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    • 1. 发明专利
    • Additive for paper
    • 添加剂
    • JP2013224502A
    • 2013-10-31
    • JP2012097227
    • 2012-04-22
    • Nof Corp日油株式会社
    • MATSUFUJI TAKASHIMARUYAMA KEIICHI
    • D21H21/22C08K5/20C08L71/00D21H17/56
    • PROBLEM TO BE SOLVED: To provide an additive for paper that can achieve both improving a good paper volume and suppressing a deterioration in paper strength.SOLUTION: An additive for paper contains a polyoxypropylene polyamine (A) represented by formula (1), and an amide-amine compound (B) obtained by condensation between 1 mol of a polyamine represented by formula (2) and 1 to 5 mols of a 12-24C aliphatic monocarboxylic acid. The mass ratio (A/B) of the polyoxypropylene polyamine (A) to the amide-amine compound (B) is 1/99 to 30/70. The total amine value is 60 to 230 mgKOH/g. [In the formula (1), Z is a dehydroxylated residue of diol or triol, and OP is an oxypropylene group; a is an average addition mol number of oxypropylene groups and is 1 to 40; and b is 2 or 3.] [In the formula (2), c is an integer of 2 to 5.]
    • 要解决的问题:提供一种能够实现既能提高纸张体积又能抑制纸张强度劣化的纸张添加剂。溶剂:纸用添加剂含有式(1)所示的聚氧丙烯多胺(A),和 通过1摩尔由式(2)表示的多胺和1至5摩尔的12-24C脂肪族单羧酸之间的缩合获得的酰胺 - 胺化合物(B)。 聚氧丙烯多胺(A)与酰胺 - 胺化合物(B)的质量比(A / B)为1/99〜30/70。 总胺值为60〜230mgKOH / g。 [式(1)中,Z为二醇或三醇的脱羟基化残基,OP为氧化丙烯基。 a是氧化丙烯基的平均加成摩尔数,为1〜40; b为2或3.] [式(2)中,c为2〜5的整数。
    • 2. 发明专利
    • Softener for paper
    • 纸张用纸
    • JP2009041158A
    • 2009-02-26
    • JP2007210436
    • 2007-08-10
    • Nof Corp日油株式会社
    • ASAKURA KAZUYOSHITAMAI TETSUYANAKAMURA YASUYUKIMATSUFUJI TAKASHI
    • D21H21/22D21H17/07D21H17/37
    • PROBLEM TO BE SOLVED: To provide a softener for paper, which gives flexibility and a good touch feeling to the paper while suppressing the reduction of strength of the paper, and further inhibiting the reduction of yield of the paper in its production processes.
      SOLUTION: This softener for the paper contains (A) an amideamine compound expressed by formula (1) [wherein, R
      1 CO is a 10-24C acyl; R
      2 is a 2-4C alkylene; and R
      3 , R
      4 are each a 1-4C alkyl], and (B) a polyacrylamide having a viscosity of 10% aqueous solution at 25°C of 3,000 to 20,000 mPa s, and having a weight ratio (A)/(B) of the amideamine compound (A) to the polyacrylamide (B) of (70/30) to (95/5).
