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1. 发明专利

JP2010149038A Method of recovering nitrogen oxides in atmospheric air by utilizing sustainable photocatalytic reaction 审中-公开
标题翻译：通过利用可持续的光催化反应在大气中回收氮氧化物的方法
公开(公告)号：JP2010149038A
公开(公告)日：2010-07-08
申请号：JP2008329408
申请日：2008-12-25
申请人： National Institute Of Advanced Industrial Science & Technology , 独立行政法人産業技術総合研究所
发明人： OKO YOSHIHISA , NAKAMURA YURI , MATSUZAWA SADAO , NEGISHI NOBUAKI , TAKEUCHI HIROSHI
IPC分类号： B01D53/86 , A61L9/00 , A61L9/18 , B01D53/94 , B01J35/02
摘要： PROBLEM TO BE SOLVED: To provide a method capable of obtaining nitrogen oxides removal effect excellent in long-term stability without applying periodical water flush or the like, and to provide an apparatus therefor. SOLUTION: The method is for removing the nitrogen oxides in the air by using a photocatalyst, the air containing the nitrogen oxides is sent into a reactor housing the photocatalyst, the air is made to pass through the water provided on the exit of the reactor together with a product due to an NO 3 radical generated by light irradiation, and thus the product separated in the air is absorbed in water and removed. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种能够获得长期稳定性优异的氮氧化物去除效果的方法，而不需要定期进行水冲洗等，并提供其设备。解决方案：该方法是通过使用光催化剂除去空气中的氮氧化物，将含有氮氧化物的空气送入容纳光催化剂的反应器中，使空气通过设在其上的水该反应器由于通过光照射而产生的NO 3 SB 3自由基产物，因此在空气中分离的产物被吸收并除去。版权所有（C）2010，JPO＆INPIT

2. 发明专利

JP2010188217A Composition for manufacture of photocatalyst material 审中-公开
标题翻译：光催化材料的制备用组合物
公开(公告)号：JP2010188217A
公开(公告)日：2010-09-02
申请号：JP2009032020
申请日：2009-02-13
申请人： National Institute Of Advanced Industrial Science & Technology , National Science & Technology Development Agency , ナショナルサイエンスアンドテクノロジーディベロップメントエイジェンシーNational Science and Technology Development Agency , 独立行政法人産業技術総合研究所
发明人： MATSUZAWA SADAO , NEGISHI NOBUAKI , CHAMORN CHAWENGKIJWANICH , DUANGKAMON VIBOONRATANASRI
IPC分类号： B01J31/38 , B01J35/02 , C09D5/16 , C09D133/02 , C09D133/06
摘要： PROBLEM TO BE SOLVED: To provide a composition for the manufacture of a photocatalyst material which can achieve high catalytic activity. SOLUTION: This composition for the manufacture of a photocatalyst material is applied to the surface of a base material containing a photocatalyst, a binder component and a solvent, then is dried and irradiated with ultraviolet rays. The binder component is a (meth)acrylic acid/(meth)acrylic ester-based copolymer with a structure represented by the formula (wherein, X is a hydrogen atom (H) or a methyl group (CH 3 ), R is hydrogen or an alkyl group with the number of carbon atoms of 1 to 10, and the H of a carboxyl group is non-substituted or is substituted with a primary to a quaternary amine or sodium (Na)). COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供可以实现高催化活性的光催化剂材料的制造用组合物。解决方案：将用于制备光催化剂材料的组合物施加到含有光催化剂，粘合剂组分和溶剂的基材的表面上，然后干燥并用紫外线照射。粘合剂成分是具有下式结构的（甲基）丙烯酸/（甲基）丙烯酸酯系共聚物（其中，X为氢原子（H）或甲基（CH 3 ），R为氢或碳原子数为1〜10的烷基，羧基的H为未取代或被伯至季胺或钠（Na）取代）。版权所有（C）2010，JPO＆INPIT

