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1. 发明专利

JPS5730787A Method for catalytic reaction of heavy petroleum oil 失效
标题翻译：重油石油催化反应方法
公开(公告)号：JPS5730787A
公开(公告)日：1982-02-19
申请号：JP10429480
申请日：1980-07-31
申请人： Nippon Oil Co Ltd
发明人： USHIO MASARU , MORITA TOORU , ISHII TAKESHI , OOISHI YASUYUKI
IPC分类号： C10G9/24 , C10G9/00 , C10G11/00 , C10G35/04 , C10G45/00 , C10G47/00
摘要： PURPOSE: To improve the utilization efficiency of solid medium in the catalytic reaction of heavy petroleum oil, by separating the magnetizable particulate solid medium coated with the metal deposited from the heavy petroleum oil by the catalytic reaction and the nonmagnetizable particulate solid medium using a magnetic separator, and then reusing the latter medium for the reaction.
CONSTITUTION: Heavy petroleum oil consisting of petroleum oil containing fractions having boiling point of ≥190°C (or a product obtained therefrom by hydrogenative desulfurization) is made to react in a catalytic reactor containing particulate solid medium having particle diameter of ≤5cm (pref. 0.1W500μm). After the reaction, at least a part of the medium is extracted from the reactor, and passed through a magnetic separator having a magnetic field of usually 1,000W20,000 gauss or more to separate the magnetizable particles from the nonmagnetizable particles, which are then returned to the catalytic reactor and reused.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：为了提高固体介质在重质石油的催化反应中的利用效率，通过使用磁选机分离涂覆有重质石油油沉积的金属的可磁化颗粒固体介质和不可磁化颗粒固体介质，然后重新使用后一种反应介质。构成：将含有沸点> = 190℃的馏分的石油油（或通过氢化脱硫得到的产物）组成的重质石油在包含粒径<= 5cm的颗粒状固体介质的催化反应器中反应（优选0.1-500mum）。反应后，将介质的至少一部分从反应器中取出，并通过具有通常为1,000〜20,000高斯或更高的磁场的磁选机，以将可磁化颗粒与不可磁化的颗粒分离，然后将其还原至催化反应器并重新使用。

2. 发明专利

JPS6337835B2 失效
公开(公告)号：JPS6337835B2
公开(公告)日：1988-07-27
申请号：JP18706580
申请日：1980-12-30
申请人： NIPPON OIL CO LTD
发明人： USHIO MASARU , MORITA TOORU , ISHII TAKESHI
IPC分类号： C10G11/18 , B01J37/00 , B01J38/00 , C01B3/38 , C10G11/02 , C10G11/20

3. 发明专利

JPS57159884A FLUIDIZED CATALYTIC CRACKING OF HEAVY OILS 失效
公开(公告)号：JPS57159884A
公开(公告)日：1982-10-02
申请号：JP4540581
申请日：1981-03-30
申请人： NIPPON OIL CO LTD
发明人： USHIO MASARU , MORITA TOORU , ISHII TAKESHI
IPC分类号： C10G11/18 , B01J29/00 , B01J37/34 , B01J38/00 , C10G69/04
摘要： PURPOSE:To reduce a necessary catalyst amount, by a method wherein the catalyst particle withdrawn from a fluidized cat cracker is sent to a high magnetic force magnetic separator to be separated into a magnetizable catalyst particle and a non-magnetizable catalyst particle and the latter is returned to the cracker to be reused therein. CONSTITUTION:A fluidized catalytic cracking catalyst such as silica-alumina containing a zeolite is used and, while part of the catalyst is replaced with a new catalyst, heavy oils are subjected to fluidized catalytic cracking. Part of the catalkyst particle with a prticle size of 1-1,000mu fluidized in a cat cracker is withdrawn and, by using air, steam or nitrogen as a transfer fluid, transferred to a high magnetic force magnetic separtor with a particle concn. of 0.01-500g/l and at a transfer fluid speed of 0.1-100m/sec. In this separator,the transferred particle is separted into a magnetizable catalyst particle containing 500ppm or more of ferromagnetic nickel derived from nickel contained in the stock oil and a non-magnetizable catalyst particle and the latter is returned into the cracker to be reused therein.