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供一种纸张柔软剂,其在抑制纸的强度降低的同时赋予纸张柔软性和良好的触感,并且进一步抑制纸张在其生产过程中的收率降低 。 解决方案:该纸的柔软剂含有(A)式(1)表示的酰胺胺化合物[其中,R SP 1 CO为10-24C酰基; R 2 SP 2是2-4C亚烷基; 和R 3 SP 4各自为1-4 C烷基],(B)在25℃下粘度为10%水溶液的聚丙烯酰胺为3,000〜 (70/30)至(95/5)的酰胺胺化合物(A)与聚丙烯酰胺(B)的重量比(A)/(B)为20,000mPa·s。 版权所有(C)2009,JPO&INPIT
    • 3. 发明专利
    • Additive for paper
    • 添加剂
    • JP2013053397A
    • 2013-03-21
    • JP2012097226
    • 2012-04-22
    • Nof Corp日油株式会社
    • MATSUFUJI TAKASHIMARUYAMA KEIICHITAMAI TETSUYA
    • D21H17/07C08K5/20C08L71/02D21H17/56D21H21/16D21H21/22
    • PROBLEM TO BE SOLVED: To provide an additive for paper which is capable of simultaneously imparting sufficient sizability and good flexibility to the paper in good valance while suppressing deterioration in interlaminar strength.SOLUTION: The additive for the paper comprises: an amide-amine compound (a) that is obtained by reacting 1 mol of a polyamine mixture comprising 25-60 mol% of a compound A represented by the formula (1) and 40-75 mol% of a compound B represented by the formula (2), with 2-5 mol of a 12-24C aliphatic monocarboxylic acid, and has an amine value of 40-220 mgKOH/g; and a polyoxy alkylene polyamine (b). The additive for the paper contains 5-40 pts.mass of the polyoxy alkylene polyamine (b) with respect to 100 pts.mass of the amide-amine compound (a). (In the formula, x+y represents an integer of 0 to 2, and z represents an integer of 3 to 5.)
    • 要解决的问题:提供一种纸,能够同时赋予纸张良好的纸张的良好的柔性,同时抑制层间强度的劣化的纸添加剂。 解决方案:纸的添加剂包括:酰胺 - 胺化合物(a),其通过使1摩尔包含25-60摩尔%的式(1)表示的化合物A和40重量% -75摩尔%的由式(2)表示的化合物B,具有2-5摩尔的12-24℃脂族一元羧酸,胺值为40-220毫克KOH /克; 和聚氧亚烷基多胺(b)。 纸的添加剂相对于100质量份的酰胺 - 胺化合物(a)含有5-40质量份的聚氧亚烷基多胺(b)。 (式中,x + y表示0〜2的整数,z表示3〜5的整数。)(C)2013,JPO&INPIT
    • 5. 发明专利
    • ロールオン容器用化粧料
    • 用于滚装容器的化妆品
    • JP2014210716A
    • 2014-11-13
    • JP2013086748
    • 2013-04-17
    • 日油株式会社Nof Corp
    • MATSUFUJI TAKASHIMURAKAMI DAITAMURA TAKESHI
    • A61K8/86A61K8/02A61K8/34A61K8/368A61K8/37A61K8/73A61K8/81A61Q19/00
    • A61K8/02A61K8/34A61K8/36A61K8/37A61K8/73A61K8/81A61K8/86A61Q19/00
    • 【課題】ロールオン容器用化粧料として好適に利用できる化粧料を提供すること。【解決手段】(A)式I:A−[O{(PO)x(EO)y}−(BO)zH]n・・・(式I)(式中、各記号は明細書中で定義した通りである。)で表されるアルキレンオキシド誘導体、(B)炭素数4〜6のジオール、(C)p−ヒドロキシ安息香酸メチルまたはp−ヒドロキシ安息香酸ナトリウム、(D)セルロース由来または多糖類由来の水溶性高分子、(E)アクリル酸系ポリマー、および(F)水を含有し、全重量に対する成分(A)の含有率が1〜20重量%、成分(B)の含有率が1〜20重量%、成分(C)の含有率が0.05〜1重量%、成分(D)の含有率が0.01〜1重量%、および成分(E)の含有率が0.01〜0.8重量%であり、残部が成分(F)であるロールオン容器用化粧料。【選択図】なし
    • 要解决的问题:提供适合用作滚涂容器的化妆品的化妆品。溶解剂:用于卷起容器的化妆品包含(A)由式I表示的氧化烯衍生物:A- [O { (PO)(EO)} - (BO)H](其中,每个字符如说明书中所定义),(B)碳数为4至6的二醇,(C)对羟基苯甲酸甲酯或钠 (D)来自纤维素或多糖的水溶性聚合物,(E)丙烯酸类聚合物和(F)水,其中组分(A)的含量比为1〜20重量%。 (B)的含量比为1〜20重量%,成分(C)的含有比例为0.05〜1重量%,成分(D)的含有比例, 为0.01〜1重量%,成分(E)的含有比例为0.01〜0.8重量%,其余为成分(F)。
    • 6. 发明专利
    • Softener for paper
    • 纸张用纸
    • JP2010126833A
    • 2010-06-10
    • JP2008302293
    • 2008-11-27
    • Nof Corp日油株式会社
    • NAKAMURA YASUYUKITAMAI TETSUYAMATSUFUJI TAKASHI
    • D21H21/22D21H17/07
    • PROBLEM TO BE SOLVED: To provide a softener for paper that imparts high softness to paper, causes no deterioration in sizing effect, does not decrease a friction coefficient, and inhibits the occurrence of stain in a papermaking machine system.