3. 发明专利

JP2008184357A Method of making surface of oxide amphiphilic 审中-公开
标题翻译：制备氧化物表面的方法
公开(公告)号：JP2008184357A
公开(公告)日：2008-08-14
申请号：JP2007018845
申请日：2007-01-30
申请人： Japan Atomic Energy Agency , National Institute Of Advanced Industrial & Technology , 独立行政法人日本原子力研究開発機構 , 独立行政法人産業技術総合研究所
发明人： OKO YOSHIHISA , FUKUDA SHURI , MATSUZAWA SADAO , TAMURA KAZUHISA , MIZUKI JUNICHIRO
IPC分类号： C01B13/14 , B01J35/02 , B01J37/34
摘要： PROBLEM TO BE SOLVED: To provide a method of making the surface of an oxide amphiphilic, which can efficiently make the surface of the oxide amphiphilic with a smaller amount of light in a shorter period and can be applied to an oxide other than titanium oxide. SOLUTION: The method of making the surface of an oxide amphiphilic comprises irradiating the solid surface of an oxide (especially, titanium oxide and strontium titanate) with radiation (for example, X ray) to make the surface of the oxide amphiphilic (hydrophiling). The process of making amphiphilic can be done with a smaller number of photons in a shorter period, and radioactive waste can be used as a light source. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种使两亲氧化物的表面形成的方法，其可以在更短的时间内有效地使少许的光的氧化物两亲性的表面有效地形成，并且可以应用于除了氧化钛。解决方案：制造两亲氧化物的表面的方法包括用辐射（例如，X射线）照射氧化物（特别是氧化钛和钛酸锶）的固体表面以制备氧化物两亲性的表面 hydrophiling）。可以在更短的时间内用较少数量的光子进行制造两亲性的过程，并且放射性废物可以用作光源。版权所有（C）2008，JPO＆INPIT

4. 发明专利

JP2008253164A Method for evaluating antimicrobial performance of photocatalytic material for general environmental microorganism 有权
标题翻译：一般环境微生物评估光催化材料抗微生物性能的方法
公开(公告)号：JP2008253164A
公开(公告)日：2008-10-23
申请号：JP2007096657
申请日：2007-04-02
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： OKO YOSHIHISA , HANADA SATOSHI , TAKEUCHI MIO , FUKUDA SHURI , SUGINO HISAKO , SAKAI EMIKO , MATSUZAWA SADAO
IPC分类号： C12Q1/18 , B01J35/02 , G01N21/78
摘要： PROBLEM TO BE SOLVED: To provide a method for simply, rapidly and quantitatively evaluating antimicrobial performance.
SOLUTION: The method for evaluating antimicrobial performance comprises using a liquid containing bacterium, such as, Synechocystis sp. PCC 6803, having pigment synthetic ability and a liquid containing further an antimicrobial material, such as, a photocatalyst in the liquid, and using changes in pigment, in both the liquids as an index for evaluating antimicrobial performance.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供简单，快速和定量评价抗菌性能的方法。解决方案：用于评价抗菌性能的方法包括使用含液体的细菌，例如集胞藻（Synechocystis sp。具有颜料合成能力的PCC 6803和另外含有抗微生物材料的液体，例如液体中的光催化剂，并且在两种液体中使用颜料的变化，作为评价抗菌性能的指标。版权所有（C）2009，JPO＆INPIT

