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    • 1. 发明专利
    • Method of manufacturing oxide superconducting thin film
    • 氧化物超导薄膜的制造方法
    • JP2011198521A
    • 2011-10-06
    • JP2010061373
    • 2010-03-17
    • National Institute Of Advanced Industrial Science & TechnologySumitomo Electric Ind Ltd住友電気工業株式会社独立行政法人産業技術総合研究所
    • MANABE TAKAAKIYAMAGUCHI IWAOHIKATA TAKESHIOKI YASUTARO
    • H01B13/00C01G1/00C01G3/00
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing an oxide superconducting thin film, enabling manufacture of the oxide superconducting thin film having uniform-crystal-orientation high Ic by stacking calcined films produced in a MOD method to produce a thick calcined film and then applying glost firing heat treatment thereto.SOLUTION: The method is provided for manufacturing the oxide superconducting thin film in an application thermal decomposition method using a metal organic compound as a raw material. The method includes a stacked calcined film layer producing step of producing stacked calcined film layers by applying metal organic compound solution onto a substrate 10 to produce a coating film and then giving heat treatment to the coating film at a calcining heat treatment temperature for thermally decomposing organic components to be removed from the metal organic compound to produce the calcined film 20, in a repetitive manner, a crystallization suppressing layer producing step of producing a crystallization suppressing layer 30 on the uppermost layer out of the stacked calcined film layers for suppressing the crystallization of the stacked calcined film layers, and an oxide superconducting thin film producing step of producing the oxide superconducting thin film by giving heat treatment at a glost firing heat treatment temperature to the stacked calcined film layers to be crystallized.
    • 要解决的问题:为了提供一种制造氧化物超导薄膜的方法,能够通过将通过MOD方法制造的煅烧膜堆叠以制备厚的煅烧膜,从而制造具有均匀晶体取向的高Ic的氧化物超导薄膜,然后 对其进行烧灼热处理。解决方案:该方法用于在以金属有机化合物为原料的应用热分解方法中制造氧化物超导薄膜。 该方法包括:堆叠的煅烧膜层的制造步骤,通过将金属有机化合物溶液施加到基板10上以制备涂膜,然后在焙烧热处理温度下对涂膜进行热分解有机物 从金属有机化合物除去的成分,以重复的方式制造结晶抑制层的制造工序,在叠层的煅烧膜层的最上层制造结晶抑制层30,以抑制结晶化 堆叠的煅烧膜层和氧化物超导薄膜的生产步骤,通过在烧结热处理温度下进行热处理以生成氧化物超导薄膜,使堆叠的煅烧膜层结晶化。
    • 7. 发明专利
    • Oxide superconductive thin film wire rod manufacturing method
    • 氧化物超导薄膜生产线制造方法
    • JP2012129084A
    • 2012-07-05
    • JP2010280105
    • 2010-12-16
    • National Institute Of Advanced Industrial & TechnologySumitomo Electric Ind Ltd住友電気工業株式会社独立行政法人産業技術総合研究所
    • HANAFUSA KEINAKANISHI TAKESHIHONDA GENKINAGAISHI TATSUOKIYAMAGUCHI IWAOKUMAGAI TOSHIYAMANABE TAKAAKISHIMOYAMA JUNICHI
    • H01B13/00C01G1/00H01B12/06H01L39/24
    • Y02E40/642
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of an oxide superconductive thin film wire rod which, in manufacturing an oxide superconductive thin film wire rod by an MOD process, restrains a heterogeneous phase from being formed on an orientated metal substrate to ensure that an oxide superconductive thin film wire rod having desired superconducting characteristics will be manufactured.SOLUTION: A manufacturing method of an oxide superconductive thin film wire rod involves forming an oxide superconductive thin film from a metal organic compound by an application thermal decomposition process using an atmosphere furnace to manufacture an oxide superconductive thin film wire rod. The manufacturing method comprises a coated film making step in which a solution of a metal organic compound is applied to an orientated metal substrate having an intermediate layer formed therein to make a coated film, a temporary calcining step in which organic components contained in the metal organic compound of the coated film are removed by thermal decomposition to make a temporarily calcined film, and a formal calcining step in which the temporarily calcined film is crystallized to make an oxide superconductive thin film. The formal calcining step is a heat treatment step in which formal calcining is carried out under a low oxygen partial pressure and high temperature atmosphere, after which, in a region other than an oxide superconductor decomposition region, operation is performed to reduce oxygen partial pressure while the temperature is lowered to cool.