      SOLUTION: The softener for paper contains a compound (A) and a compound (B) in a mass ratio of the compound (A) to the compound (B) of 80/20 to 99/1. The compound (A) is an ester compound obtained by mixing a 10C-12C linear saturated fatty acid to a 14C-18C linear saturated fatty acid in a mass ratio of 10/90 to 55/45 and making the mixed fatty acid react with a compound represented by formula (1) [wherein R
      1 represents a 1C-4C alkyl group] in a molar ratio of 1.7/1 to 2.0/1, and the compound (B) is a compound represented by formula (2): R
      2 O(CH
      2 CH
      2 O)
      n R
      3 [in formula (2), R
      2 and R
      3 each independently represent a 4C-8C alkyl group, which may be the same or different; and n is 1-3].
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供赋予纸张高柔度的纸张用软化剂,不会造成施胶效果的劣化,不会降低摩擦系数,并且抑制造纸机系统中的污渍的发生。 解决方案:纸张用柔软剂含有化合物(A)和化合物(B),化合物(A)与化合物(B)的质量比为80/20〜99/1。 化合物(A)是通过将10 -12C线性饱和脂肪酸与质量比为10/90至55/45的14C-18C线性饱和脂肪酸混合而得到的酯化合物,并使混合脂肪酸与 由式(1)表示的化合物[其中R 1 表示1C-4C烷基],摩尔比为1.7 / 1〜2.0 / 1,化合物(B)为 式(2):R(SP)2 O(CH 2 SB)2 2 / SP> [式(2)中,R 2 和R 3 各自独立地表示可以相同或不同的4C-8C烷基; n为1-3]。 版权所有(C)2010,JPO&INPIT
    • 7. 发明专利
    • Softener for paper
    • 纸张用纸
    • JP2010024561A
    • 2010-02-04
    • JP2008184629
    • 2008-07-16
    • Nof Corp日油株式会社
    • TAMAI TETSUYAMATSUFUJI TAKASHIYAMANAKA AIKO
    • D21H21/22
    • PROBLEM TO BE SOLVED: To provide a softener for paper which gives the paper having good softness and smoothness and giving a moist feeling, without deteriorating water absorbability, and has little bubbles in a process for coating the softener on the paper.
