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    • 2. 发明专利
    • Hydrogen producing apparatus
    • 氢生产设备
    • JP2011116577A
    • 2011-06-16
    • JP2009273574
    • 2009-12-01
    • Ngk Spark Plug Co LtdTokyo Gas Co Ltd日本特殊陶業株式会社東京瓦斯株式会社
    • MITSUYA KOHEISHIMAMORI TORUHIKOSAKA HIDEAKIYASUDA ISAMUSHIRASAKI YOSHINORIKUROKAWA HIDETONISHII TAKUMI
    • C01B3/40C01B3/56
    • PROBLEM TO BE SOLVED: To provide a hydrogen producing apparatus where leaked carbon monoxide is as little as possible even when defects are caused in a hydrogen separating layer. SOLUTION: In the hydrogen producing apparatus where a raw material gas is reformed and hydrogen is generated, the raw material gas is reformed in a reforming catalyst layer 50 and hydrogen is generated, permeated selectively in the hydrogen separating layer 30 and then separated. Carbon monoxide in gases except hydrogen permeated through the hydrogen separating layer 30 is converted to a hydrocarbon gas in a converting catalyst layer 10. A second porous reaction preventing layer 20 and a first porous reaction preventing layer 40 preventing reactions between the component of the hydrogen separating layer 30 and catalytic components in respective layers are arranged between the reforming catalyst layer 50 and the hydrogen separating layer 30 and between the hydrogen separating layer 30 and the converting catalyst layer 10. In this way, the amount of the leaked carbon monoxide is minimized by the methanation of carbon monoxide in the converting catalyst layer 10 even if the defects are caused in the hydrogen separating layer 30. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供即使在氢分离层中产生缺陷的情况下,泄漏的一氧化碳尽可能少的制氢装置。 解决方案:在重整原料气体并产生氢气的氢气生产设备中,原料气体在重整催化剂层50中重整并产生氢,在氢分离层30中选择性渗透,然后分离 。 渗透通过氢分离层30的除了氢气之外的气体中的一氧化碳在转化催化剂层10中转化为烃气。第二多孔反应防止层20和第一多孔反应防止层40防止氢分离的组分之间的反应 层30和各层中的催化组分布置在重整催化剂层50和氢分离层30之间以及氢分离层30和转化催化剂层10之间。以这种方式,泄漏的一氧化碳的量被最小化 即使在氢分离层30中引起缺陷,转化催化剂层10中的一氧化碳的甲烷化。(C)2011,JPO和INPIT
    • 3. 发明专利
    • Hydrogen separation device and method for manufacturing hydrogen separation device
    • 氢分离装置及制氢装置的制造方法
    • JP2011143335A
    • 2011-07-28
    • JP2010004982
    • 2010-01-13
    • Ngk Spark Plug Co LtdTokyo Gas Co Ltd日本特殊陶業株式会社東京瓦斯株式会社
    • HIKOSAKA HIDEAKISHIMAMORI TORUMITSUYA KOHEIYASUDA ISAMUSHIRASAKI YOSHINORIKUROKAWA HIDETONISHII TAKUMI
    • B01D53/22B01D69/12B01D71/02C01B3/38C01B3/56H01M8/06
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To provide a hydrogen separation device which can inhibit the leakage of a feedstock gas and obtain high-purity hydrogen gas.
