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    • 1. 发明专利
    • Takahax desulfurization process
    • TAKAHAX脱硫工艺
    • JPS59159890A
    • 1984-09-10
    • JP3493883
    • 1983-03-03
    • Nippon Kokan Kk
    • FUJIMURA TAKEOSEKIKAWA AYAOMORISHITA YOSHIHIKOKOUMURA SEIJI
    • B01D53/52B01D53/34B01D53/54C10K1/12
    • PURPOSE: To maintain and improve desulfurizatin ratio in the Takahax desulfurization process, by introducing coke oven gas into an absorption tower and perfoming desulfurization under controlled density of an absorbing solution and gas/liquid ratio.
      CONSTITUTION: Coke oven gas 1 is introduced into an absorption tower 2 for absorption of NH
      3 , H
      2 S and HCN contained in the coke oven gas by an absorbing solution 3 and the absorbing solution is led into an oxidation tower 5 through a circulating tank 4 in the presence of a catalyst. In the oxidation tower, the absorbing solution 3 is brought into contact with air for oxidative regeneration and the regenerated solution is returned to the absorption tower 2. To maintain the ratio of desulfurization especially in summer season, etc., the density of absorbing solution and liquid/gas ratio are controlled through establishment of an optimum desulfurization ratio, measurement or estimate of the temperature of the absorbing solution and determination of the specific gravity of the solution. Thus a decrease in the specific gravity of the absorbing solution and an increase in the liquid/gas ratio make it possible to maintain an effective alkali concentration and prevent lowering of the desulfurization ratio even when the absorbing solution is at a high temperature.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:为了保持和提高Takahax脱硫工艺中的脱硫剂比例,将焦炉煤气引入吸收塔,并以吸收溶液和气液比控制密度进行脱硫。 构成:将焦炉煤气1引入到吸收塔2中,用于通过吸收溶液3吸收焦炉煤气中所含的NH 3,H 2 S和HCN,吸收溶液通过循环罐4引入氧化塔5中 存在催化剂。 在氧化塔中,吸收溶液3与空气接触进行氧化再生,再生溶液返回到吸收塔2.为了保持脱硫比特别是夏季等,吸收溶液的密度和 通过建立最佳脱硫比,吸收溶液的温度的测量或估计和溶液的比重的确定来控制液/气比。 因此,吸收溶液的比重的降低和液体/气体比的增加使得即使当吸收溶液处于高温时也可以保持有效的碱浓度并防止脱硫率的降低。
    • 2. 发明专利
    • Removal of ammonia in ammonium sulfate solution
    • 在硫酸铵溶液中去除氨
    • JPS58219983A
    • 1983-12-21
    • JP10431182
    • 1982-06-17
    • Nippon Kokan Kk
    • KATOU TOMONORISEKIKAWA AYAOMATSUMURA SUSUMUTAWARA TSUTOMUKOUMURA SEIJI
    • C02F1/20C02F1/58
    • PURPOSE: To remove ammonia in good efficiency, by adding a scale dispersant in an ammonium sulfate solution prior to introducing the ammonium sulfate solution having slaked lime added thereto into a still and a thermocompressor to prevent the clogging due to slaked lime.
      CONSTITUTION: The ammonium sulfate solution 2
      1 in an ammonium sulfate tank 1 is introduced into a first still 6 through a prefilter 3 and heat exchangers 4, 5 and, after free ammonia 8 in the ammonium sulfate solution 2
      1 is removed by steam 7, the treated solution is passed through a heat exchanger 5 to be introduced into a reaction tank 9 where slaked lime 10 is added. In the next step, the ammonium sulfate solution 2
      3 in the reaction tank 9 is introduced into a thickener 11 and, after slaked lime and reaction substances are precipitated and removed, the treated solution is introduced into a stock liquid tank 12 to be added with a scale dispersant 13 in an amount of 5W100ppm per 1m
      2 ammonium sulfate solution. The dispersant added solution is introduced into a second still 14 to remove free ammonia in the ammonium sulfate solution 2
      4 by steam 15
      1 and the treated solution is introduced into a thermocompressor 16 to be further subjected to activation treatment through a heat exchanger 4.