4. 发明专利

JPS5730788A Catalytic cracking of heavy petroleum oil 失效
标题翻译：重油石油催化裂化
公开(公告)号：JPS5730788A
公开(公告)日：1982-02-19
申请号：JP10429680
申请日：1980-07-31
申请人： Nippon Oil Co Ltd
发明人： USHIO MASARU , MORITA TOORU , ISHII TAKESHI
IPC分类号： C10G11/18 , C10G69/04
摘要： PURPOSE: To economize the catalyst in the catalytic cracking of heavy petroleum oil, by separating the magnetizable particles coated with metals deposited from the heavy petroleum oil by the catalytic cracking and the nonmagnetizable particles using a high-gradient magnetic separator, and reusing the former particles after the removal of the metals and the latter particles as they are to the cracking reaction.
CONSTITUTION: A part of the fluidized catalyst particles are extracted from the fluidized catalytic cracking apparatus of heavy petroleum oil, and passed through a high-gradient magnetic separator containing ferromagnetic packing in a space having uniform and high magnetic field to separate the magnetizable catalyst particles magnetized by the deposited Ni, V, iron and copper contained in the heavy petroleum oil from the nonmagnetizable catalyst particles. The nonmagnetizable particles are returned directly, and the magnetizable particles are returned after removing the metals, to the catalytic cracking apparatus, and reused.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：为了节省重质石油油催化裂化催化剂，通过催化裂化分离沉积在重质石油中的金属的可磁化颗粒和使用高梯度磁选机分离出不可磁化颗粒，并重新使用前颗粒在将金属和后者颗粒原样除去至裂化反应之后。构成：将一部分流化催化剂颗粒从重质石油油的流化催化裂化装置中提取出来，并通过含有铁磁性填料的高梯度磁选机在具有均匀高磁场的空间中分离出磁化的可磁化催化剂颗粒通过由不可磁化的催化剂颗粒沉积在重质石油中的Ni，V，铁和铜。不可磁化的颗粒直接返回，并且在除去金属之后使可磁化颗粒返回到催化裂化装置中并重新使用。

5. 发明专利

JPS5734189A Fluid catalytic cracking of heavy petroleum including distillation residue 失效
标题翻译：含重油的重油催化裂化
公开(公告)号：JPS5734189A
公开(公告)日：1982-02-24
申请号：JP10822380
申请日：1980-08-08
申请人： Nippon Oil Co Ltd
发明人： USHIO MASARU , MORITA TOORU , ISHII TAKESHI
IPC分类号： C10G11/18
摘要： PURPOSE: To save an amt. of a catalyst used without lowering conversion ratio, by reusing a nonmagnetic catalyst obtd. by catalytically treating heavy petroleum, chemically treating a catalyst separated from the cracked product and then treating it with a high-gradient magnetic separator.
CONSTITUTION: Heavy petroleum including a distillation residue such as an atmospheric distillation bottom from crude oil in cracked into gasoline, kerosine, gas oil etc. by contact with a silica-alumina catalyst, etc. After the catalyst is separated from the cracked product and subjected to chemical treatment such as oxidation with air at about 500W800°C, it is treated with a high-gradient magnetic separator constituted of a uniformly highly magnetic space contg. a ferromagnetic filler, separating into a magnetic catalyst particle on which Ni, V, Fe, etc. have deposited and a nonmagnetic catalyst particle. Only said nonmagnetic catalyst particle is returned to the catalytic cracking unit and reused.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：为了节省成本。的催化剂，而不降低转化率，通过重新使用非磁性催化剂。通过催化处理重质石油，化学处理从裂化产物分离的催化剂，然后用高梯度磁选机处理。构成：通过与二氧化硅 - 氧化铝催化剂接触等将原油中的蒸馏残渣（例如原油的蒸馏残渣）裂解成汽油，煤油，瓦斯油等重质石油。将催化剂与裂化产物分离后，进行化学处理，如在约500-800℃的空气中氧化，用高均匀高磁性空间的高梯度磁选机处理。铁磁填料，分离成沉积有Ni，V，Fe等的磁性催化剂颗粒和非磁性催化剂颗粒。只有所述非磁性催化剂颗粒返回到催化裂化装置并重复使用。

6. 发明专利

JPS5734188A Fluid catalytic cracking of heavy petroleum including distillation residue 失效
标题翻译：含重油的重油催化裂化
公开(公告)号：JPS5734188A
公开(公告)日：1982-02-24
申请号：JP10822280
申请日：1980-08-08
申请人： Nippon Oil Co Ltd
发明人： USHIO MASARU , MORITA TOORU , ISHII TAKESHI
IPC分类号： C10G11/18
摘要： PURPOSE: To save an amt. of a catalyst used without lowering conversion ratio, by reusing as a catalyst a nonmagnetic material obtd. by catalytically treating heavy petroleum with addition of a metal contaminant-passivating agent, and then treating a catalyst separated from the cracked product by a high-gradient magnetic separator.
CONSTITUTION: Heavy petroleum including a distillation residue such as an atmospheric distillation bottom from crude oil is cracked with addition of a metal contaminant-passivating agent such as antimony trioxide into gasoline, kerosine, gas oil, etc. by contact with a silica-alumina catalyst, etc. The catalyst is separated from the cracked product, and then separated into a magnetic catalyst particle on which N, V, Fe, etc. have deposited and a nonmagnetic catalyst particle by treatment with a high-tradient magnetic separator constituted of a uniformly highly magnetic field contg. a ferromagnetic material. Only said nonmagnetic catalyst particle in returned to the catalytic cracking unit and reused.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：为了节省成本。的催化剂，而不降低转化率，通过重新使用非磁性材料作为催化剂。通过加入金属污染物钝化剂催化处理重质石油，然后用高梯度磁选机处理从裂化产物分离的催化剂。构成：通过与二氧化硅 - 氧化铝催化剂接触，向汽油，煤油，瓦斯油等中加入金属污染物钝化剂，例如三氧化锑等，将原油等含有蒸馏残渣（如原油的常压蒸馏塔底）的重质石油裂化等等。将催化剂与裂化产物分离，然后分离成其中沉积有N，V，Fe等的磁性催化剂颗粒和通过用均匀地构成的高通量磁选机处理的非磁性催化剂颗粒高磁场强度铁磁材料。只有非磁性催化剂颗粒才返回到催化裂化装置并重新使用。