      SOLUTION: The softener for the paper comprises glycerol (A), an amide compound (B) represented by formula (1), [wherein R
      1 CO is a 14-20C acyl group having an unsaturated bond or a branched chain; R
      2 is H or (A
      2 O)
      n H; A
      1 O and A
      2 O are each a 2-3C oxyalkylene group; (m) and (n) are each average addition molar number of the oxyalkylene group; and (m)+(n) is 1-6], and a 14-20C unsaturated aliphatic alcohol or a branched aliphatic alcohol (C); wherein the mass ratio A/B of (A) to (B) is 92/8 to 99.5/0.5; and the mass ratio B/C of (B) to (C) is 75/25 to 90/10.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:为了提供一种纸,其具有良好的柔软性和平滑性并且赋予潮湿感,而不会降低吸水性,并且在将柔软剂涂布在纸上的过程中几乎没有气泡。 本发明的软化剂包括甘油(A),由式(1)表示的酰胺化合物(B),[其中R“SP”是具有14-20个碳原子的酰基, 不饱和键或支链; R 2 是H或(A 2 O) n H; A 1 O和A 2 O分别为2-3C氧化烯基团; (m)和(n)分别为氧化烯基的平均加成摩尔数; 和(m)+(n)为1-6]和14-20℃不饱和脂族醇或支链脂族醇(C); (A)〜(B)的质量比A / B为92/8〜99.5 / 0.5; (B)〜(C)的质量比B / C为75/25〜90/10。 版权所有(C)2010,JPO&INPIT
    • 9. 发明专利
    • 罫線割れ防止剤
    • 规则线破裂抑制剂
    • JP2015014070A
    • 2015-01-22
    • JP2013142439
    • 2013-07-08
    • 日油株式会社Nof Corp
    • MORIKAWA TOSHIYUKIMATSUFUJI TAKASHIEBANA HIROATSU
    • D21H21/14D21H19/30
    • 【課題】外部添加によって板紙に優れた罫線割れ防止適性を効率的に付与することができる罫線割れ防止剤の提供。【解決手段】式(1)で表されるポリアミン化合物1モルに対して、炭素数10〜14の脂肪酸2〜4モルを反応させて得られるアミドアミン化合物またはその塩からなり、式(2)で表されるアミノ基1個当たりの脂肪酸の炭素数(A)が5.5〜8.5であることを特徴とする罫線割れ防止剤。NH2−(CH2CH2−NH)xH ・・・式(1)(式中、xは3〜5の整数である。)A=脂肪酸炭素数?アミド化率・・・式(2)アミド化率=(反応開始時のアミン価−反応終了時のアミン価)/反応開始時のアミン価【選択図】なし
    • 要解决的问题:提供一种能够通过外部添加赋予纸板优良的划线裂纹防止适应性的划线裂纹抑制剂。解决方案:线条裂纹抑制剂由酰胺胺化合物或其盐,通过使1mol 具有2-4mol 10-14C脂肪酸的式(1)的多胺化合物,并且具有式(2)的每个氨基的脂肪酸的碳数(A)为5.5-8.5。 式(1)NH-(CHCH-NH)H,其中x是3-5的整数。 式(2)A =脂肪酸的碳数×酰胺化率,其中酰胺化率=(反应末端的反应起始胺值的胺值)/反应开始时的胺值。
    • 10. 发明专利
    • Additive for paper
    • 添加剂
    • JP2013224503A
    • 2013-10-31
    • JP2012097228
    • 2012-04-22
    • Nof Corp日油株式会社
    • MATSUFUJI TAKASHIMARUYAMA KEIICHI
    • D21H17/56D21H21/22
    • PROBLEM TO BE SOLVED: To provide an additive for paper that can achieve both improving a good paper volume and suppressing a deterioration in tensile strength of paper.SOLUTION: An additive for paper contains a polyoxypropylene polyamine (A) represented by formula (1), and an amide-amine compound (B) obtained by condensation between an amine represented by formula (2) and a 12-24C aliphatic monocarboxylic acid. The mass ratio (A/B) of the polyoxypropylene polyamine (A) to the amide-amine compound (B) is 1/99 to 30/70. The total amine value is 100 to 200 mgKOH/g.
    • 要解决的问题:提供一种能够实现既能提高纸张体积又能抑制纸张的拉伸强度劣化的纸张添加剂。解决方案:纸用添加剂含有式(1)所示的聚氧丙烯多胺(A) 和由式(2)表示的胺与12-24C脂族一元羧酸缩合得到的酰胺 - 胺化合物(B)。 聚氧丙烯多胺(A)与酰胺 - 胺化合物(B)的质量比(A / B)为1/99〜30/70。 总胺值为100〜200mgKOH / g。