      SOLUTION: First, a hydrogen separation cylinder 3 for separating hydrogen gas from a gas containing hydrogen, is configured to include a porous support 60 which is a modified catalyst and concurrently a support, and a hydrogen-permeable membrane 10. The porous support 60 is constituted of a reaction inhibitory layer (the first porous layer) 40 covering the outside surface of a porous support layer 50, a hydrogen permeable membrane 30 formed covering the outside surface of the reaction inhibitory layer 40 and a reaction inhibitory layer 20 covering the outside of the hydrogen permeable layer 30. The hydrogen separation membrane 10 is so formed as to cover the reaction inhibitory layer 20. The hydrogen permeable layer 30 is filled with a hydrogen permeable metallic material Pd in the way the layer can be formed in the porous support 60, and the hydrogen permeable membrane 10 is of a Pd thin membrane type. As the hydrogen separation layer is double-structured as described, it is possible to inhibit a leak which occurs in one structural half of the hydrogen permeable layer 30, using the other structural half. Thus, a high purity hydrogen gas can be stably supplied.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种可以抑制原料气体泄漏并获得高纯度氢气的氢分离装置。 解决方案:首先,用于从含氢气体中分离氢气的氢气分离缸3被构造成包括多孔载体60,多孔载体60是改性催化剂,同时是载体和透氢膜10.多孔 载体60由覆盖多孔载体层50的外表面的反应抑制层(第一多孔层)40,覆盖反应抑制层40的外表面的形成的氢透过膜30和覆盖 氢分解膜10形成为覆盖反应抑制层20.氢可渗透层30填充有氢可渗透金属材料Pd,其层可以形成在 多孔支撑体60,氢透过膜10为Pd薄膜型。 由于氢分离层如上所述是双重结构的,所以可以使用另一结构半部分来抑制在氢可渗透层30的一个结构半部分中发生的泄漏。 因此,可以稳定地供给高纯度氢气。 版权所有(C)2011,JPO&INPIT
    • 4. 发明专利
    • Hydrogen separation apparatus
    • 氢分离装置
    • JP2009213960A
    • 2009-09-24
    • JP2008057981
    • 2008-03-07
    • Ngk Spark Plug Co LtdTokyo Gas Co Ltd日本特殊陶業株式会社東京瓦斯株式会社
    • MITSUYA KOHEISHIMAMORI TORUSHIRASAKI YOSHINORITSUNEKI TATSUYAKUROKAWA HIDETO
    • B01D53/22B01D63/00B01D63/06C01B3/38C01B3/56H01M8/06H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a hydrogen separation apparatus preventing a hydrogen separation cylinder from being damaged by a pressing member, when a seal member is pressed by the pressing member. SOLUTION: The pressing member 9 is a cylindrical pressing fittings, wherein the front end is abutted on the pressing plate 35 of a fixing fittings 11, and the rear end is abutted on the seal member 7. A straight part 53 having a surface parallel to an axial direction is formed on the seal member side of the inner peripheral surface of a through-hole 51 formed in the axial center of the pressing fittings 9. A tapered part 55 with an inner diameter getting larger toward the left side is formed on the fixing fittings 11 side. A round part 57 is formed between the straight part 53 and tapered part 55 for smoothly connecting both. Chamfered parts 59, 61 are formed at corner parts of both opening ends of the first through-hole 51. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种氢分离装置,其防止氢气分离筒被按压部件损坏,当密封部件被按压部件按压时。 解决方案:按压构件9是圆柱形的压配件,其中前端抵靠在固定配件11的压板35上,后端抵接在密封构件7上。具有 在形成于按压配件9的轴心的通孔51的内周面的密封部件侧形成有平行于轴向的表面。内径朝向左侧变大的锥形部55为 形成在固定配件11侧上。 在直线部分53和锥形部分55之间形成圆形部分57,以平滑地连接两者。 倒角部59,61形成在第一通孔51的两个开口端的角部。(C)2009,JPO&INPIT
    • 5. 发明专利