      COPYRIGHT: (C)1983,JPO&Japio
    • 目的:为了在将硫酸铵溶液加入到静止和热压机中之前加入硫酸铵溶液中的硫酸铵溶液,以防止由于熟石灰引起的堵塞,为了有效地除去氨。 构成:硫酸铵罐1中的硫酸铵溶液21通过预滤器3和热交换器4,5引入第一静止物6,并且在蒸汽7中除去硫酸铵溶液21中的游离氨8后,处理过的 溶液通过热交换器5以引入反应罐9中,其中加入熟石灰10。 在下一步骤中,将反应罐9中的硫酸铵溶液23引入增稠剂11中,在将石灰和反应物质沉淀除去之后,将处理后的溶液引入储液罐12中,加入 规模分散剂13,每1m 2硫酸铵溶液为5-100ppm。 将分散剂添加溶液引入第二静止物14中以通过蒸汽151除去硫酸铵溶液24中的游离氨,并将处理过的溶液引入热压机16中,以进一步通过热交换器4进行活化处理。
    • 3. 发明专利
    • Production of ammonium sulfate
    • 生产硫酸铵
    • JPS59162125A
    • 1984-09-13
    • JP3493783
    • 1983-03-03
    • Nippon Kokan Kk
    • FUJIMURA TAKEOSEKIKAWA AYAOMORISHITA YOSHIHIKOKOUMURA SEIJI
    • C01C1/24B01D9/02
    • PURPOSE: In the production of ammonium sulfate crystals by concentration of ammonium sulfate mother liquor, the steam formed in the evaporator is pressurized to raise its temperature and utilize as a heat source for the heater whereby the steam for heating is made unnecessary and corrosion of the equipment and local precipitation are prevented.
      CONSTITUTION: The mother liquor of ammonium sulfate 1 is sent by pump 11 through crystallizer 2 to heater 3 where its temperature is raised up with steam 4. The hot mother liquor 1 is introduced into the evaporator which is kept in vacuum 5 where water is distilled off, then the concentrated liquor 1' is introduced through the vertical tube 8 into the salt collector 12 which is set at the bottom of the crystallizator 2 where crystalls of ammonium sulfate are fromed and the product is sent, in the form of a slurry, to the following process such as dehydration and drying. In the meantime, the steam formed in the evaporator 5 is introduced through cyclone 13 into the vapor compressor 14 where it is compressed until its temperature rises up to 78.5°C and the steam 4 is fed to the heater 3 to heat the ammonium sulfate mother liquor 1.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:在通过浓缩硫酸铵母液生产硫酸铵晶体时,在蒸发器中形成的蒸汽被加压以提高其温度并用作加热器的热源,从而不需要用于加热的蒸汽和腐蚀 防止设备和地方降水。 构成:硫酸铵1的母液由泵11通过结晶器2送到加热器3,加热器3的温度用蒸汽4升高。将热母液1引入蒸发器中,蒸发器保持在真空5中,蒸馏水 然后将浓缩液1'通过垂直管8引入到盐析器12中,该盐收集器12设置在结晶器2的底部,其中硫酸铵的结晶被从浆液中形成,产物被送出, 进行以下处理,如脱水和干燥。 同时,在蒸发器5中形成的蒸汽通过旋风分离器13引入蒸气压缩机14中,在那里被压缩直到其温度上升到78.5℃,蒸汽4被送入加热器3以加热硫酸铵 母酒1。
    • 4. 发明专利
    • Treatment of waste liquid of high ammonia concentration with activated sludge
    • 用激活的泥浆处理高浓度氨水浓度的废液
    • JPS59160593A
    • 1984-09-11
    • JP3493983
    • 1983-03-03
    • Nippon Kokan Kk
    • FUJIMURA TAKEOSEKIKAWA AYAOMORISHITA YOSHIHIKOKOUMURA SEIJITAWARA TSUTOMU
    • C02F3/12
    • Y02W10/15
    • PURPOSE: To perform treatment of waste liquid of high ammonia concn. without pretreatment or dilution by adjusting the concn. of dissolved oxygen in an aeration tank contg. waste liquid of high ammonia concn. to 0.1W0.5ppm and performing treatment with activated sludge for the adjusted waste liquid.
      CONSTITUTION: Ammonia liquor having 5,000ppm ammonia concn. is charged to an aeration tank and aerated to 0.3ppm dissolved oxygen. and then subjected to the treatment with activated sludge. As the result, SCN
      - is held always at ≤3ppm; the superiority of the performance of the treatment is thus recognized. The control of the dissolved oxygen in the aeration tank is performed by the control of the working number of stirrers in accordance with detection signals issued by a measuring instrument for the dissolved oxygen installed in the aeration tank, or by other means. For the control of the dissolved oxygen, it is desirable to use simultaneously oxidation-reduction potential and pH as the measure for the operation. By this way, treatment of waste liquid of high ammonia concn. is possible without dilution.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:对高氨浓度废液进行处理。 没有预处理或稀释调整浓度 的曝气池中的溶解氧 高氨浓度废液 至0.1〜0.5ppm,并对调整废液进行活性污泥处理。 构成:氨水浓度为5000ppm的氨液 充入曝气池并充气至0.3ppm溶解氧。 然后用活性污泥进行处理。 因此,SCN < - >始终保持在<= 3ppm; 因此认识到治疗性能的优越性。 通过根据由安装在曝气池中的溶解氧的测量仪器发出的检测信号或通过其他方式控制搅拌器的工作数量来进行曝气池中的溶解氧的控制。 为了控制溶解氧,期望同时使用氧化还原电位和pH作为操作的量度。 通过这种方式,处理高氨浓度的废液。 是没有稀释的可能。