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1. 发明专利

JPS5284005A COMPOSITION OF HARDENABLE COATING 失效
公开(公告)号：JPS5284005A
公开(公告)日：1977-07-13
申请号：JP32976
申请日：1976-01-01
申请人： NIPPON OIL CO LTD , TOYO INK MFG CO
发明人： TSUCHIYA SHIYOUZOU , HAYASHI HIDEO , IIDA KAZUYOSHI , GOTOU KIYOSHI
IPC分类号： C08F2/00 , C08F2/46 , C08F2/48 , C08F2/54 , C08F8/00 , C08F8/14 , C08F30/00 , C08F30/02 , C08F290/00 , C08F299/00 , C08F299/02 , C08G61/02 , C08G81/02 , C08L45/00 , C09D4/00 , C09D11/00 , C09D11/10

2. 发明专利

JPS5378298A PREPARATION OF CURABLE RESIN 失效
公开(公告)号：JPS5378298A
公开(公告)日：1978-07-11
申请号：JP15421076
申请日：1976-12-23
申请人： NIPPON OIL CO LTD , TOYO INK MFG CO
发明人： TSUCHIYA SHIYOUZOU , HAYASHI HIDEO , SASAKI MAKOTO , GOTOU KIYOSHI , MATSUBARA TOORU
IPC分类号： C08F2/00 , C08F2/46 , C08F8/00 , C08F8/14 , C08F290/00 , C08F299/00 , C09D11/00 , C09D11/10 , C09D11/101 , C09D11/106 , C09D11/108
摘要： PURPOSE:To prepare the title resin rapidly-curable by irradiation, and having excellent fluidity and emulsifying properties, by reaction of a hydroxy group-contg. unsaturated compound with a specific five-membered ring compound, etc. under a specific condition, followed by reaction with a (meth) acrylic acid.

3. 发明专利

JPS5378290A PREPATATION OF CURABLE RESIN FOR COATING 失效
公开(公告)号：JPS5378290A
公开(公告)日：1978-07-11
申请号：JP15343676
申请日：1976-12-22
申请人： NIPPON OIL CO LTD , TOYO INK MFG CO
发明人： TSUCHIYA SHIYOUZOU , HAYASHI HIDEO , SASAKI MAKOTO , GOTOU KIYOSHI , IIDA KAZUYOSHI
IPC分类号： C08F8/00 , C08F8/04 , C08F8/14 , C08F290/00 , C08F299/00 , C09D11/00 , C09D11/10 , C09D11/101 , C09D11/106 , C09D11/108
摘要： PURPOSE:To prepara a curable resin suitable for production of a light color ink, free from ill odor and having improved color, by esteifying (meth) acrylic acid with a hydroxyl group-containing resin prepared by hydrogenation of a specific resin prepared from a five membered ring compound, etc.

4. 发明专利

JPS599089A Desensitizer 失效
标题翻译：脱敏剂
公开(公告)号：JPS599089A
公开(公告)日：1984-01-18
申请号：JP11842682
申请日：1982-07-09
申请人： Toyo Ink Mfg Co Ltd
发明人： TANAKA TSUNEO , HIKOSAKA MICHIJI , GOTOU KIYOSHI , DAIMATSU TOSHITAKA
IPC分类号： B41M5/128
CPC分类号： B41M5/128
摘要： PURPOSE:To obtain a desensitizer having an excellent desenstitizing effect on no-carbon pressure-sensitive duplicate paper and enabling even printers other than latterpress printers to perform printing by using an alkylene oxide-addition product of a specific resin having hydroxyl groups. CONSTITUTION:A densitizer contians an alkylene oxide-addition product of a resin having hydroxyl groups, obtained by selectively hydrogenating said resin (or its double bond only) obtained from a compound (A) from a 5-membered ring compound having conjugated double bonds or from Diels-Alder reaction of the compound, represented by the formula (where R is a C1-C3 organic residuel group and m+n=6) and a compound (B) having polymerizable double bonds and hydroxyl groups in the same molecule. As the component (A), cyclopentadiene, methyldicyclopentadiene, etc., may be cited, and as the component (B), (meth)allyl alcohol, 2-hydroxyethyl (metha)acrylate, etc., may be cited.
摘要翻译：目的：为了获得对无碳压敏复印纸具有优异的去斑效果的脱敏剂，并且使得除了后期印刷机之外的打印机甚至可以通过使用具有羟基的特定树脂的环氧烷加成产物进行印刷。构成：通过选择性氢化由化合物（A）得到的具有共轭双键的5元环化合物的所述树脂（或其双键）而获得的具有羟基的树脂的氧化烯加成产物，由式（其中R是C1-C3有机残基组，m + n = 6）表示的化合物的Diels-Alder反应和在同一分子中具有可聚合双键和羟基的化合物（B）。作为（A）成分，可以举出环戊二烯，甲基二环戊二烯等，作为（B）成分，可列举出（甲基）烯丙醇，2-羟乙基（甲基）丙烯酸酯等。

