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    • 1. 发明专利
    • Catalyst material for purifying nitrogen oxides
    • 用于净化氮氧化物的催化材料
    • JPH11276892A
    • 1999-10-12
    • JP8562198
    • 1998-03-31
    • Nissan Motor Co Ltd日産自動車株式会社
    • MUNAKATA FUMIOAKIMUNE YOSHIO
    • B01D53/86B01D53/94B01J23/34B01J23/889
    • PROBLEM TO BE SOLVED: To achieve a high NOx purifying capacity even in an area the temperature of which does not exceed a specified value and in an oxidative atmosphere by using a complex oxide of a layer perovskite structure as a catalyst raw material. SOLUTION: In an NOx purifying catalyst material, in the layer perovskite structure expressed by the general formula, A3 B2 O7 . A comprises at least one element selected from the group consisting of rare earth elements, alkaline earth elements and Y; B comprises at least one element selected from Mn and Fe. This structure can purify NOx even in a temperature range of 500 deg.C or below, has a high melting point, and can improve heat resistance. For example, in the powder of a complex oxide expressed by La1.0 Ba2.0 Mn2 O7-8 , the carbonates or hydroxides of lanthanum, barium, and manganese are used as starting raw materials, they are added to make their composition ratio La:Ba: Mn=1.0:2.0:2, crushed and mixed, after the complex citrate being produced, and after provisional baking, they are baked.
    • 要解决的问题:即使在温度不超过规定值的区域中,并且通过使用钙钛矿结构层的复合氧化物作为催化剂原料,在氧化气氛中也能实现高的NOx净化能力。 解决方案:在一种NOx净化催化剂材料中,由通式A3 B2 O7表示的钙钛矿结构层中。 A包括选自由稀土元素,碱土金属元素和Y组成的组中的至少一种元素; B包含至少一种选自Mn和Fe的元素。 该结构即使在500℃以下的温度范围也可以净化NOx,具有高熔点,并且可以提高耐热性。 例如,在由La1.0 Ba2.0 Mn2O7-8表示的复合氧化物的粉末中,使用镧,钡,锰的碳酸盐或氢氧化物作为起始原料,添加它们的组成比La :Ba:Mn = 1.0:2.0:2,在制备柠檬酸复合物之后,进行粉碎和混合,并且在临时烘烤之后,将其烘焙。
    • 2. 发明专利
    • Manufacture of substrate having heater for gas sensor element
    • 具有加热器的气体传感器元件制造
    • JPS58198754A
    • 1983-11-18
    • JP8029182
    • 1982-05-14
    • Nissan Motor Co Ltd
    • SHIODA MASAHIKOISHITANI MASAOIKEZAWA KENJIAKIMUNE YOSHIOABE SATOSHI
    • G01N27/12G01N27/406G01N27/409
    • G01N27/4067
    • PURPOSE:To prevent plastic deformation caused during a sintering process and to increase the durability of a heater, by adhering conductive paste containing conductive powder and ceramic powder at an unsintered ceramic substrate in a heater shape before ignition. CONSTITUTION:The unsintered sheet 1 is manufactured by adding a suitable flux, etc. to a ceramic powder material. A pure metal or an alloy of platinum group element is used as the conductive material to form the heater. The ceramic powder is added by 10-30vol% to this conductive material powder to delay the sintering progress thereof and to bring close to the sintering progress rate of the ceramic sheet substrate 1, and this mixture and an organic vehicle are mixed to manufacture the conductive paste which is adhered on the substrate 1 in a heater shape 2. Then a gas concn. detecting part is formed on the ceramic sheet base plate and ignited. By constituting in such way, the durability of the heater is improved and the increase of the resistance percentage is minimized even in a longterm service.
