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1. 发明专利

JP2013091797A Copolymer latex for adhesive for rubber and fiber, and composition for adhesive 有权
标题翻译：用于橡胶和纤维的粘合剂的粘合剂和用于粘合剂的组合物
公开(公告)号：JP2013091797A
公开(公告)日：2013-05-16
申请号：JP2012274884
申请日：2012-12-17
申请人： Nippon A&L Inc , 日本エイアンドエル株式会社
发明人： TAKENAKA TAKASHI , MISAKI KOYU , KAMIMURA AKIRA
IPC分类号： C09J109/10 , C08F226/06 , C08F236/04 , C09J111/02 , C09J161/12
摘要： PROBLEM TO BE SOLVED: To provide a polymer latex for an adhesive for rubber and fiber which achieves extremely low generation of coarse aggregates generated in a polymerization reaction, does not require excess heating from outside the polymerization reaction system, and has excellent energy-saving properties and good efficiency.SOLUTION: A copolymer latex is obtained by performing emulsion polymerization of the total 100 pts.wt. of a polymerizable monomer comprising 30-80 pts.wt. of an aliphatic conjugate diene, 5-30 pts.wt. of vinylpyridine, and 0-65 pts.wt. of another monomer which is copolymerizable with them. The copolymer latex for an adhesive for rubber and fiber is obtained by a production method, in which the polymerization starts when a temperature T1 in the polymerization system is in the range of 0-40°C after the feed of a part of or all of the monomer is finished, and then the temperature T2 in the polymerization system is made to reach the range of 45-80°C, at least 15% of the heat quantity necessary to raise the temperature (T2-T1) is obtained by utilizing the heat of polymerization resulting from the polymerization.
摘要翻译：要解决的问题：为了提供用于橡胶和纤维的粘合剂的聚合物胶乳，其在聚合反应中产生极少的粗骨料产生，不需要从聚合反应体系外部进行过量的加热，并且具有优异的能量保存性能好，效率高。解决方案：通过进行总共100重量份的乳液聚合获得共聚物胶乳。的可聚合单体，其包含30-80重量份的脂肪族共轭二烯，5-30重量份的乙烯基吡啶，和0-65重量份的可与其共聚的另一种单体。用于橡胶和纤维的粘合剂的共聚物胶乳通过一种制备方法获得，其中当聚合体系中的温度T1在0-40℃的范围内时，聚合开始于部分或全部单体结束后，使聚合体系中的温度T2达到45〜80℃的范围，通过利用该温度得到提高温度所需的热量的至少15％（T2-T1）由聚合引起的聚合热。版权所有（C）2013，JPO＆INPIT

2. 发明专利

JP2009286894A Manufacturing method of copolymer latex for adhesive between rubber and fiber, copolymer latex for adhesive, and composition for adhesive 有权
标题翻译：橡胶和纤维之间的粘合剂的共聚物胶乳的制造方法，粘合剂的共聚物和粘合剂的组合物
公开(公告)号：JP2009286894A
公开(公告)日：2009-12-10
申请号：JP2008140662
申请日：2008-05-29
申请人： Nippon A&L Inc , 日本エイアンドエル株式会社
发明人： TAKENAKA TAKASHI , MISAKI KOYU , KAMIMURA AKIRA
IPC分类号： C08F236/04 , C08F2/22 , C08F226/06 , C09J109/10 , C09J139/08 , C09J157/00 , C09J161/04
摘要： PROBLEM TO BE SOLVED: To provide an energy-saving efficient copolymer latex, which hardly generates bulky aggregates during a polymerization reaction and requires no excessive heating from the outside of a polymerization reaction system, for an adhesive between rubber and fibers. SOLUTION: The copolymer latex is obtained by emulsifying polymerization of 100 pts.wt. of a polymerizable monomer composed of 30-80 pts.wt. of an aliphatic conjugated diene, 5-30 pts.wt. of a vinylpyridine, and 0-65 pts.wt. of another polymer copolymerizable with them. In the manufacturing method of the copolymer latex for an adhesive between rubber and fibers, after completion of preparation of the whole or a part of the monomers, a temperature T2 in the polymerization system is brought to the range of 45-80°C after polymerization is started when a temperature T1 in the polymerization system is within the range of 0-40°C, and in this process, 15% or more of the quantity of heat necessary for temperature increase (T2-T1) uses polymerization heat by the polymerization. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种在聚合反应期间几乎不产生大体积聚集体并且不需要从聚合反应体系的外部过度加热的节能高效共聚物胶乳，用于橡胶和纤维之间的粘合剂。解决方案：通过乳化100重量份的聚合获得共聚物胶乳。的可聚合单体由30-80重量份组成的脂肪族共轭二烯，5-30重量份的乙烯基吡啶，和0-65重量份可与其共聚的另一种聚合物。在橡胶和纤维之间的粘合剂用共聚物胶乳的制造方法中，在全部或部分单体完成后，聚合体系中的温度T2在聚合后达到45-80℃的范围当聚合体系中的温度T1在0-40℃的范围内时开始，在该过程中，升温所需的热量（T2-T1）的15％以上通过聚合使用聚合热。版权所有（C）2010，JPO＆INPIT