    • Hydrogen production apparatus
    • 氢生产设备
    • JP2011116576A
    • 2011-06-16
    • JP2009273573
    • 2009-12-01
    • Ngk Spark Plug Co LtdTokyo Gas Co Ltd日本特殊陶業株式会社東京瓦斯株式会社
    • HIKOSAKA HIDEAKISHIMAMORI TORUMITSUYA KOHEIYASUDA ISAMUSHIRASAKI YOSHINORIKUROKAWA HIDETONISHII TAKUMI
    • C01B3/40B01J23/755C01B3/56
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide a small hydrogen production apparatus with high durability. SOLUTION: In order to avoid diffusion of a nickel component in a porous body and a palladium component in a hydrogen separation layer 30, a reaction inhibition layer 40 formed of yttria-stabilized zirconia is formed on a reforming catalyst layer 50 which is a support of a bottomed tube shape having a catalytic function for reforming a raw material gas and a role as a support for the hydrogen separation layer 30, etc. The hydrogen separation layer 30 in which palladium as a hydrogen-permeable metal material is filled into a porous layer formed of stabilized zirconia is formed on the reaction inhibition layer 40. In order to protect the surface of the hydrogen separation layer 30, a surface protective layer 20 formed of yttria-stabilized zirconia is formed on the hydrogen separation layer 30. When a raw material gas is supplied to a hydrogen separation tube 3 thus formed from the reforming catalyst layer 50 side, the raw material gas is reformed in the reforming catalyst layer 50, hydrogen is separated by permeation in the hydrogen separation layer 30, and the remaining gas is discharged to the surface protective layer 20 side. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供具有高耐久性的小型氢气制备装置。 解决方案:为了避免镍组分在多孔体中的扩散和氢分离层30中的钯组分,在氧化钇稳定的氧化锆形成的反应抑制层40形成在重整催化剂层50上,重整催化剂层50是 具有用于重整原料气体的催化功能和作为氢分离层30的载体的作用的有底管形状的支撑体等。作为氢可渗透金属材料的钯被填充到其中的氢分离层30 在反应抑制层40上形成由稳定的氧化锆形成的多孔层。为了保护氢分离层30的表面,在氢分离层30上形成由氧化钇稳定的氧化锆形成的表面保护层20。 向由重整催化剂层50侧形成的氢分离管3供给原料气体,将原料气体在重整催化剂层50中重整,氢化 通过在氢分离层30中的渗透分离出原子,剩余的气体被排出到表面保护层20侧。 版权所有(C)2011,JPO&INPIT
    • 6. 发明专利
    • Hydrogen separation apparatus
    • 氢分离装置
    • JP2009184883A
    • 2009-08-20
    • JP2008026948
    • 2008-02-06
    • Ngk Spark Plug Co LtdTokyo Gas Co Ltd日本特殊陶業株式会社東京瓦斯株式会社
    • MITSUYA KOHEISHIMAMORI TORUSHIRASAKI YOSHINORITSUNEKI TATSUYAKUROKAWA HIDETO
    • C01B3/56B01D53/22C01B3/38C09K3/10H01M8/06
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To provide a hydrogen separation apparatus capable of preventing gas leakage from a sealing member. SOLUTION: The hydrogen separation apparatus 1 is equipped with a hydrogen separation cylinder 3, a fixing bracket 5 into which the open-end side of the hydrogen separation cylinder 3 is inserted, the sealing member 7 disposed between the outer surface of the hydrogen separation cylinder 3 and the inner surface of the fixing bracket 5 and a pressing bracket 9 that presses the anterior tip of the sealing member 7. The sealing member 7 is a cylindrical airtight member made of expanded graphite and is disposed in a space 41 between the inner surface of a tip cylindrical part 25 of the fixing bracket 5 and the outer surface of the hydrogen separation cylinder 3. The sealing member 7 comprises a first sealing member 43 disposed at the anterior tip and a second sealing member 45 disposed at the posterior tip. The first sealing member 43 comprises expanded graphite sheets that are laminated in the axial direction, and the second sealing member 45 comprises expanded graphite sheets that are laminated in the radial direction. COPYRIGHT: (C)2009,JPO&INPIT
