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    • 2. 发明专利
    • PURGING AND TRAPPING APPARATUS
    • JPH04355341A
    • 1992-12-09
    • JP15598891
    • 1991-05-31
    • NEC CORP
    • ADACHI HIROSHIADACHI MAKIKO
    • G01N1/28
    • PURPOSE:To enable complete removal of moisture blocking analysis while achieving a trapping of, wide ranging components in the trapping of a volatile substance in a sample. CONSTITUTION:A sample bottle 6 with a capacity thereof corresponding to the condition of a sample is arranged at a purge section 1 provided with a stirrer 5. The sample is heated and purged in helium in the sample bottle 6. A volatile component extracted is introduced into a trap tube 3 and adsorbed and before the trap tube 3, a moisture removing part 2 is arranged to remove the moisture and a specified component in the volatile component. The moisture removing part 2 comprises two or more moisture removing tubes 9 and 10 different in cooling temperature using a solenoid valve 12. To adjust heating temperature of the moisture removing tubes 9 and 10, a heating coil 14 is used. Otherwise, a microwave tube, a far infrared ray lamp or a high frequency heater may be used.
    • 3. 发明专利
    • SAMPLE CONCENTRATION TRAPPING APPARATUS
    • JPH0755781A
    • 1995-03-03
    • JP20084693
    • 1993-08-12
    • NEC CORP
    • ADACHI HIROSHITATEISHI KAZUO
    • B01D61/36G01N30/12
    • PURPOSE:To completely extract volatile ingredient in water from moisture by providing a pump for pressurizing sample, a heater for heating, and a stirrer for stirring, permeating to vaporizes only object substance via a permeating and vaporizing film, and guiding it to a trap tube via carrier gas. CONSTITUTION:A sample permeating and vaporizing unit 1 has a pump 11 for pressurizing sample in a sample bottle 10, a heater 4 for heating the sample, a magnet 8 to be rotated by a stirrer 5 for stirring the sample, and a permeating and vaporizing film 2 for permeating and vaporizing only the substance. Volatile ingredient in the water is permeated through the film 2 to a carrier gas introducing unit 3, passed through a volatile ingredient exhaust tube 7 under the guidance of the gas, introduced to a trap tube 9 and concentrated. Then, it is heated, desorbed, and introduced to a sample introducing unit of a gas chromatograph. Thus, it can be completely separated from moisture without loss of the volatile ingredient, accurately concentrated, and trapped.
    • 7. 发明专利
    • TG-GC/MS APPARATUS
    • JPH03220447A
    • 1991-09-27
    • JP1480290
    • 1990-01-26
    • NEC CORP
    • ADACHI HIROSHIKOGA MAKIKO
    • G01N25/00G01N30/08
    • PURPOSE:To analyze the mass of each gas component in time sequence which is generated very slightly from a TG apparatus by sequentially trapping the gas component into each trapping pipe in association with the reduction of the thermal weight and heating/separating the same for every trapping pipe. CONSTITUTION:In a TG apparatus 1, gaseous components generated when a sample 9 is heated by a heater 10 are guided by a carrier gas to a trapping device 2 through a line 4. Several trapping pipes 5 are set in the device 2, which can be driven sequentially in accordance with the reduction of the weight during the TG measurement. The pipes 5 are cooled by liquid nitrogen and filled with an adsorbent. After the TG measurement, each pipe 5 is heated by a heating device 6 and the adsorbed component is separated. If the amount of the generated gas is very small, the pipes 5 are returned to the initial state, so that a sample 9 is filled again to be trapped. The separated component is sent to a GC/MS apparatus 3 through a line 7 for mass analysis. Accordingly, the local change of the thermodynamic or physical properties in the molecular structure of the sample 9 can be detected.