3. 发明专利

JP2013107942A Aqueous flame-retardant resin composition 审中-公开
标题翻译：水性阻燃树脂组合物
公开(公告)号：JP2013107942A
公开(公告)日：2013-06-06
申请号：JP2011251989
申请日：2011-11-17
申请人： Nippon A&L Inc , 日本エイアンドエル株式会社
发明人： MORI BUNZO , KAMIMURA AKIRA
IPC分类号： C08L101/00 , C08K5/49
摘要： PROBLEM TO BE SOLVED: To provide an aqueous flame-retardant resin composition exhibiting high flame retardancy without using halogen-based flame retardant, excellent in texture of obtained fiber products, and excellent in storage stability.SOLUTION: This aqueous flame-retardant resin composition includes 10-500 pts.wt. (solid content) of polyphosphate (b) and 0.5-10 pts.wt. (solid content) of a surfactant (c) to 100 pts.wt. (solid content) of a synthetic emulsion (a), and the total content of sodium and potassium in the synthetic emulsion (a) is 5,000 ppm or less to the solid content of the synthetic emulsion.
摘要翻译：要解决的问题：提供一种不使用卤素系阻燃剂而具有高阻燃性的水性阻燃性树脂组合物，所得纤维制品的质地优异，储存稳定性优异。该水性阻燃树脂组合物包含10-500重量份（固体含量）多磷酸盐（b）和0.5-10重量份（固体成分）表面活性剂（c）至100重量份（固体成分），合成乳液（a）中的钠和钾的总含量相对于合成乳液的固体成分为5000ppm以下。版权所有（C）2013，JPO＆INPIT

4. 发明专利

JP2011168720A Copolymer latex for adhesive 有权
标题翻译：胶粘剂胶粘剂
公开(公告)号：JP2011168720A
公开(公告)日：2011-09-01
申请号：JP2010035180
申请日：2010-02-19
申请人： Nippon A&L Inc , 日本エイアンドエル株式会社
发明人： TANEMURA JUNMI , TAKENAKA TAKASHI , KAMIMURA AKIRA
IPC分类号： C09J109/08 , C09J125/10 , D06M15/233 , D06M15/356 , D06M15/693
CPC分类号： C09J125/10 , C08L9/08 , C08L25/10 , C08L2205/02 , C09J109/08
摘要： PROBLEM TO BE SOLVED: To provide a copolymer latex for an adhesive that can enhance an adhesive force between a rubber and a rubber reinforcing fiber while inhibiting the deterioration of strength of the rubber reinforcing fiber due to heat treatment.
SOLUTION: A copolymer latex (A) produced by emulsion polymerization of (a) a monomer composition including 35-75 wt.% butadiene monomer, 10-30 wt.% vinylpyridine monomer and 10-55 wt.% styrene monomer, in an amount of 50-90 wt.% (in terms of solid content), and a copolymer latex (B) produced by emulsion polymerization of (b) a monomer composition including 3-25 wt.% butadiene monomer, 0-5 wt.% vinylpyridine monomer, 55-97 wt.% styrene monomer and 0-20 wt.% other copolymerizable monomers and not containing an ethylenically unsaturated carboxylic acid monomer, in an amount of 10-50 wt.% (in terms of solid content), are incorporated into a copolymer latex for an adhesive for adhesively bonding a rubber and a rubber reinforcing fiber.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种粘合剂用共聚物胶乳，其可以增强橡胶与橡胶增强纤维之间的粘合力，同时抑制由于热处理引起的橡胶增强纤维的强度的劣化。解决方案：通过（a）包含35-75重量％丁二烯单体，10-30重量％乙烯基吡啶单体和10-55重量％苯乙烯单体的单体组合物的乳液聚合制备的共聚物胶乳（A）以固体含量计的50-90重量％的量和通过（b）包含3-25重量％丁二烯单体的0-5重量％的单体组合物的乳液聚合制备的共聚物胶乳（B）％乙烯基吡啶单体，55-97重量％苯乙烯单体和0-20重量％的其它可共聚单体，不含乙烯基不饱和羧酸单体，其量为10-50重量％（以固体含量计）被引入用于粘合剂粘合橡胶和橡胶增强纤维的粘合剂的共聚物胶乳中。版权所有（C）2011，JPO＆INPIT