5. 发明专利

JP2008142636A Method of applying photocatalyst on polyolefin based resin molding 审中-公开
标题翻译：在基于聚烯烃的树脂模塑上应用光催化剂的方法
公开(公告)号：JP2008142636A
公开(公告)日：2008-06-26
申请号：JP2006333335
申请日：2006-12-11
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： MATSUZAWA SADAO , SANO TAIZO , SAKAI EMIKO
IPC分类号： B05D1/18 , B01D53/86 , B01J35/02 , B01J37/02 , B05D7/02 , C09D5/00 , C09D131/04 , C09D183/04 , D06M11/46 , D06M15/333 , D06M15/643 , D06M101/20
摘要： PROBLEM TO BE SOLVED: To provide a method of applying a photocatalyst on a polyolefin based resin molding by which the photocatalyst such as titanium dioxide is prevented from being buried in a binder component used for the coating of the polyolefin based resin molding and a photocatalytic material having the photocatalyst densely and strongly bonded on the surface, having high activity and small peeling is manufactured. SOLUTION: The method of applying the photocatalyst is carried out by dipping the polyolefin based resin molding having a surface zeta potential adjusted to have positive (+) or negative potential (-) by the application of a primer material into a mixed solution having a photocatalyst/water weight ratio of 0.0005-0.1 and electrostatically bonding the photocatalyst having positive (+) or negative potential (-) opposed to the surface zeta potential of the molding to the molding and successively removing water. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决问题的方法：提供一种在聚烯烃类树脂成型体上涂布光催化剂的方法，通过该方法，防止诸如二氧化钛的光催化剂被掩埋在用于涂覆聚烯烃基树脂成型体的粘合剂组分中，以及制造具有高活性且剥离小的光催化材料，其光催化剂密实且牢固地结合在表面上。解决方案：通过将具有正（+）或负电位（ - ）的表面ζ电位的聚烯烃基树脂模制品通过施加底漆材料浸渍到混合溶液中来进行涂覆光催化剂的方法光催化剂/水重量比为0.0005-0.1，并将与模制品的表面ζ电位相反的正（+）或负电位（ - ）的光催化剂静电粘合到模塑件上并连续地除去水。版权所有（C）2008，JPO＆INPIT

6. 发明专利

JP2007054802A Photocatalytic reactor tower for cleaning atmosphere 有权
标题翻译：用于清洁大气的光催化反应塔
公开(公告)号：JP2007054802A
公开(公告)日：2007-03-08
申请号：JP2005246557
申请日：2005-08-26
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： NEGISHI NOBUAKI , MATSUZAWA SADAO , TAKEUCHI HIROSHI
IPC分类号： B01D53/86 , B01J19/24 , B01J35/02
CPC分类号： Y02A50/235
摘要： PROBLEM TO BE SOLVED: To provide a simple photocatalytic reactor tower for cleaning atmosphere capable of efficiently removing a volatile organic compound contained in the atmosphere in a low concentration by activating a photocatalyst with the sunlight. SOLUTION: The photocatalytic reactor tower for cleaning atmosphere comprises an outermost cylindrical body provided on its top part with an opening which receives the sun light and on its inner surface with a reflecting mirror which diffuses incident light, and in its center part a double-cylindrical body comprising an inside cylindrical body and an outside cylindrical body, the top end of the inside cylindrical body being opened and a photocatalyst layer irradiated with the reflected and diffused light being provided on the surface of the inside cylindrical body, the outside cylindrical body being disposed so as to contain the inside cylindrical body and the top end of the outside cylindrical body being closed, wherein the contaminated atmosphere containing the volatile organic compound flows in from the under part of the inside cylindrical body and the atmosphere cleaned by a photocatalytic reaction flows out from the under part of the outside cylindrical body. The opening of the uppermost part of the outermost cylindrical body has preferably a slanted structure. It is useful for cleaning an atmosphere in a room where the sunlight does not reach, especially for an exhaust gas from an automobile or that from a factory treating the volatile organic compound. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于清洁气氛的简单的光催化反应塔，其能够通过用阳光活化光催化剂来有效地除去低浓度的大气中含有的挥发性有机化合物。解决方案：用于清洁气氛的光催化反应塔包括最外圆柱体，其在其顶部设置有开口，其接收太阳光，并在其内表面上设置有扩散入射光的反射镜，并且在其中心部分a 双筒体包括内圆柱体和外圆柱体，内圆柱体的顶端被打开，并且在内筒体的表面上设置有被反射和漫射的光照射的光催化剂层，外圆柱体本体被设置为容纳内部圆柱体并且外部圆筒体的顶端被封闭，其中含有挥发性有机化合物的污染气氛从内部圆柱体的下部流入，并且由光催化剂清洁的气氛反应从外圆柱体的下部流出。最外面的圆柱体的最上部的开口优选为倾斜结构。特别是对于来自汽车的废气或来自处理挥发性有机化合物的工厂的废气，清洁阳光不能达到的室内的气氛是有用的。版权所有（C）2007，JPO＆INPIT