5. 发明专利

JPS5385607A SETTING COATING COMPOSITION 失效
公开(公告)号：JPS5385607A
公开(公告)日：1978-07-28
申请号：JP16012376
申请日：1976-12-29
申请人： TOYO INK MFG CO
发明人： GOTOU KIYOSHI
IPC分类号： B41C1/06 , C09D5/00 , C09D11/00 , C09D11/033 , C09D11/037 , C09D11/10 , C09D11/101 , C09D11/106 , C09D11/108 , C09D167/07

6. 发明专利

JPS58149969A ENERGETIC RAY CURING PRINTING INK COMPOSITION 失效
公开(公告)号：JPS58149969A
公开(公告)日：1983-09-06
申请号：JP3178782
申请日：1982-03-02
申请人： TOYO INK MFG CO
发明人： GOTOU KIYOSHI , SATOU KOUJI
IPC分类号： C09D11/00 , C09D11/10 , C09D163/00
摘要： PURPOSE:To provide the titled printing ink compsn. which consists of a specified reaction product, a (meth) acrylic ester monomer and a radical polymerization initiator, is excellent in adhesion to substrate and workability and is suitable for offset printing. CONSTITUTION:The printing ink compsn. is prepared by blending (A) 10-80wt% reaction product obtained by interaction of (a) epoxy compd. containing at least one epoxy group in one molecule and having a molecular weight of 200-4,000 (e.g. glycidyl ether type epoxy resin) and (b) 90-20wt% non-radical-polymerizing monocarboxylic acid (e.g. acetic acid) at 70-300 deg.C, (B) 90-20wt% (meth) acrylic ester monomer of the formula where R1 is H, methyl, propyl or butyl; R2 is H or methyl; X is (alkyl)benzene ring or bisphenol residue; n is 1-10 and (C) 0-30wt% radical-polymerization initiator (e.g. benzoin).

7. 发明专利

JPS58191773A Ink composition curable with active energy ray 失效
标题翻译：墨水组合物可用活性能量固化
公开(公告)号：JPS58191773A
公开(公告)日：1983-11-09
申请号：JP7518582
申请日：1982-05-07
申请人： Toyo Ink Mfg Co Ltd
发明人： GOTOU KIYOSHI , SATOU KOUJI
IPC分类号： C08G59/00 , C08G59/20 , C08G59/40 , C09D11/00 , C09D11/10
摘要： PURPOSE: The titled composition, prepared by incorporating an epoxy compound with a low-molecular weight unsaturated compound obtained by adding an alkylene oxide to phenol, etc., and esterifying the resultant addition product with (meth)acrylic acid and a photosensitizer, and curable in a short time.
CONSTITUTION: A composition obtained by incorporating (A) an epoxy compound having preferably 200W4,000 molecular weight, e.g. bisphenol type epoxy compound, with (B) a low-molecular weight unsaturated compound obtained by adding an alkylene oxide to at least one of (un)substituted phenol, bisphenol and aliphatic polyhydric alcohol, and further esterifying the resultant addition product with (meth)acrylic acid, and (C) if necessary a radical polymerization initiator, e.g. benzoin, preferably at (10W80):(20W90):(0W15) weight ratio of the components (A), (B) and (C).
EFFECT: Improved adhesion and bending property and, suitable for offset printing.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：通过将环氧化合物与通过在苯酚等中添加环氧烷而获得的低分子量不饱和化合物并将所得加成物与（甲基）丙烯酸和光敏剂酯化并将其固化而得到的标题化合物，短时间内。构成：通过将（A）优选具有200-4,000分子量的环氧化合物，例如，双酚型环氧化合物与（B）通过在（取代的）酚，双酚和脂肪族多元醇中的至少一种中加入烯化氧而得到的低分子量不饱和化合物，并进一步使所得加成产物与（甲基）丙烯酸，（C）如果需要自由基聚合引发剂，例如（A），（B）和（C）的（10-80）：（20-90）：（0-15）的重量比。效果：改善粘合力和弯曲性能，适用于胶版印刷。