5. 发明专利

JP2010106089A Copolymer latex for rubber-polyester fiber adhesive 有权
标题翻译：用于橡胶聚酯纤维粘合剂的共聚物胶粘剂
公开(公告)号：JP2010106089A
公开(公告)日：2010-05-13
申请号：JP2008277649
申请日：2008-10-29
申请人： Nippon A&L Inc , 日本エイアンドエル株式会社
发明人： KAMIMURA AKIRA , TAKENAKA TAKASHI , TANEMURA JUNMI
IPC分类号： C09J109/06 , C08F212/08 , C08F236/06 , C08F257/02 , C09J11/06 , C09J113/02
摘要： PROBLEM TO BE SOLVED: To provide a copolymer latex for rubber-polyester fiber adhesives, which reduces the deterioration in the strength of fiber cords after high temperature vulcanization, has good adhesive forces between rubbers and fibers, little causes the bubbling of RFL liquids, and improves dipping workability.
SOLUTION: There is provided the copolymer latex for rubber-polyester fiber adhesives, characterized by comprising 50 to 90 pts.wt. (in terms of solid content) of a copolymer latex (A) obtained by emulsion-polymerizing 35 to 75 wt.% of butadiene, 10 to 30 wt.% of vinylpyridine and 10 to 55 wt.% of styrene, and 10 to 50 pts.wt. of a copolymer latex (B) having a glass transition temperature of 40 to 90°C and obtained by emulsion-polymerizing 3 to 20 wt.% of butadiene, 75 to 96.9 wt.% of styrene, 0.1 to 10 wt.% of an ethylenically unsaturated carboxylic acid, and 0 to 20 wt.% of one or more other copolymerizable monomers [wherein, the total amount of (A) and (B) is 100 pts.wt.].
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：为了提供橡胶 - 聚酯纤维粘合剂的共聚物胶乳，其降低高温硫化后的纤维帘线强度的劣化，在橡胶和纤维之间具有良好的粘合力，很少引起RFL的起泡液体，并提高浸渍加工性能。解决方案：提供了用于橡胶 - 聚酯纤维粘合剂的共聚物胶乳，其特征在于包含50至90重量份通过乳液聚合35〜75重量％的丁二烯，10〜30重量％的乙烯基吡啶和10〜55重量％的苯乙烯得到的共聚物胶乳（A）的固体含量（以固体含量表示）和10〜50 重量份的玻璃化转变温度为40〜90℃，通过乳液聚合3〜20重量％的丁二烯，75〜96.9重量％的苯乙烯，0.1〜10重量％的苯乙烯的共聚物胶乳（B）烯键式不饱和羧酸和0〜20重量％的一种或多种其它可共聚单体[其中（A）和（B）的总量为100重量份]。版权所有（C）2010，JPO＆INPIT