7. 发明专利

JPS5730786A Method for catalytic reaction of heavy petroleum oil 失效
标题翻译：重油石油催化反应方法
公开(公告)号：JPS5730786A
公开(公告)日：1982-02-19
申请号：JP10429380
申请日：1980-07-31
申请人： Nippon Oil Co Ltd
发明人： USHIO MASARU , MORITA TOORU , ISHII TAKESHI , OOISHI YASUYUKI
IPC分类号： C10G9/24 , B01J23/90 , C10G11/00 , C10G45/18
CPC分类号： C10G45/18 , B01J23/90
摘要： PURPOSE: To improve the utilization efficiency of solid medium in the catalytic reaction of heavy petroleum oil, by separating the magnetizable particulate solid medium coated with the metal deposited from the heavy petroleum oil by the catalytic reaction and the nonmagnetizable particulate solid medium using a high-gradient magnetic separator, and then reusing the latter medium for the reaction.
CONSTITUTION: At least a part of particulate solid medium is extracted from a catalytic reactor of heavy petroleum oil and the solid medium, and passed through a high-gradient (2,000×10
3 W20,000×10
3 gauss/cm) magnetic separator which contains ferromagnetic packing in a space having uniform and high magnetic field. The magnetizable medium particles which are magnetized by the deposition of Ni, V, iron, and copper contained in the heavy petroleum oil are separated from the nonmagnetizable medium particles, which are returned to the catalytic reactor and reused. The ferromagnetic packing is an aggregate of ferromagnetic fine filaments of usually 1W1,000μm in diameter, e.g. steel wool, steel net, etc.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：为了提高固体介质在重质石油的催化反应中的利用效率，通过催化反应和不可磁化的颗粒状固体介质分离涂覆有重金属沉积的金属的可磁化颗粒固体介质，梯度磁选机，然后重新使用后一种反应介质。构成：从重质石油油和固体介质的催化反应器中提取至少一部分颗粒状固体介质，并通过高梯度（2,000×10 -3 -20,000×10 3高斯/ cm）磁选机其在具有均匀和高磁场的空间中包含铁磁填料。通过沉积重质石油中所含的Ni，V，铁和铜而被磁化的可磁化介质颗粒与不可磁化介质颗粒分离，返回到催化反应器并重新使用。铁磁填料是直径通常为1-1000μm的铁磁细丝的集合体，例如钢丝绒，钢丝网等

8. 发明专利

JPS6337156B2 失效
公开(公告)号：JPS6337156B2
公开(公告)日：1988-07-22
申请号：JP5947380
申请日：1980-05-07
申请人： NIPPON OIL CO LTD
发明人： USHIO MASARU , MORITA TOORU , ISHII TAKESHI
IPC分类号： C10B57/04 , C10G11/18

9. 发明专利

JPS6024831B2 失效
公开(公告)号：JPS6024831B2
公开(公告)日：1985-06-14
申请号：JP16565979
申请日：1979-12-21
申请人： NIPPON OIL CO LTD
发明人： USHIO MASARU , MORITA TOORU , ISHII TAKESHI
IPC分类号： B01J21/20 , C10G11/18

10. 发明专利

JPS57115488A FLUIDIZED CATALYTIC CRACKING METHOD OF HEAVY PETROLEUM 失效
公开(公告)号：JPS57115488A
公开(公告)日：1982-07-17
申请号：JP18706580
申请日：1980-12-30
申请人： NIPPON OIL CO LTD
发明人： USHIO MASARU , MORITA TOORU , ISHII TAKESHI
IPC分类号： C10G11/18 , B01J37/00 , B01J38/00 , C01B3/38 , C10G11/02 , C10G11/20
摘要： PURPOSE:To improve the conversion of heavy petroleum in the fluidized bed catalytic cracking, by feeding catalytic particles flowing through a fluidized catalytic cracking apparatus partially to a high gradient magnetic separator, and removing the metal in the heavy oil as magnetized catalytic particles. CONSTITUTION:Catalytic cracking particles, having a particle diameter of 5- 200mu, and flowing through a fluidized catalytic cracking apparatus having the respective zones of reaction, separation and stripping are partially taken out and fed to a high gradient magnetic separator containing net-like packings, having a wire diameter of 10-1,000mu and a size of 3-80 mesh, and made of a ferromagnetic material placed on top of each other in a space of a high magnetic field by a transferring gas, e.g. air, at a particle concentration of 0.01-500g/l and a transferring fluid speed of 0.01-100m/sec. The catalytic particles are separated into a magnetized catalytic particles magnetized by the deposition of a metal, e.g. nickel, contained in a heavy petroleum and unmagnetized catalytic particles, which are then returned to the cracking apparatus. The fluidized bed catalytic cracking of the heavy oil is carried out while reusing the returned catalytic particles.

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