7. 发明专利

JP2004141739A Nitrogen-containing titanium oxide-based photocatalyst and method for decontaminating environmentally-polluted gas by using the same 有权
标题翻译：含氮氧化物的光催化剂及其使用环境污染气体去除环境的方法
公开(公告)号：JP2004141739A
公开(公告)日：2004-05-20
申请号：JP2002307990
申请日：2002-10-23
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： SANO TAIZO , NEGISHI NOBUAKI , TAKEUCHI HIROSHI , MATSUZAWA SADAO
IPC分类号： B01D53/86 , B01J21/06 , B01J27/24 , B01J35/00 , B01J35/02 , B01J37/08
CPC分类号： B01D53/8628 , B01D53/8678 , B01D2255/802 , B01J21/063 , B01J27/24 , B01J35/004 , B01J37/082
摘要： PROBLEM TO BE SOLVED: To provide a nitrogen-containing titanium oxide-based photocatalyst exhibiting high photocatalytic activity in light having a wide wavelength, particularly, in visible light and to provide a method for decontaminating the environmentally-polluted gas by using this photocatalyst. SOLUTION: This photocatalyst consists of a crystal of nitrogen-containing titanium oxide obtained by firing a titanium complex prepared by coordinating a nitrogen-containing organic compound with metal titanium and exhibits catalytic activity in the light containing the visible light. In the method for decontaminating the environmentally-polluted gas, the environmentally-polluted gas containing nitrogen oxides or organic substances is brought into contact with this photocatalyst while this photocatalyst is irradiated with the light containing the visible light so that the organic substances and nitrogen oxides are decomposed and removed by the chemical reaction. COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供一种在具有宽波长，特别是可见光的光的光中具有高光催化活性的含氮二氧化钛类光催化剂，并提供一种通过使用这种方法对环境污染的气体进行净化光催化剂。解决方案：该光催化剂由通过将含氮有机化合物与金属钛配位而制备的钛络合物烧成而得到的含氮氧化钛的结晶，并且在含有可见光的光中显示出催化活性。在对环境污染气体进行净化的方法中，使含有氮氧化物或有机物质的环境污染气体与该光催化剂接触，同时用含有可见光的光照射该光催化剂，使得有机物和氮氧化物为通过化学反应分解和去除。版权所有（C）2004，JPO

8. 发明专利

JP2008076262A Automatic performance evaluation device of atmosphere purifying photocatalytic material 有权
标题翻译：大气净化光电材料的自动性能评估装置
公开(公告)号：JP2008076262A
公开(公告)日：2008-04-03
申请号：JP2006256646
申请日：2006-09-22
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： SANO TAIZO , OKO YOSHIHISA , KOIKE KAZUHIDE , SAKAI EMIKO , MATSUZAWA SADAO , TAKEUCHI HIROSHI
IPC分类号： G01N31/10 , B01J35/02 , B01J37/00
摘要： PROBLEM TO BE SOLVED: To provide an automatic performance evaluation device of an atmosphere purifying photocatalyst capable of accurately and stably sampling a low flow speed low concentration gas being a target substance and capable of accurately calculating the performance of a photocatalyst as a result.
SOLUTION: The automatic performance evaluation device of the atmosphere purifying photocatalytic material has a means for supplying a low concentration harmful standard gas by constant amount, a mass for supplying air containing humidity or air containing no humidity by constant amount, a supply means of the low concentration harmful standard gas containing air, which contains a constant amount of humidity, connected through a gas mixing container from those means and a means for measuring the content of the low concentration harmful standard gas the low concentration harmful standard gas containing air which contains humidity and measuring the content of the low concentration harmful standard gas contained in the unreacted low concentration harmful standard gas obtained from a reactor and evaluate the capacity of the atmosphere purifying photocatalytic material from the measuring results of both of them.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：为了提供能够精确稳定地取样作为目标物质的低流速低浓度气体并能够精确计算光催化剂性能的气氛纯化光催化剂的自动性能评价装置，结果。气溶胶净化光催化材料的自动性能评价装置具有用于以恒定量供给低浓度有害标准气体的装置，用于供给含湿度的空气的质量或恒定量的不含湿度的空气的装置，供给装置含有通过气体混合容器从这些装置连接的含有恒定量的湿气的低浓度有害标准气体的含有低浓度有害标准气体的含有空气的低浓度有害标准气体的装置，含有湿度并测量从反应器获得的未反应的低浓度有害标准气体中所含的低浓度有害标准气体的含量，并根据它们的测量结果评估大气净化光催化材料的容量。版权所有（C）2008，JPO＆INPIT