8. 发明专利

JPS52129790A ULTRAVIOLET*CURING COMPOSITION 失效
公开(公告)号：JPS52129790A
公开(公告)日：1977-10-31
申请号：JP4663476
申请日：1976-04-26
申请人： TOYO INK MFG CO
发明人： KONNO RIYOUZOU , GOTOU KIYOSHI , MATSUBARA TOORU
IPC分类号： C08F2/00 , C08F2/48 , C08F2/50 , C08F299/02 , C08F299/04 , C09D4/00 , C09D11/00 , C09D11/10
摘要： PURPOSE:A ultraviolet-curing composition free from odor caused by the photopolymerization initiator before or after the irradiation of ultraviolet rays, having having improved curing properties, being composed of a monomer and a prepolymer having radically curable ethylenic unsaturated double bonds and a specific photopolymerization initiator.

9. 发明专利

JPS5472237A ULTRAVIOLET CURABLE COATING COMPOSITION 失效
公开(公告)号：JPS5472237A
公开(公告)日：1979-06-09
申请号：JP13895177
申请日：1977-11-21
申请人： TOYO INK MFG CO
发明人： GOTOU KIYOSHI
IPC分类号： C08F2/00 , C08F2/48 , C08F8/14 , C09D4/00 , C09D11/00 , C09D11/033 , C09D11/037 , C09D11/10 , C09D11/101 , C09D11/102 , C09D11/106 , C09D11/108 , C09D145/00
摘要： PURPOSE:An ultraviolet curable coating compositin suitable for printing ink, that is composed of a copolymer from a cyclopentadiene compound and a polymerizable unsaturated compound bearing hydroxyl groups and a benzophenone derivative bearing carboxyl groups. CONSTITUTION:(I) a copolymer from (A) a cyclopentadiene compound of the formula (R is organic residue of 1-3 carbon atoms, n is 0 or integral number of 1- 6) or its Diels-Alder adduct and (B) a compound having a polymerizable double bond and hydroxyl group in the molecule such as allyl alcohol, or its hydrogenated product is esterified with (II) a benzophenone derivative bearing carboxyl groups such as o-benzoylbenzoic acid or a mixture thereof with unsaturated carboxylic acids to form said ultraviolet curable resin composition. The resulting resin composition can start photopolymerization by its own and can eliminate drawbacks caused by the excess addition of photosensitizer. Further it disperse smoothly pigments and can be washed readily with petroleum cleaners.

10. 发明专利

JPS5869269A INK FOR MACHINE PLATE 失效
公开(公告)号：JPS5869269A
公开(公告)日：1983-04-25
申请号：JP16729281
申请日：1981-10-21
申请人： TOYO INK MFG CO
发明人： GOTOU KIYOSHI
IPC分类号： C09D11/00 , C09D11/10
摘要： PURPOSE:To provide the titled ink which is ultraviolet-curable, has excellent curing characteristics, and adhesion to substrates and can form an original plate having good printing durability, by blending a curable resin obtd. by reacting (meth)acrylic acid with a novolak type epoxy resin. CONSTITUTION:20-90wt% curable resin obtd. by reacting (meth)acrylic acid with a novolak type epoxy resin of the formula (wherein R is H, 10C or lower alkyl; n is 0-10), 5-50wt% reactive diluent such as trimethylol-propane triacrylate, 0.1-30pts.wt. photosensitizer such as thioxanthone and 0-40pts.wt. pigment are blended together to form the titled ink.

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