6. 发明专利

JP2005053950A Method for producing copolymer latex for chipping-resistant water-based coating 有权
标题翻译：用于生产用于抗水性涂料的共聚物漆的方法
公开(公告)号：JP2005053950A
公开(公告)日：2005-03-03
申请号：JP2003205792
申请日：2003-08-04
申请人： Nippon A & L Kk , 日本エイアンドエル株式会社
发明人： NISHIOKA TOSHITAKA , KAMIMURA AKIRA , ITAGAKI MAKOTO
IPC分类号： C08F2/22 , C08F236/04 , C08L45/00 , C09D5/02 , C09D109/08 , C09D109/10 , C09D151/00
CPC分类号： C08F2/22
摘要： PROBLEM TO BE SOLVED: To provide a copolymer latex for a chipping-resistant water-based coating remarkably improving balance among chipping resistance, adhesion to a metal substrate, water resistance and cooling/heating cycle resistance.
SOLUTION: The method for producing the copolymer latex for the chipping-resistant water-based coating is characterized as follows. When emulsion polymerization of 20-80 pts.wt. of a conjugated diene monomer, 0.5-15 pts.wt. of an ethylenically unsaturated carboxylic acid monomer, 5-40 pts.wt. of an aromatic vinylic monomer, 5-40 pts.wt. of an alkyl unsaturated carboxylate monomer and 0-69.5 pts.wt. of other vinylic monomers copolymerizable therewith (the total of the monomers is 100 pts.wt.) is carried out, 5-50 wt.% of the aromatic vinylic monomer and 5-50 wt.% of the alkyl unsaturated carboxylate monomer are added in the latter term of the polymerization, respectively.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种用于耐崩裂性水性涂料的共聚物胶乳，显着提高耐切割性，与金属基材的粘附性，耐水性和冷却/加热循环耐受性之间的平衡。解决方案：制备用于耐切屑水性涂料的共聚物胶乳的方法的特征如下。当乳液聚合20-80重量份的共轭二烯单体，0.5-15重量份的烯属不饱和羧酸单体，5-40重量份的芳族乙烯基单体，5-40重量份的烷基不饱和羧酸酯单体和0-69.5重量份可与其共聚的其它乙烯基单体（总共单体为100重量份），将5-50重量％的芳族乙烯基单体和5-50重量％的烷基不饱和羧酸酯单体加入分别是聚合的后一项。版权所有（C）2005，JPO＆NCIPI

7. 发明专利

JP2007186585A Latex composition for adhesive for ethylene-propylene rubber and fiber 审中-公开
标题翻译：用于乙烯 - 丙烯橡胶和纤维的胶粘剂组合物
公开(公告)号：JP2007186585A
公开(公告)日：2007-07-26
申请号：JP2006005553
申请日：2006-01-13
申请人： Nippon A & L Kk , 日本エイアンドエル株式会社
发明人： KAMIMURA AKIRA , ITAGAKI MAKOTO , TAKENAKA TAKASHI , MORI BUNZO
IPC分类号： C09J109/10 , C09J139/08
摘要： PROBLEM TO BE SOLVED: To provide a latex composition for an adhesive that has little lowering of cord strength after heat processing and provides good adhesion between an ethylene-propylene rubber and a fiber.
SOLUTION: The latex composition for an adhesive for an ethylene-propylene rubber and a fiber comprises 10-90 pts.wt. (solid content conversion) of a copolymer latex (A) obtained by emulsion-polymerizing 50-80 wt.% of an aliphatic conjugated diene-based monomer, 5-30 wt.% of a vinylpyridine-based monomer, and 0-45 wt.% of another monomer that can be copolymerized with them and 10-90 pts.wt. (solid content conversion) of polyisoprene latex (wherein, the total of the copolymer latex (A) and the polyisoprene latex (B) is 100 pts.wt.).
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种粘合剂用胶乳组合物，其在热处理后几乎不降低帘线强度，并且在乙丙橡胶和纤维之间提供良好的粘附性。解决方案：用于乙丙橡胶和纤维的粘合剂的胶乳组合物包含10-90重量份通过乳液聚合50-80重量％的脂族共轭二烯类单体，5-30重量％的乙烯基吡啶类单体和0-45重量％的共聚物胶乳（A）的固体成分（固体成分转化率）可以与它们共聚的另一种单体的百分比和10-90重量份（固体成分转化率）聚异戊二烯胶乳（其中，共聚物胶乳（A）和聚异戊二烯胶乳（B）的总量为100重量份）。版权所有（C）2007，JPO＆INPIT