    • 解决的问题:提供一种氧化物超导薄膜线材的制造方法,其在通过MOD工艺制造氧化物超导薄膜线材时抑制在取向的金属基板上形成非均匀相, 确保制造具有期望的超导特性的氧化物超导薄膜线材。 解决方案:氧化物超导薄膜线材的制造方法包括通过使用气氛炉的施加热分解方法从金属有机化合物形成氧化物超导薄膜,以制造氧化物超导薄膜线材。 制造方法包括:涂膜制作步骤,其中将金属有机化合物的溶液施加到其中形成有中间层的定向金属基材上以制备涂膜;临时煅烧步骤,其中有机组分包含在金属有机 通过热分解除去涂膜的化合物以制备临时煅烧的膜,并且将临时煅烧的膜结晶以制备氧化物超导薄膜的正式煅烧步骤。 正式煅烧步骤是在低氧分压和高温气氛下进行正式煅烧的热处理步骤,然后在氧化物超导体分解区域以外的区域中进行操作以降低氧分压,同时 将温度降低冷却。 版权所有(C)2012,JPO&INPIT
    • 10. 发明专利
    • Oxide superconductive thin film wire rod and manufacturing method thereof
    • 氧化物超薄膜生产线及其制造方法
    • JP2012129085A
    • 2012-07-05
    • JP2010280106
    • 2010-12-16
    • National Institute Of Advanced Industrial & TechnologySumitomo Electric Ind Ltd住友電気工業株式会社独立行政法人産業技術総合研究所
    • HONDA GENKINAGAISHI TATSUOKINAKANISHI TAKESHIOKI YASUTAROHANAFUSA KEIMANABE TAKAAKIYAMAGUCHI IWAOKAMIYA KUNIOSHIMOYAMA JUNICHI
    • H01B13/00C01G1/00C01G3/00H01B12/06H01F6/06
    • Y02E40/642
    • PROBLEM TO BE SOLVED: To provide an oxide superconductive thin film wire rod which, owing to an oxide superconductive thin film formed in greater thickness, excels in superconducting characteristics showing sufficiently high Jc and Ic.SOLUTION: A manufacturing method of an oxide superconductive thin film wire rod involves forming an oxide superconductive thin film from a metal organic compound by an application thermal decomposition process on an oriented metal substrate having an intermediate layer formed on an oriented metal base material. The manufacturing method of an oxide superconductive thin film wire rod comprises a YBCO superconductive thin film formation step of forming a YBCO superconductive thin film on the intermediate layer of the oriented metal substrate and a HoBCO superconductive thin film formation step of forming a HoBCO superconductive thin film on top of the YBCO superconductive thin film. The oxide superconductive thin film wire rod has the YBCO superconductive thin film in film thickness of 0.3 μm or less formed on the oriented metal substrate having the intermediate layer formed on the oriented metal base material and further the HoBCO superconductive thin film formed on top of the YBCO superconductive thin film.
    • 要解决的问题:提供一种氧化物超导薄膜线材,其由于形成更大厚度的氧化物超导薄膜,具有显示足够高的Jc和Ic的超导特性。 解决方案:氧化物超导薄膜线材的制造方法包括通过在具有在取向金属基材上形成的中间层的取向金属基材上的应用热分解方法从金属有机化合物形成氧化物超导薄膜 。 氧化物超导薄膜线材的制造方法包括在定向金属基板的中间层上形成YBCO超导薄膜的YBCO超导薄膜形成步骤和形成HoBCO超导薄膜的HoBCO超导薄膜形成步骤 在YBCO超导薄膜的顶部。 氧化物超导薄膜线材具有在具有形成在取向金属基材上的中间层的取向金属基板上形成的膜厚度为0.3μm以下的YBCO超导薄膜,并且还形成在该顶面上的HoBCO超导薄膜 YBCO超导薄膜。 版权所有(C)2012,JPO&INPIT