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1. 发明专利

JP2011052276A Method for surface-treating carbon-based film 有权
标题翻译：表面处理碳膜的方法
公开(公告)号：JP2011052276A
公开(公告)日：2011-03-17
申请号：JP2009202235
申请日：2009-09-02
申请人： National Institute Of Advanced Industrial Science & Technology , 独立行政法人産業技術総合研究所
发明人： NAKAMURA TAKAKO , OHANA TSUGUYORI
IPC分类号： C23C16/56 , C09K3/18
摘要： PROBLEM TO BE SOLVED: To provide a method for safely, simply and easily introducing a fluorine-containing functional group onto a surface of a carbon-based film without using a solution and a toxic gas, and without conducting a complicated operation.
SOLUTION: This surface-treating method includes irradiating the carbon-based film with ultraviolet light in the presence of a gas of a perfluoroazoalkane expressed by formula (1): R
F N=NR
F , wherein R
F represents a perfluoroalkyl group, and chemically bonding the perfluoroalkyl group to the surface of the carbon-based film. Thereby, the carbon-based film can further possess a function of specific properties peculiar to a fluorine atom and a fluorine-atom-containing functional group.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种在不使用溶液和有毒气体的情况下安全，简单且容易地将含氟官能团引入到碳基膜的表面上的方法，并且不进行复杂的操作。解决方案：该表面处理方法包括在由式（1）表示的全氟偶氮烷的气体存在下用紫外光照射碳基膜：R SB = N SB > F ，其中R SB表示全氟烷基，并将全氟烷基化学键合到碳系膜的表面。因此，碳基膜还可以具有氟原子和含氟原子的官能团特有的特定性质的功能。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2012046378A Surface oxidation method of carbon material 有权
标题翻译：碳材料的表面氧化方法
公开(公告)号：JP2012046378A
公开(公告)日：2012-03-08
申请号：JP2010190258
申请日：2010-08-27
申请人： National Institute Of Advanced Industrial Science & Technology , 独立行政法人産業技術総合研究所
发明人： NAKAMURA TAKAKO , OHANA TSUGUYORI
IPC分类号： C01B31/02
摘要： PROBLEM TO BE SOLVED: To provide a method of introducing an oxygen-containing functional group on a carbon material surface safely and easily without using poisonous chemicals, and a large vacuum device for such as plasma treatment, and without heating treatment and complicated operation, and to provide a method of acquiring a carbon material which is acquired from the obtained oxygen functionalized carbon material and is chemically modified only by a hydroxy group.SOLUTION: In the presence of hydrogen peroxide solution, ultraviolet light having preferably a wavelength 170-300 nm is irradiated on the carbon material. Thereby, the oxygen-containing functional group is chemically bonded on the surface of the carbon material. By having a hydrogenating agent act on the obtained oxygen-containing functionalized carbon material, the carbon material of which a surface is chemically modified by the hydroxy group can be obtained.
摘要翻译：要解决的问题：提供一种在不使用有毒化学物质的情况下安全容易地在碳材料表面上引入含氧官能团的方法，以及用于诸如等离子体处理的大型真空装置，并且不加热处理和复杂操作，并提供从获得的氧官能化碳材料中获得的碳材料的方法，并且仅由羟基进行化学改性。解决方案：在过氧化氢溶液的存在下，将优选为波长170-300nm的紫外线照射在碳材料上。由此，含氧官能团化学键合在碳材料的表面上。通过使氢化剂作用于所得到的含氧官能化碳材料，可以获得表面经羟基化学改性的碳材料。版权所有（C）2012，JPO＆INPIT

3. 发明专利

JP2010232453A Superconducting current limiting element having enhanced environmental resistance 有权
标题翻译：超导电流限制元件具有增强的环境电阻
公开(公告)号：JP2010232453A
公开(公告)日：2010-10-14
申请号：JP2009078910
申请日：2009-03-27
申请人： National Institute Of Advanced Industrial Science & Technology , 独立行政法人産業技術総合研究所
发明人： MATSUI HIROAKI , KONDO WAKICHI , YAMAZAKI HIROFUMI , OHANA TSUGUYORI , KUMAGAI TOSHIYA
IPC分类号： H01L39/16 , H01L39/24 , H02H9/02
CPC分类号： Y02E40/69
摘要： PROBLEM TO BE SOLVED: To provide an environmentally-resistant protective film having superior characteristics, and a superconducting current limiting element with characteristics that are hard to deteriorate in immersion into and removal from liquid nitrogen, and in resulting attachment of water, and in an acceleration test at a high temperature and a high humidity.
SOLUTION: The superconducting current limiting element comprises: a monocrystalline substrate that may have an intermediate layer; a superconducting film; a shunt layer to be used at the transition to normal conduction; and a protective film. A film including a natural resin or a carbon material is employed as the protective film. As the natural resin, an animal resin such as shellac resin is preferable. The superconducting current limiting element has a long life and exhibits characteristics excellent in low temperature resistance and thermal shock resistance.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异特性的耐环境保护膜和具有在浸入和除去液氮时难以劣化的特性的极限流体元件，以及由此产生的水的附着，以及在高温高湿的加速试验中。超导电流限制元件包括：可以具有中间层的单晶衬底; 超导膜; 在正常传导过渡中使用的并联层; 和保护膜。使用包含天然树脂或碳材料的薄膜作为保护膜。作为天然树脂，优选虫胶树脂等动物树脂。超导限流元件寿命长，具有耐低温性和耐热冲击性优异的特性。版权所有（C）2011，JPO＆INPIT

4. 发明专利

JP2014065784A Surface treatment method of polymer material 有权
标题翻译：聚合物材料的表面处理方法
公开(公告)号：JP2014065784A
公开(公告)日：2014-04-17
申请号：JP2012210853
申请日：2012-09-25
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： NAKAMURA TAKAKO , OHANA TSUGUYORI
IPC分类号： C08J7/18
摘要： PROBLEM TO BE SOLVED: To provide a method of safely and simply introducing a fluorine functional group onto a surface of a polymer material without using a noxious gas such as fluorine used in conventional modification methods of a polymer surface, using a large-size apparatus for a plasma treatment, and applying a complicated operations for synthesizing a fluorine functional group-containing precursor.SOLUTION: A surface of a polymer material is modified by introducing a fluorine functional group by chemically binding a perfluoroalkyl group to the polymer surface by irradiating ultraviolet light to the polymer surface in the presence of perfluoroazoalkane represented by the general formula (1). RN=NR(1), where Rrepresents a perfluoroalkyl group.
摘要翻译：要解决的问题：提供一种安全简单地将氟官能团引入到聚合物材料的表面上而不使用聚合物表面的常规改性方法中使用的有害气体如氟的方法，使用大型设备等离子体处理，以及用于合成含氟官能团的前体的复杂操作。解决方案：通过将全氟烷基化学结合到聚合物表面上，通过将紫外光照射到在由通式（1）表示的全氟偶氮烷存在下的聚合物表面。 RN = NR（1），其中R表示全氟烷基。

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