极层。在光电转换层中，将形成在电极基板上的多孔半导体微粒层的表面上沉积或吸附有机 - 无机混合钙钛矿化合物而获得的第一半导体层嵌入到包含无机钙钛矿化合物的第二半导体层中， /或有机 - 无机杂化钙钛矿化合物。

7. 发明专利

JP2012146631A Method of manufacturing photoelectric conversion element, photoelectric conversion element and photocell 有权
标题翻译：光电转换元件，光电转换元件和光电二极管的制造方法
公开(公告)号：JP2012146631A
公开(公告)日：2012-08-02
申请号：JP2011219840
申请日：2011-10-04
申请人： Peccell Technologies Inc , ペクセル・テクノロジーズ株式会社
发明人： KOJIMA AKIHIRO , IKEGAMI KAZUYUKI
IPC分类号： H01M14/00 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521
摘要： PROBLEM TO BE SOLVED: To provide an economically excellent manufacturing method of a dye-sensitized photoelectric conversion element in which adhesion (wet peeling durability) of a porous semiconductor fine particle layer and a conductive substrate can be maintained for a long term at a photoelectrode responsible for power generation even under a wet environment due to the liquid electrolyte of a charge transport layer, and to provide a dye-sensitized solar cell using the photoelectric conversion element.SOLUTION: In the method of manufacturing a photoelectrode 1 for a dye-sensitized photoelectric conversion element where a conductive substrate, an underlying layer 13 and metal oxide semiconductor fine particle layer 14 carrying a dye 15 are laminated in this order, the underlying layer is irradiated with electromagnetic waves having a wavelength of 400 nm or less, before laminating the metal oxide semiconductor fine particle layer 14 on the conductive substrate on which the underlying layer is formed or simultaneously with the lamination.
摘要翻译：要解决的问题：为了提供经济上优异的染料敏化光电转换元件的制造方法，其中可以长期保持多孔半导体细颗粒层和导电基底的粘附（湿剥离耐久性）由于电荷输送层的液体电解质，即使在潮湿的环境下也能够发电的光电极，并且提供使用该光电转换元件的染料敏化太阳能电池。解决方案：在制造用于染料敏化光电转换元件的光电极1的方法中，其中导电基底，承载染料15的下层13和金属氧化物半导体微粒层14依次层叠，在将金属氧化物半导体微粒层14层叠在其上形成有下层或与层叠同时的导电性基板上之前，用波长400nm以下的电磁波照射层。版权所有（C）2012，JPO＆INPIT

8. 发明专利

JP2014130734A Dye-sensitized photoelectric conversion element, and dye-sensitized solar battery 有权
标题翻译：透明光电转换元件和透明太阳能电池
公开(公告)号：JP2014130734A
公开(公告)日：2014-07-10
申请号：JP2012287793
申请日：2012-12-28
申请人： Peccell Technologies Inc , ペクセル・テクノロジーズ株式会社
发明人： IKEGAMI KAZUSHI , KOJIMA AKIHIRO , KURAKI YASUO
IPC分类号： H01M14/00 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521
摘要： PROBLEM TO BE SOLVED: To provide a conductive electrode substrate having excellent anticorrosiveness and that is low in cost, to provide a dye-sensitized photoelectric conversion element using the same, and to provide a dye-sensitized photoelectric conversion element and a dye-sensitized solar battery module that is configured by a plastic substrate that is light in weight and less likely to be broken.SOLUTION: A dye-sensitized photoelectric conversion element has a photoelectrode 15 to which a dye-sensitized porous semiconductor particle layer 14 is formed, an electrolyte layer 16, and a counter electrode consisting of a conductive electrode substrate having a catalytic action, in this order on a conductive electrode substrate. The conductive electrode substrate is obtained by laminating a nano-carbon layer consisting of fibrous carbon with a nanometer-sized diameter on the substrate. Also provided is a dye-sensitized solar battery.
摘要翻译：要解决的问题：为了提供具有优异的耐腐蚀性并且成本低的导电电极基板，提供使用该导电电极基板的染料敏化光电转换元件，并提供染料敏化光电转换元件和染料敏化太阳能电池模块，其由重量轻且不太可能破裂的塑料基板构成。解决方案：染料敏化光电转换元件具有形成染料敏化多孔半导体颗粒层14的光电极15，电解质层16，以及由具有催化作用的导电电极基板构成的对电极，依次形成在导电性电极基板上。导电电极基板通过在基板上层叠由纳米尺寸直径的纤维状碳构成的纳米碳层而获得。还提供染料敏化太阳能电池。