8. 发明专利

JP2007154126A Copolymer latex for adhesive of rubber and fiber 有权
标题翻译：用于粘合橡胶和纤维的共聚物胶粘剂
公开(公告)号：JP2007154126A
公开(公告)日：2007-06-21
申请号：JP2005354739
申请日：2005-12-08
申请人： Nippon A & L Kk , 日本エイアンドエル株式会社
发明人： KAMIMURA AKIRA , ITAGAKI MAKOTO , TAKENAKA TAKASHI , MORI BUNZO
IPC分类号： C09J109/10 , C09J139/08
摘要： PROBLEM TO BE SOLVED: To provide a copolymer latex having an excellent adhesive force between a rubber (especially an ethylene-propylene based rubber) and a fiber, and low in reduction of cord strength after heat treatment.
SOLUTION: The copolymer latex for adhesion of rubber and fiber comprises (A) 10-90 pts.wt. (solid content conversion) of a copolymer latex obtained by emulsion polymerization of 70-100 wt.% of an aliphatic conjugated diene with 0-30 wt.% of the other copolymerizable monomer, wherein the copolymer latex has 50-350 nm of a weight average particle diameter and forming a dry film with 0-60% of toluene insoluble part, and (B) 10-90 pts.wt. (solid content conversion) of a copolymer latex obtained by emulsion polymerization of 60-80 wt.% of an aliphatic conjugated diene, 5-20 wt.% of a vinylpyridine and 0-35 wt.% of the other monomer copolymerizable with them, wherein the sum of the (A) and (B) is 100 pts.wt.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种在橡胶（特别是乙烯 - 丙烯基橡胶）和纤维之间具有优异的粘合力的共聚物胶乳，并且热处理后帘线强度的降低低。解决方案：用于粘合橡胶和纤维的共聚物胶乳包含（A）10-90重量份（固体成分转化率）通过70-100重量％的脂肪族共轭二烯与0-30重量％的其它可共聚单体的乳液聚合获得的共聚物胶乳，其中共聚物胶乳具有50-350纳米的重量形成具有0-60％甲苯不溶部分的干膜，（B）10-90重量份通过乳液聚合获得的共聚物胶乳（固体成分转化率）为60-80重量％的脂族共轭二烯，5-20重量％的乙烯基吡啶和0-35重量％的可共聚的其它单体，其中（A）和（B）的和为100重量份。版权所有（C）2007，JPO＆INPIT

