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    • 5. 发明专利
    • Production method of filler-dispersed melt-kneaded product, molded resin product obtained by production method of melt-kneaded product, and production method or use thereof
    • 填充金属切割制品的生产方法,熔融生产方法生产的模制树脂产品及其生产方法或其使用
    • JP2009029114A
    • 2009-02-12
    • JP2008120781
    • 2008-05-02
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • SHIMIZU HIROSHIRI YUSHINZHAO LI
    • B29B7/38B01D71/00B29B7/90C08J3/20C08K3/00C08L67/00C08L101/00
    • B29C47/6018B29C47/92
    • PROBLEM TO BE SOLVED: To provide a melt-kneaded product of an incompatible polymer blend with a controlled co-continuous structural composition from an incompatible polymer blend, to provide a molded resin product of an incompatible polymer blend with a controlled co-continuous structural composition from the melt-kneaded product, and to provide a material obtained by subjecting the molded resin product to solvent treatment. SOLUTION: The melt-kneaded product is obtained in such a manner that a melt-kneaded resin or elastomer obtained by treating a filler, an incompatible resin or the like in specified ratios under the conditions where the speed of rotation of a screw is 600 rpm to 3,000 rpm and its shear rate is 900 to 4,500 sec -1 is sent from a rear end of the screw to its front end, then the melt-kneaded resin or elastomer is subjected to circulation where the melt-kneaded resin or elastomer is trapped in a space at the front screw, and then moved to the rear screw end, the co-continuous structure as the internal structure of the melt-kneaded product is controlled, and the size of the continuous phase is freely changed at mesoscopic level (0.3 to 100 μm). The molded resin product, and the material obtained by subjecting the molded resin product to solvent treatment are also provided. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供不相容的聚合物共混物的熔融捏合产物和来自不相容的聚合物共混物的受控共连续结构组合物,以提供不相容的聚合物共混物与受控共混物的模制树脂产物, 来自熔融捏合产物的连续结构组成,并提供通过使模塑树脂产物进行溶剂处理而获得的材料。 解决方案:熔融捏合产物是这样获得的,即在螺杆的旋转速度的条件下以特定比例处理填料,不相容树脂等获得的熔融捏合树脂或弹性体 600rpm至3,000rpm,剪切速度为900〜4,500sec。从螺杆的后端向其前端发送 -1 ,然后对熔融捏合的树脂或弹性体进行循环 其中熔融捏合的树脂或弹性体被捕获在前螺杆的空间中,然后移动到后螺杆端,作为熔融捏合产物的内部结构的共连续结构被控制, 连续相在介观水平(0.3〜100μm)内自由变化。 还提供了模塑树脂产品和通过使模制树脂产物进行溶剂处理获得的材料。 版权所有(C)2009,JPO&INPIT
    • 7. 发明专利
    • Melt kneading method, molding processing method, and resin molded product of polycarbonate and polymethyl methacrylate
    • 熔融加工方法,成型加工方法和聚碳酸酯和甲基丙烯酸甲酯的树脂成型产品
    • JP2009196196A
    • 2009-09-03
    • JP2008039774
    • 2008-02-21
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • SHIMIZU HIROSHIRI YUSHIN
    • B29B7/38B29K33/04B29K69/00C08J3/20C08L69/00
    • B29C47/8895
    • PROBLEM TO BE SOLVED: To provide an extruded product (including a film-like or a sheet-like product) of a nano dispersed polymer blend having a microscopic dispersed structure and a method for manufacturing the same, in melt kneading of incompatible polycarbonate (PC)/polymethyl methacrylate (PMMA), wherein when one polymer component PC is made into a matrix, size of a dispersed phase of the other polymer component PMMA is controlled to be several hundred nm or less. SOLUTION: The extruded