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    • 6. 发明专利
    • APPARATUS FOR MEASURING FREE CHLORINE IN SAMPLE WATER
    • JPH02285260A
    • 1990-11-22
    • JP10696689
    • 1989-04-26
    • FUJI ELECTRIC CO LTDNEW COSMOS ELECTRIC COAOKI TOYOAKI
    • NISHIKATA SATOSHIITO HARUOTAKADA TADASHISAKAI TOSHIAOKI TOYOAKIHAMA YUKIO
    • G01N31/00G01N33/18
    • PURPOSE:To measure free chlorine by transferring free chlorine in sample water to a gaseous phase while preventing the condensation of moisture on the inner wall of a measuring apparatus by mounting a gaseous phase extraction means, a carrier gas humidity conditioning means and a semiconductor type detection means. CONSTITUTION:Free chlorine in sample water is transferred to carrier gas by a gaseous phase extraction means 15 and the humidity of the carrier gas containing chlorine subjected to gaseous phase extraction is conditioned by a humidity conditioning means 16. A semiconductor type detection means 17 detects the amount of free chlorine transmitted to the carrier gas. Both of free chlorine and bound chlorine are transferred to the carrier gas by the gaseous phase extraction means 15 but the semiconductor type detection means 17 responds only to free chlorine and only hypochlorous acid in the sample water can be separated and measured without receiving the effect of bound chlorine in the sample water. Further, since the steam pressure in the carrier gas is held to saturated steam pressure or less by the humidity conditioning means 16, no moisture is condensed on the inner wall of a measuring apparatus and the re-dissolution and re-emission of free chlorine are eliminated and free chlorine in the sample water can be measured with high accuracy.