    • 解决的问题:提供能够防止气体从密封部件泄漏的氢分离装置。 解决方案:氢分离装置1配备有氢分离筒3,固定支架5,氢分离筒3的开放端侧插入其中,密封部件7设置在氢分离筒3的外表面之间 氢气分离筒3和固定支架5的内表面以及按压密封部件7的前端的按压支架9.密封部件7是由膨胀石墨构成的圆筒形气密部件, 固定支架5的顶端圆筒部25的内表面和氢气分离筒3的外表面。密封部件7包括设置在前端部的第一密封部件43和设置在后方的第二密封部件45 小费。 第一密封构件43包括沿轴向层压的膨胀石墨片,第二密封构件45包括沿径向层压的膨胀石墨片。 版权所有(C)2009,JPO&INPIT
    • 7. 发明专利
    • Hydrogen separation apparatus
    • 氢分离装置
    • JP2009234798A
    • 2009-10-15
    • JP2008078891
    • 2008-03-25
    • Ngk Spark Plug Co LtdTokyo Gas Co Ltd日本特殊陶業株式会社東京瓦斯株式会社
    • MITSUYA KOHEISHIMAMORI TORUSHIRASAKI YOSHINORITSUNEKI TATSUYAKUROKAWA HIDETO
    • C01B3/56B01D53/22B01D69/04H01M8/06H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a hydrogen separation apparatus preventing extraneous substances such as metal fine particles from adhering to a hydrogen-permeable membrane.
      SOLUTION: A protective sleeve 13 is a cylindrical member which prevents extraneous substances suspended around a hydrogen separation tube 3, such as metal fine particles from adhering to the hydrogen separation tube 3 and has gas permeability by which it is permeable to hydrogen gas. Particularly, the protective sleeve 13 is composed of a web formed by cylindrically knitting yarn comprising fibers such as alumina fibers and tightly covers the entire outer surface of the hydrogen separation tube 3. The protective sleeve 13 has gas permeability by which it is permeable to hydrogen separated by the hydrogen separation tube 3 and supplied to the outer peripheral side, and a gap between the fibers of the protective sleeve 13 is made so small that fine particles of ≥0.5 μm cannot pass through the gap.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种氢分离装置,其防止诸如金属微粒的外来物质附着在透氢膜上。 解决方案:保护套筒13是一种圆柱形部件,其防止悬浮在诸如金属细颗粒的氢分离管3周围的外来物质附着到氢分离管3,并且具有透气性,通过氢气分离管 。 特别地,保护套13由通过包括诸如氧化铝纤维的纤维的圆筒编织纱线形成的网构成,并且紧密地覆盖氢分离管3的整个外表面。保护套筒13具有透气性,通过其可渗透氢 由氢分离管3分离并供给到外周侧,保护套13的纤维之间的间隙如此小,使得≥0.5μm的细颗粒不能通过间隙。 版权所有(C)2010,JPO&INPIT
    • 9. 发明专利
    • Hydrogen production system
    • 氢生产系统
    • JP2007269595A
    • 2007-10-18
    • JP2006099686
    • 2006-03-31
    • Ngk Spark Plug Co LtdTokyo Gas Co Ltd日本特殊陶業株式会社東京瓦斯株式会社
    • MITSUYA KOHEISHIMAMORI TORUSHIGAKI HIDEKAZUTANAKA HIROYUKIYASUDA ISAMUSHIRASAKI YOSHINORITSUNEKI TATSUYA
    • C01B3/56B01D53/22B01D69/10B01D71/02C01B3/38H01M8/06
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To provide a hydrogen production system which, while preventing the releasing or cracking of a porous support and a hydrogen-permeable membrane, prevents the diffusion and reaction between a metal component in the hydrogen-permeable membrane and a metal component in the porous substrate, and thus exhibits a long life even when used at a high temperature. SOLUTION: There is provided the hydrogen production system 1 having the following characteristics: an adhesion layer 