product of the nano dispersed polymer blend having the microscopic dispersed structure in which when one polymer component PC is made into a matrix, size of dispersed phase of the other polymer component PMMA is controlled to be several hundred nm or less, can be manufactured by melt kneading of the incompatible polymer blend using a micro scale high shear molding processing machine in which a screw is rotatable in ≥1000 rpm, without adding any excessive additive, such as a compatibilizer. Specifically, it is necessary to boost a shear flow field applied to a blend sample in the micro scale shear molding processing machine in order to form a microstructure of a nanometer level. A method to further rev up number of revolutions of the screw, to lengthen kneading time under a fixed number of revolutions, or the like, is effective. First creation of an optically transparent material can be achieved by preparing such high shear molding processing conditions to form a structure in which the size of the dispersed phase is controlled to be several hundred nm or less. COPYRIGHT: (C)2009,JPO&INPIT
    • 待解决的问题:为了提供具有微观分散结构的纳米分散聚合物共混物的挤出产品(包括膜状或片状产品)及其制造方法,在不相容的熔融捏合 聚碳酸酯(PC)/聚甲基丙烯酸甲酯(PMMA),其中当将一种聚合物组分PC制成基质时,将另一种聚合物组分PMMA的分散相的尺寸控制在几百纳米或更小。 解决方案:具有微观分散结构的纳米分散聚合物共混物的挤出产物,其中当将一种聚合物组分PC制成基质时,另一种聚合物组分PMMA的分散相的尺寸被控制为几百nm或 可以使用微型高剪切成型加工机熔融捏合不相容的聚合物共混物来制造,其中螺杆可以以大于1000rpm的速度旋转,而不添加任何过量的添加剂如增容剂。 具体地说,为了形成纳米级的微观结构,需要增加施加到微型剪切模塑加工机中的共混物样品的剪切流场。 进一步提高螺杆转速,固定转数等的搅拌时间的方法是有效的。 可以通过制备这种高剪切模制加工条件来形成光学透明材料的首次创建,以形成其中分散相的尺寸被控制在几百纳米或更小的结构。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Molten kneaded material, resin molding and manufacturing method of the same
    • MOLTEN KNEADED MATERIAL,RESIN MOLDING AND MANUFACTURING METHOD OF THE SAME
    • JP2008266577A
    • 2008-11-06
    • JP2008025964
    • 2008-02-06
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • SHIMIZU HIROSHIRI YUSHIN
    • C08J3/20C08J5/00
    • C08J3/201C08J3/005C08J2321/00C08J2327/16Y10S977/742Y10S977/773Y10T428/25
    • PROBLEM TO BE SOLVED: To provide a novel melt-blending method for homogeneously dispersing a nano-level sized filler in an elastomer or a resin, a melt-blended material prepared by the melt-blending method and a molded material formed by molding the novel melt-blended material. SOLUTION: A filling material composed of a filler and an elastomer or a resin are charged into a charging hole set at the end part of a melt blending part with a heating portion on a cylinder providing with a screw, the elastomer or the resin melt-blended prepared by treating the material under the conditions, where a rotational frequency of the screw is from 600 rpm to 3,000 rpm and a shear rate from 900 to 4,500 sec -1 , and is sent from the end of the screw to the top thereof and is blocked into a gap at the top of the screw and then recycled from the gap to the rear end through the hole of the screw. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种将纳米级填料均匀分散在弹性体或树脂中的新的熔融共混方法,通过熔融共混法制备的熔融共混材料和由 成型新型熔融混合材料。 解决方案:将由填料和弹性体或树脂组成的填充材料装入设置在熔融共混部分的端部的充填孔中,该填充孔与提供螺杆的圆筒上的加热部分,弹性体或 在螺杆的转速为600rpm至3,000rpm,剪切速率为900至4,500sec -1的条件下处理材料制备的树脂熔融共混,并从 螺钉的端部到其顶部并被阻塞在螺钉顶部的间隙中,然后通过螺钉的孔从间隙再循环到后端。 版权所有(C)2009,JPO&INPIT