9. 发明专利

JP2005075921A Copolymer latex for adhesive of rubber and fiber 有权
标题翻译：用于粘合橡胶和纤维的共聚物胶粘剂
公开(公告)号：JP2005075921A
公开(公告)日：2005-03-24
申请号：JP2003307708
申请日：2003-08-29
申请人： Nippon A & L Kk , 日本エイアンドエル株式会社
发明人： KAMIMURA AKIRA , NISHIOKA TOSHITAKA , TAKENAKA TAKASHI
IPC分类号： C09J151/04 , C09J109/10 , C09J139/08 , D06M15/693
摘要： PROBLEM TO BE SOLVED: To provide a copolymer latex having good initial adhesive force between a rubber (especially ethylene-propylene-based rubber) and a fiber, and heat-resistant adhesive force.
SOLUTION: The copolymer latex for an adhesive of the rubber and the fiber is obtained by mixing a grafted copolymer latex (Y) obtained by subjecting 5-50 pts. wt. vinylpyridine and 0-50 pts. wt. other monomers copolymerizable therewith to graft polymerization in the presence of 100 pts. wt. copolymer latex (X) (expressed in terms of solid) obtained by subjecting 90-100 wt.% aliphatic conjugated diene and 0-10 wt.% other monomers copolymerizable therewith (except an ethylenic unsaturated carboxylic acid) to emulsion polymerization, with a copolymer latex (Z) obtained by subjecting 5-50 wt.% aliphatic conjugated diene, 5-25 wt.% vinylpyridine and 25-90 wt.% other monomers copolymerizable therewith to the emulsion polymerization, regulated so that the weight ratio of the solids of the components (Y) to (Z) may be (10/90)-(90/10) (with the proviso that the total of the components (Y) and (Z) is 100 pts. wt.).
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供在橡胶（特别是乙烯 - 丙烯类橡胶）和纤维之间具有良好初始粘合力的共聚物胶乳和耐热粘合力。解决方案：用于橡胶和纤维的粘合剂的共聚物胶乳通过混合通过经受5-50个点获得的接枝共聚物胶乳（Y）而获得。重量。乙烯基吡啶和0-50 pts。重量。可与其共聚的其它单体在100点的存在下进行接枝聚合。重量。共聚物胶乳（X）（以固体表示）通过使90-100重量％的脂族共轭二烯和0-10重量％的与其可共聚的其它单体（除了烯属不饱和羧酸）进行乳液聚合而获得，通过使5-50重量％的脂族共轭二烯，5-25重量％的乙烯基吡啶和25-90重量％的与其可共聚的其它单体进行乳液聚合而获得的胶乳（Z）被调节为使得固体的重量比组分（Y）至（Z）可以是（10/90） - （90/10）（条件是组分（Y）和（Z）的总量为100重量份）。版权所有（C）2005，JPO＆NCIPI

10. 发明专利

JP2005075920A Copolymer latex for adhesive of rubber and fiber 有权
标题翻译：用于粘合橡胶和纤维的共聚物胶粘剂
公开(公告)号：JP2005075920A
公开(公告)日：2005-03-24
申请号：JP2003307707
申请日：2003-08-29
申请人： Nippon A & L Kk , 日本エイアンドエル株式会社
发明人： KAMIMURA AKIRA , ITAGAKI MAKOTO , TAKENAKA TAKASHI
IPC分类号： C09J109/10 , C09J125/08 , C09J133/10 , C09J139/08 , D06M15/41 , D06M15/693
摘要： PROBLEM TO BE SOLVED: To provide a copolymer latex hardly causing reduction of cord strength after heat treatment, and having good adhesive force between a rubber (especially ethylene-propylene-based rubber) and a fiber.
SOLUTION: The copolymer latex for an adhesive of the rubber and the fiber comprises (A) 10-90 pts. wt. copolymer latex obtained by subjecting 90-100 t.% aliphatic conjugated dienic monomer and 0-10 wt.% other monomers copolymerizable therewith (except an ethylenic unsaturated carboxylic acid monomer) to emulsion polymerization, and (B) 10-90 pts. wt. copolymer latex obtained by subjecting 5-50 wt.% aliphatic conjugated dienic monomer, 5-25 wt.% vinylpyridine-based monomer and 25-90 wt.% other monomers copolymerizable therewith to the emulsion polymerization [with the proviso that the total of the components (A) and (B) is 100 pts. wt.].
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种几乎不会导致热处理后帘线强度降低并且在橡胶（特别是乙烯 - 丙烯类橡胶）和纤维之间具有良好粘合力的共聚物胶乳。解决方案：用于橡胶和纤维的粘合剂的共聚物胶乳包含（A）10-90重量份。重量。通过将90-100重量％的脂族共轭二烯单体和0-10重量％的与其共聚的其它单体（除了烯属不饱和羧酸单体除外）进行乳液聚合而获得的共聚物胶乳，和（B）10-90重量份。重量。通过使5-50重量％的脂族共轭二烯单体，5-25重量％的乙烯基吡啶类单体和25-90重量％的可与其共聚的其它单体进行乳液聚合而获得的共聚物胶乳[附带条件是组分（A）和（B）为100个。重量。版权所有（C）2005，JPO＆NCIPI

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