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1. 发明专利

JP2014148114A Method for manufacturing resin laminate 审中-公开
标题翻译：制造树脂层压板的方法
公开(公告)号：JP2014148114A
公开(公告)日：2014-08-21
申请号：JP2013018551
申请日：2013-02-01
申请人： Nippon Steel & Sumikin Chemical Co Ltd , 新日鉄住金化学株式会社
发明人： KAMIYA MIYUKI , SAITO KEN
IPC分类号： B32B37/16 , B32B7/06 , C08F2/44 , C08F2/46
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing a resin laminate that is optimal for a window pane of a vehicle or the like, by forming a hard coat layer for imparting transparency and wear resistance similar to those of glass on a transparent thermoplastic resin molded article such as a polycarbonate by a transfer process.SOLUTION: The method for manufacturing a resin laminate includes: a first step of forming a silica-containing photocurable coating film layer comprising a silica-containing photocurable resin composition on one surface of a transparent substrate film to obtain a transfer film; a second step of forming a photocurable adhesion layer comprising a photocurable adhesion layer resin composition on a transparent thermoplastic resin molded article, and bonding the adhesion layer to the silica-containing photocurable coating film layer side of the transfer film; a third step of curing the silica-containing photocurable coating film layer and the adhesion layer with light to form a hard coat layer; and a fourth step of stripping the transparent film while leaving the hard coat layer.
摘要翻译：要解决的问题：提供一种用于制造车辆等的窗玻璃最佳的树脂层压体的方法，通过在透明热塑性树脂上形成类似于玻璃的透明度和耐磨性的硬涂层树脂层叠体的制造方法包括：在透明基板的一个表面上形成含二氧化硅的光固化性树脂组合物的含二氧化硅的光固化性涂膜层的第一工序电影获得转印膜; 在透明热塑性树脂成型体上形成光固化性粘合层树脂组合物的光固化性粘合层的第二工序，将粘合层与转印膜的含二氧化硅的光固化性涂膜层接合; 第三步，用光固化二氧化硅的光固化性涂膜层和粘合层，形成硬涂层; 以及在离开硬涂层的同时剥离透明膜的第四步骤。

2. 发明专利

JP2013107354A Laminate 审中-公开
标题翻译：层压板
公开(公告)号：JP2013107354A
公开(公告)日：2013-06-06
申请号：JP2011255923
申请日：2011-11-24
申请人： Nippon Steel & Sumikin Chemical Co Ltd , 新日鉄住金化学株式会社
发明人： SAITO KEN
IPC分类号： B32B27/00 , B32B17/10 , C03C17/32 , C08G77/14 , C08G77/20
摘要： PROBLEM TO BE SOLVED: To provide a laminate excellent in heat resistance and transparency in addition to flexibility, shock resistance and a gas barrier property not needing heat treatment as conventionally.SOLUTION: In the laminate that a resin layer formed by curing a curable resin composition containing a curable resin including a cage-type silsesquioxan structure and a curing catalyst is disposed on one surface or both surfaces of glass via an adhesive layer or a viscous layer. The glass is not more than 0.7 mm in thickness and the ratio of the total thickness of the resin layer to the glass thickness (total thickness of the resin layer/the glass thickness) is at least 0.01 and smaller than 4.0.
摘要翻译：要解决的问题：提供除柔性，抗冲击性和不需要常规热处理的阻气性之外的耐热性和透明性优异的层压体。解决方案：在通过固化含有包含笼型硅倍半醌结构和固化催化剂的可固化树脂的固化性树脂组合物而形成的树脂层的层压体中，通过粘合剂层或玻璃的一面或两面配置粘性层。该玻璃的厚度不大于0.7mm，树脂层的总厚度与玻璃厚度（树脂层的总厚度/玻璃厚度）的比率至少为0.01以上且小于4.0。版权所有（C）2013，JPO＆INPIT