9. 发明专利

JP2014056903A Photoelectric conversion element using perovskite compound and method of manufacturing the same 有权
标题翻译：使用PEROVSKITE化合物的光电转换元件及其制造方法
公开(公告)号：JP2014056903A
公开(公告)日：2014-03-27
申请号：JP2012200060
申请日：2012-09-12
申请人： Peccell Technologies Inc , ペクセル・テクノロジーズ株式会社
发明人： KOJIMA AKIHIRO , KISHIMOTO SHINZO , MUKUNOKI YASUO , TESHIMA KENJIRO , IKEGAMI KAZUSHI
IPC分类号： H01L51/42
CPC分类号： Y02E10/549
摘要： PROBLEM TO BE SOLVED: To provide a solid-junction solar cell as an alternative to a dye-sensitized solar cell inferior in durability and an organic thin-film solar cell inferior in light resistance and moisture resistance.SOLUTION: A solid-junction photoelectric conversion element 1 has a photoelectric conversion layer 3 between a pair of transparent electrode substrates 2 each comprising a transparent substrate 21 and a transparent electrode layer 22 formed on the transparent substrate 21. In the photoelectric conversion layer 3, a first semiconductor layer 4 obtained by depositing or adsorbing an organic-inorganic hybrid perovskite compound onto the surface of a carbon nanotube layer formed on the electrode substrates is embedded in a second semiconductor layer 5 comprising an inorganic perovskite compound and/or an organic-inorganic hybrid perovskite compound.
摘要翻译：要解决的问题：提供一种固体太阳能电池作为耐久性劣化的染料敏化太阳能电池的替代品以及耐光性和耐湿性差的有机薄膜太阳能电池。解决方案：固体结光电转换元件1在一对透明电极基板2之间具有光电转换层3，每个透明电极基板2包括透明基板21和形成在透明基板21上的透明电极层22.在光电转换层3中，或将有机 - 无机混合钙钛矿化合物吸附到形成在电极基板上的碳纳米管层的表面上，埋入包含无机钙钛矿化合物和/或有机 - 无机混合钙钛矿化合物的第二半导体层5中。

10. 发明专利

JP2014056801A Conductive film using perovskite compound and production method of the same 有权
标题翻译：使用PEROVSKITE化合物的导电膜及其生产方法
公开(公告)号：JP2014056801A
公开(公告)日：2014-03-27
申请号：JP2012202467
申请日：2012-09-14
申请人： Peccell Technologies Inc , ペクセル・テクノロジーズ株式会社
发明人： KOJIMA AKIHIRO , KISHIMOTO SHINZO , MUKUNOKI YASUO , TESHIMA KENJIRO , IKEGAMI KAZUSHI
IPC分类号： H01B5/14 , C01B31/02 , H01B13/00
摘要： PROBLEM TO BE SOLVED: To provide a conductive film having high transparency and conductivity.SOLUTION: The transparent film is a transparent conductive film having a transparent electrode layer formed on a transparent film, wherein a transparent conductive layer comprising a carbon nanotube on which an organic-inorganic hybrid perovskite compound shown in general formula (1) or (2) is applied as a film or adsorbed is formed on the transparent film. The transparent conductive layer comprising the carbon nanotube on which the organic-inorganic hybrid perovskite compound (A) is applied as a film or adsorbed is formed by using a solution containing a precursor that can constitute the organic-inorganic hybrid perovskite compound. The carbon nanotube constituting the carbon nanotube layer includes a metallic carbon nanotube by 50% or more.
摘要翻译：要解决的问题：提供具有高透明度和导电性的导电膜。解决方案：透明膜是在透明膜上形成透明电极层的透明导电膜，其中包含碳纳米管的透明导电层，其上有机通式（1）或（2）所示的无机杂化钙钛矿化合物作为膜而被使用或吸附在透明膜上。通过使用含有可构成有机 - 无机混合钙钛矿化合物的前体的溶液，形成包含有机 - 无机混合钙钛矿化合物（A）作为膜或吸附的碳纳米管的透明导电层。构成碳纳米管层的碳纳米管包括50％以上的金属性碳纳米管。

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