    • 目的:为了防止在烧结过程中引起的塑性变形并提高加热器的耐久性,通过在点火前将含有导电粉末和陶瓷粉末的导电膏粘附在加热器形状的未烧结的陶瓷基板上。 构成:通过向陶瓷粉末材料中添加合适的助熔剂等,制造未烧结片材1。 使用纯金属或铂族元素的合金作为导电材料来形成加热器。 陶瓷粉末以10-30vol%的比例添加到该导电材料粉末中以延迟其烧结过程并使陶瓷片基材1的烧结进程接近,并将该混合物和有机载体混合以制造导电 糊状物以加热器形状2附着在基板1上。 检测部件形成在陶瓷片基板上并点燃。 通过这样构成,能够提高加热器的耐久性,并且即使长期使用也能够使电阻百分比的上升最小化。
    • 6. 发明专利
    • Piezoelectric material actuator
    • 压电材料执行机构
    • JP2006143588A
    • 2006-06-08
    • JP2006035146
    • 2006-02-13
    • Nissan Motor Co Ltd日産自動車株式会社
    • AKIMUNE YOSHIOMUNAKATA FUMIOSHINOHARA MIKIYA
    • C04B35/00C04B35/64H01L41/187H01L41/39H01L41/43
    • PROBLEM TO BE SOLVED: To provide a piezoelectric material actuator not including toxic lead ingredients such as PZT, and excellent in piezoelectric characteristics. SOLUTION: The piezoelectric material actuator is obtained by adding 0.5 to 3.0 wt% La 2 O 3 or the like as ingredients for improving characteristics to a polycrystalline piezoelectric compound having a chemical composition expressed by Sr 2-x Ca x NaNb 5 O 15 [wherein, (x) is 0.05 to 0.35]. When the size of crystal grains composed of a sintered compact, is regarded as the value of the average in the lengths of the grains to which parallel direct lines cross in an electron microscope photograph obtained using an image apparatus, the average grain diameter is 3 to 10 μm. The production method comprises: a mixing process for porcelain raw materials; a synthesizing process; a crushing process; a molding process; and a sintering process. A firing condition in the synthesizing process is conducted at 1,050 to 1,150°C for 2 to 12 h. A firing condition in the sintering process is that the first firing step is carried out at 1,180 to 1,270°C for 4 to 8 h, and the second firing step is carried out at 1,370 to 1,400°C for 10 to 75 h. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供不含PZT等有毒铅成分的压电材料致动器,压电特性优异。 解决方案:压电材料致动器是通过添加0.5至3.0重量%的La SB 2 O 3 SB 3等作为用于改善特性的成分的多晶压电化合物,其具有 由Sr 2-x 15 表示的化学组成[其中,(x)为 0.05〜0.35]。 当由烧结体构成的晶粒的尺寸被认为是使用图像装置获得的电子显微镜照片中平行直线交叉的晶粒的长度的平均值,平均粒径为3〜 10μm。 生产方法包括:瓷原料混合工艺; 合成过程; 破碎过程; 成型工艺; 和烧结工艺。 合成过程中的烧成条件在1050〜1150℃进行2〜12小时。 烧结工序中的烧成条件是,第1烧成工序在1,180〜1270℃下进行4〜8小时,第2烧成工序在1,370〜1400℃下进行10〜75小时。 版权所有(C)2006,JPO&NCIPI
    • 9. 发明专利
    • Manufacture of fine zirconia powder containing solubilized yttria
    • 含有溶解氧化锌的精细粉末的制造
    • JPS59156918A
    • 1984-09-06
    • JP2691883
    • 1983-02-22
    • Nissan Motor Co Ltd
    • AKIMUNE YOSHIO
    • C04B35/48C01G25/00
    • PURPOSE: To manufacture the titled powder capable of forming sintered zirconia porcelain having superior mechanical properties by a neutralization and coprecipitation method by drying precipitated hydroxide by an induction heating method.
      CONSTITUTION: An aqueous soln. contg. a water soluble zirconium salt such as ZrOCl
      2 .8H
      2 O and a water soluble yttrium salt such as YCl
      3 .6H
      2 O is neutralized by adding an aqueous soln. of NH
      4 OH, and Zr(Y)(OH)
      4 is precipitated. The precipitate is well washed and dehydrated at ≥ about 7.2g/(sec.mole rate of evaporation. by the drying the precipitate is directly converted into Zr(Y)O
      2-x without passing through a stage for conversion into Zr(Y)O(OH)
      2 . The Zr(Y)O
      2-x is calcined at about 600W800°C to obtain fine zirconic powder contg. solubilized yttria.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过中和和共沉淀方法,通过感应加热方法干燥沉淀的氢氧化物,制造能够形成具有优异机械性能的氧化锆烧结体的粉末粉末。 构成:水溶胶 contg。 通过加入水溶液中和水溶性锆盐如ZrOCl 2·8H 2 O和水溶性钇盐如YCl 3·6H 2 O. 的NH 4 OH,Zr(Y)(OH)4沉淀。 在> =约7.2g /(sec.mole蒸发速率)下,将沉淀物充分洗涤并脱水,通过干燥将沉淀物直接转化为Zr(Y)O 2-x,而不经过用于转化为Zr(Y) O(OH)2。Zr(Y)O 2-x在约600-800℃下煅烧,得到细小的锆石粉,溶解氧化钇。