3. 发明专利

JP2013091703A Resin composition, resin molded body using the same, and method for producing resin molded body 审中-公开
标题翻译：树脂组合物，使用其的树脂模制体以及用于生产树脂模制体的方法
公开(公告)号：JP2013091703A
公开(公告)日：2013-05-16
申请号：JP2011234053
申请日：2011-10-25
申请人： Nippon Steel & Sumikin Chemical Co Ltd , 新日鉄住金化学株式会社
发明人： SATO MEGUMI , KAWATANI TOSHIHIRO , YUASA MASATOSHI , SAITO KEN
IPC分类号： C08G59/20
摘要： PROBLEM TO BE SOLVED: To provide a resin composition giving a resin molded body with excellent surface hardness, molded body and production method thereof.SOLUTION: This resin composition includes (A) a polyhedral silsesquioxane resin of formula (1): [RSiO][RSiO][RSiO]{Ris an organic group having an alkenyl group; Ris an organic group having an epoxy group; Ris an alkyl group or the like; n, m and k are integers satisfying conditions expressed by formulae: (i) n≥1; (ii) m≥1; (iii) n+m+k=h, respectively [in formula (iii), h is any integer selected from the group consisting of 8, 10, 12 and 14]}; (B) a cation polymerization initiator; and (C) a radical polymerization initiator.
摘要翻译：要解决的问题：提供给树脂成型体的树脂组合物具有优异的表面硬度，成型体及其制造方法。解决方案：该树脂组合物包含（A）式（1）的多面体倍半硅氧烷树脂：[R SP SP =“POST”> 1 SiO 3/2 < / SB>] n [R 2 SiO 3/2 ] < SB POS =“POST”> m [R 3 SiO 3/2 ] äR 1 是具有烯基的有机基团; R 2 是具有环氧基的有机基团; 3 是烷基等; n，m和k是满足由公式表示的条件的整数：（i）n≥1; （ii）m≥1; （iii）分别为n + m + k = h [式（iii）中，h为选自8,10,12及14]中的任意整数。（B）阳离子聚合引发剂; 和（C）自由基聚合引发剂。版权所有（C）2013，JPO＆INPIT

4. 发明专利

JP2014037547A Silicone resin 审中-公开
标题翻译：硅树脂
公开(公告)号：JP2014037547A
公开(公告)日：2014-02-27
申请号：JP2013213602
申请日：2013-10-11
申请人： Nippon Steel & Sumikin Chemical Co Ltd , 新日鉄住金化学株式会社
发明人： ONO YUKI , ISOZAKI MASAYOSHI , SAITO KEN
IPC分类号： C08G77/42 , C08F299/08
CPC分类号： C08G77/38 , C08F299/08 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/20 , C08G77/44 , C08G77/70 , C08L83/04 , G02B1/04 , G11B7/2533 , C08L83/00
摘要： PROBLEM TO BE SOLVED: To provide a silicone resin that may yield a cured product with high transparency excellent in flexibility, toughness, and heat resistance.SOLUTION: The silicone resin is obtained by reacting an organopolysiloxane having SiH groups represented by the general formula (3) with an organopolysiloxane having hydroxyl groups at both ends represented by the general formula (5) and an alcohol containing radically reactive groups represented by the general formula (6) by using a hydroxylamine compound represented by the general formula (4) as a catalyst.
摘要翻译：要解决的问题：提供可以产生柔软性，韧性和耐热性优异的高透明性的固化产物的硅树脂。溶胶：通过使由通式（3）表示的具有SiH基团的有机聚硅氧烷）与由通式（5）表示的两端具有羟基的有机聚硅氧烷和通式（6）所示的含有自由基反应性基团的醇通过使用由通式（4）表示的羟胺化合物作为催化剂。

5. 发明专利

JP2014133905A Formed body 有权
标题翻译：形成的身体
公开(公告)号：JP2014133905A
公开(公告)日：2014-07-24
申请号：JP2014093513
申请日：2014-04-30
申请人： Nippon Steel & Sumikin Chemical Co Ltd , 新日鉄住金化学株式会社
发明人： SAITO KEN
IPC分类号： C08G77/50 , C08G77/38
摘要： PROBLEM TO BE SOLVED: To provide a formed body in which such problems as embrittling and an increase of curing shrinkage accompanied by the construction of a stronger cross-linked structure are solved.SOLUTION: The formed body comprises a film shape, a sheet shape or a thick plate shape, and is obtained by radical polymerizing a compound a having an organic group containing a radically polymerizable carbon-carbon double bond and a hydrosilyl group in the molecule, in which the molecular weight per carbon-carbon double bond is 100-5,000 and the molecular weight per hydrosilyl group is 25-1,000, in such a manner that the resulting polymer is primarily cured into a film shape, a sheet shape or a thick plate shape while having the alkoxysilyl groups, and bringing the obtained primarily cured material into contact with a basic aqueous solution to subject the alkoxysilyl groups to dehydrogenation condensation.
摘要翻译：要解决的问题：提供一种成形体，其中解决了脆化和增加固化收缩等问题，同时具有较强的交联结构的结构。解决方案：成型体包括薄膜形状，片状或通过在分子中自由基聚合具有含有自由基聚合性碳 - 碳双键和氢化硅烷基的有机基团的化合物而获得，其中每碳 - 碳双键的分子量为100-5,000 每个氢甲硅烷基的分子量为25-1,000，使所得聚合物主要固化成具有烷氧基甲硅烷基的薄膜形状，片状或厚板状，并将获得的主要固化物质与碱性水溶液接触以使烷氧基甲硅烷基脱氢缩合。

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