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    • 3. 发明专利
    • PRODUCTION OF DENTAL PORCELAIN FOR PREVENTING YELLOWING
    • JPH0381212A
    • 1991-04-05
    • JP21601589
    • 1989-08-24
    • NORITAKE CO LTD
    • KAMIYA TADAOINOUE MOTOYUKIINADA HIROSHI
    • A61K6/027A61K6/06C04B35/00C04B37/02
    • PURPOSE:To obtain a dental porcelain having a prescribed color tone without exhibiting yellowing phenomenon by adding prescribed amounts of antimony trioxide and nitric acid or a salt thereof to a porcelain raw material, heat- treating the resultant mixture at the softening temperature or above, pulverizing the prepared melt and washing the produced powder with water. CONSTITUTION:Antimony trioxide in an amount of 0.1-2.0wt.% based on a porcelain raw material and nitric acid or as a salt thereof in an amount of 0.01-5wt.% based on the porcelain raw material are added thereto and the resultant blended powder is then heat-treated at the softening temperature thereof or above. The prepared melt is subsequently pulverized and washed with water to afford a dental porcelain. In the pulverizing step of the melt, 0.01-5wt.% nitric acid or salt thereof is preferably readded. A porcelain layer having a prescribed tone without exhibiting yellowing phenomenon even in baking and calcining thereof especially on a metal surface containing silver can be formed by using the aforementioned porcelain. Yellowing can be more surely prevented by readding the nitric acid or salt thereof without causing clouding.
    • 7. 发明专利
    • Preparation of porous grindstone and immersion liquid thereof
    • 多孔磨石及其浸出液的制备
    • JPS59142069A
    • 1984-08-15
    • JP1151583
    • 1983-01-28
    • Noritake Co Ltd
    • INADA HIROSHIKOBAYASHI MICHIO
    • B24D3/28B24D3/30B24D3/32
    • B24D3/32
    • PURPOSE:To improve the water resistance, grinding performance, and lapping performance of the captioned grindstone by using the combination of PVA, aldehyde, and acid, as the phenol-resin containing immersion liquid for a porous grindstone which is fixedly molded, thus improving the affinity with a PVA bond grindstone. CONSTITUTION:A proper kind of PVA is used for grindstone bonding agent, and 5-95parts PVA by weight is used for 100parts phenol-resin by weight. Aldehyde group is necessary in 20-80pts.wt. with respect to 100parts. PVA by weitht. Acidic catalyst is hydrochloric acid, sulfuric acid, etc., and 5-10pts.wt. is required for 100parts PVA by weight. The grindstone is immersed into said immersion liquid and then dried, and heat-treated at 40-130 deg.C for formal reaction and phenol-resin condensation, and further heat-treated at 130-200 deg.C for several hours for hardening. Thus, the grindstone which is uniform and free from irregularity can be prepared without forming crack during heating. Moreover, a grindstone having the superior water resistance, strength, grinding performance, abrasion proofness, and the good lapping performance can be obtained.
    • 目的:通过使用PVA,醛和酸的组合提高标题磨石的耐水性,研磨性能和研磨性能,作为固体成型用的多孔磨石的含酚树脂浸渍液,从而改善了 与PVA粘结磨石的亲和力。 构成:用于研磨粘合剂的适当种类的PVA,以重量计为100份的酚醛树脂使用5-95重量份的PVA。 醛类是20-80pts.wt。 相对于100件。 PVA由weitht。 酸性催化剂为盐酸,硫酸等,5-10pts.wt。 是100重量份的PVA。 将磨石浸入所述浸渍液中,然后干燥,并在40-130℃下进行热处理,进行正式反应和酚醛树脂缩合,并进一步在130-200℃热处理几小时进行硬化。 因此,可以在加热期间制备均匀且无凹凸的磨石,而不会形成裂纹。 此外,可以获得具有优异的耐水性,强度,研磨性能,耐磨性和良好研磨性能的磨石。