9. 发明专利

JP2003081905A Method for producing aromatic aldehyde 有权
标题翻译：生产芳香醛的方法
公开(公告)号：JP2003081905A
公开(公告)日：2003-03-19
申请号：JP2001271239
申请日：2001-09-07
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： MATSUZAWA SADAO , IBUSUKI AKITSUGU
IPC分类号： C07C45/36 , C07B61/00 , C07C47/546
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an aromatic aldehyde at a low cost in high yield by selectively oxidizing an aromatic hydrocarbon having the aliphatic hydrocarbon substituent as a raw material. SOLUTION: This method for producing the aromatic aldehyde is as follows. The aromatic hydrocarbon having at least the one aliphatic hydrocarbon substituent is dissolved in a low-polar hydrocarbon solvent and exposed to light in the presence of a photocatalyst. Thereby, the substituent is converted into an aldehyde (CHO) group.
摘要翻译：要解决的问题：通过选择性氧化具有脂肪族烃取代基的芳族烃作为原料，提供以低成本生产芳族醛的方法。解决方案：该芳族醛的制造方法如下。具有至少一个脂族烃取代基的芳族烃溶解在低极性烃溶剂中，并在光催化剂存在下曝光。由此，将取代基转化为醛（CHO）基团。

10. 发明专利

JP2003049173A Oil reforming 有权
标题翻译：油改造
公开(公告)号：JP2003049173A
公开(公告)日：2003-02-21
申请号：JP2001239737
申请日：2001-08-07
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： MATSUZAWA SADAO , IBUSUKI AKITSUGU
IPC分类号： B01J21/06 , B01J35/02 , C10G27/00 , C10G29/16 , C10G32/00
摘要： PROBLEM TO BE SOLVED: To provide a method of efficiently reforming oil in a low cost by selectively oxidizing heterocyclic compounds bearing condensed rings that exists in the oil through photoctalytic reactions, particularly dibenzothiophene that is very difficult to be desulfurized and removing the formed oxides, and to provide an efficient and low cost hydrosulfurization process using the reforming process.
SOLUTION: As a pretreatment process for the hydrodesulfurization process for oil, the oil including heterocyclic compounds bearing condensed rings is irradiated with light in the presence of a low polar hydrocarbon solvent and a photocatalyst and the oxidized products of the heterocyclic compounds are dissolved in the solvent and removed whereby the oil is reformed.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：提供一种通过选择性地氧化通过光催化反应存在于油中的含有稠环的杂环化合物，特别是非常难以脱硫和除去形成的氧化物的二苯并噻吩，从而低成本地有效地重整油的方法，以及以提供使用重整过程的有效且低成本的加氢硫化方法。解决方案：作为油的加氢脱硫工艺的预处理方法，在低极性烃溶剂和光催化剂存在下，用光照射含有稠环的杂环化合物的油，将杂环化合物的氧化物溶解在溶剂中并除去，由此油被重整。

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