3, a barrier layer 4, and the hydrogen-permeable membrane 5 are formed sequentially on the surface of the porous substrate 2; the porous substrate 2 contains a catalyst metal component; the hydrogen-permeable membrane 5 contains a hydrogen-permeable metal; the barrier layer 4 is a porous layer having a layer not containing the catalyst metal component; and the adhesion layer 3 is a porous layer having a thermal expansion coefficient between that of the porous substrate 2 and that of the barrier layer 4. There is also provided the hydrogen production system 1 having the following characteristics: an adhesion layer 3, a barrier layer 4, and a hydrogen-permeable membrane 5 are formed sequentially on the surface of the porous substrate 2; the porous substrate 2, the hydrogen-permeable membrane 5, and the barrier layer 4 are each the same as those described above; and the adhesion layer 3 is a porous layer containing the catalyst metal component in a quantity smaller than that contained in the porous substrate 2. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种氢制造系统,其在防止多孔载体和氢渗透膜的释放或破裂的同时,防止氢渗透膜中的金属成分与 多孔基材中的金属成分,即使在高温下使用也显示出长寿命。 解决方案:提供具有以下特征的氢气制备系统1:在多孔基材2的表面上依次形成粘合层3,阻挡层4和氢渗透膜5; 多孔基材2含有催化剂金属成分; 透氢膜5含有透氢性金属; 阻挡层4是具有不含催化剂金属成分的层的多孔层, 并且粘合层3是具有在多孔基材2和阻挡层4的热膨胀系数之间的热膨胀系数的多孔层。还提供具有以下特征的氢气生产系统1:粘附层3,阻挡层 层4和透氢膜5依次形成在多孔基材2的表面上; 多孔质基材2,透氢膜5和阻挡层4分别与上述相同; 粘合层3是含有比多孔质基材2中所含的催化剂金属成分少的多孔层。(C)2008,JPO&INPIT
    • 10. 发明专利
    • Hydrogen-permeable membrane module and its manufacturing method
    • 氢渗透膜模块及其制造方法
    • JP2007253066A
    • 2007-10-04
    • JP2006080943
    • 2006-03-23
    • Ngk Spark Plug Co LtdTokyo Gas Co Ltd日本特殊陶業株式会社東京瓦斯株式会社
    • YASUDA ISAMUSHIRASAKI YOSHINORITSUNEKI TATSUYASHIMAMORI TORUSHIGAKI HIDEKAZUTANAKA HIROYUKIMITSUYA KOHEI
    • B01D63/00B01D53/22B01D63/06B01D69/10C01B3/38
    • PROBLEM TO BE SOLVED: To obtain a hydrogen-permeable membrane module, which is characterized in that the anxiety of a gas leak at its bonded part is eliminated, without using an inorganic adhesive, without exposing the hydrogen-permeable membrane module to a soldering temperature and requiring twice labor apprehended in preceding technique, and its manufacturing method.
      SOLUTION: The hydrogen-permeable membrane module is constituted by joining a metal cap member to the outer peripheral surface of a cylindrical porous support or a cylindrical porous reforming catalyst and support and manufactured by a process (a) for joining the outer peripheral surface of the end part of the cylindrical porous support or the cylindrical porous reforming catalyst and support and the metal cap member by soldering using a metal solder material and a process (b) for forming a hydrogen-permeable membrane on the outer peripheral surface of the cylindrical porous support or the cylindrical porous reforming catalyst and support.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了获得一种氢渗透膜组件,其特征在于消除了在其接合部分处的气体泄漏的焦虑,而不使用无机粘合剂,而不将氢渗透膜组件暴露于 焊接温度及其前期技术要求两次劳动及其制造方法。 解决方案:透氢膜组件通过将金属盖构件连接到圆柱形多孔载体的外周表面或圆柱形多孔重整催化剂和支撑体构成,并通过用于连接外周的方法(a)制造 圆柱形多孔载体的端部表面或圆柱形多孔重整催化剂和支撑体和金属盖构件通过使用金属焊料材料进行焊接和用于在其外周表面上形成氢渗透膜的方法(b) 圆柱形多孔载体或圆柱形多孔重整催化剂和载体。 版权所有(C)2008,JPO&INPIT