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1. 发明专利

JPH1060459A FUEL OIL ADDITIVE AND FUEL OIL COMPOSITION CONTAINING THE ADDITIVE 失效
公开(公告)号：JPH1060459A
公开(公告)日：1998-03-03
申请号：JP23476396
申请日：1996-08-16
申请人： NIPPON OIL CO LTD
发明人： ISHIDA NOBORU , HAJI KATSUHIKO , NAGAO MASAKI , YOSHII TORU
IPC分类号： C10L1/06 , C10L1/22 , C10L1/224 , C10L1/232
摘要： PROBLEM TO BE SOLVED: To obtain a fuel oil additive comprising a specific nitrogen-containing compound, capable of exhibiting excellent cleaning effects on the induction systems an combustion chambers of gasoline engines without generating sludges therein and useful for gasolines for internal combustion engines. SOLUTION: This fuel oil additive comprises a compound of formula I [R is H, a 1-30C hydrocarbon group; R -R are each H, a 1-10C hydrocarbon group, etc.; R is a 2-6C alkylene; R is a 1-6C alkylene, (a) is 1-100; (b) is 0-100; wherein 1 -OH as an initiator, chloroformylating the obtained compound of formula IV formula IV and subsequently reacting the chloroformylation product with a compound of formula V.

2. 发明专利

JPH07166187A ELECTROVISCOUS FLUID 失效
公开(公告)号：JPH07166187A
公开(公告)日：1995-06-27
申请号：JP34238593
申请日：1993-12-14
申请人： NIPPON OIL CO LTD
发明人： HAJI KATSUHIKO , SASAKI MAKOTO
IPC分类号： C10M169/04 , C10N20/06 , C10N40/04 , C10N40/08
摘要： PURPOSE:To obtain an electroviscous fluid, containing carbonaceous dispersed particles treated with an alcohol and an electrical insulating liquid in a nonaqueous system, having high electroviscous effects without deteriorating performances even in a high- temperature region and useful for an engine mount, etc. CONSTITUTION:This electroviscous fluid is obtained by carrying out the fluid catalytic cracking of a desulfurized oil prepared from a vacuum distillation gas oil of Arabian crude oil at 500 deg.C using a silica-alumina-based catalyst, heat-treating the resultant heavy oil having 320-550 deg.C boiling point at 430 deg.C temperature under 15kg/cm .G pressure for 3hr, then removing a light fraction under reduced pressure, heat-treating the prepared pitch at 400 deg.C temperature for 12hr in nitrogen, finely pulverizing the heat-treated pitch, mixing and stirring the resultant pitch particles in ethanol at ambient temperature for 20min, then filtering the pitch particles, drying the carbonaceous dispersed particles treated with the ethanol, subsequently adding the resultant particles to an electrical insulating liquid such as a silicone oil and dispersing the particles therein in a ball mill for 2hr. The obtained electroviscous fluid has high electroviscous effects in spite of a nonaqueous system without deteriorating performances even in a high-temperature region.

3. 发明专利

JPH06330066A ELECTROVISCOUS FLUID 失效
公开(公告)号：JPH06330066A
公开(公告)日：1994-11-29
申请号：JP14274993
申请日：1993-05-21
申请人： NIPPON OIL CO LTD
发明人： SASAKI MAKOTO , KOBAYASHI YUKIO , HAJI KATSUHIKO
IPC分类号： C10M125/02 , C10N20/06 , C10N40/14 , C10N60/00
摘要： PURPOSE:To provide an electroviscous fluid which comprises dispersed carbonaceous particles treated with an inorganic acid, etc., and an electric insulating fluid and is useful in the engine mount because it has high electroviscous properties with reduced electric current and no shortcircuiting. CONSTITUTION:The electroviscous fluid comprises (A) anisotropic carbonaceous dispersion particles which are treated with an inorganic acid such as nitric acid or an organic acid such as acetic acid and have 0.02 to 10,000mum length, 0.01 to 500mum diameter and 2 to 1,000,000 aspect ratio, preferably in an amount of 1 to 60wt.% and (B) an electric insulating liquid such as mineral oil or an alkylnaphthalene preferably in an amount of 40 to 99wt.%.

4. 发明专利

JPH051105A PRODUCTION OF TRANSPARENT POLYMER BEADS 失效
公开(公告)号：JPH051105A
公开(公告)日：1993-01-08
申请号：JP4301091
申请日：1991-02-15
申请人： NIPPON OIL CO LTD
发明人： SASAKI MAKOTO , HAJI KATSUHIKO , SATO NAOTAKE
IPC分类号： C08F2/00 , C08F2/18 , C08F2/20
摘要： PURPOSE:To obtain a transparent glass beads having relatively large particle diameter (1-20mm), close to true globe and having uniform particle diameter. CONSTITUTION:A radical-polymerizable vinyl monomer and a monomer having at least 2 vinyl groups in one molecule are subjected to suspension polymerization under relatively mild conditions in water wherein, polyacrylic acid sodium salt exists as a dispersing agent.

5. 发明专利

JPH11140468A FUEL OIL ADDITIVE AND FUEL OIL COMPOSITION CONTAINING THE SAME 失效
公开(公告)号：JPH11140468A
公开(公告)日：1999-05-25
申请号：JP32714597
申请日：1997-11-12
申请人： NIPPON OIL CO LTD
发明人： HAJI KATSUHIKO , NAGAO MASAKI , YOSHII TORU , KOMATA TATSUO
IPC分类号： C10L1/22 , C10L1/222 , C10L1/232
摘要： PROBLEM TO BE SOLVED: To obtain a fuel oil additive capable of exhibiting excellent cleaning property to air supply system and the interior of combustion chamber of gasoline engine even under severe conditions such as cooling of an engine machine and useful for automobile fuel oil or the like by using a specific nitrogen- containing compound. SOLUTION: This fuel oil additive uses a compound of formula I R is H or a 1-30C hydrocarbon group; R to R are each H, a 1-10C hydrocarbon group or a group of formula II [R and R are each H, a 1-10C hydrocarbon group or the like; R is a 2-6C alkylene or the like; R is H, a 1-30C hydrocarbon or the like; (f) is 0-50] and at least one is a group of formula II; R is a 2-6C alkylene; R and R are each a 1-6C alkylene; (a) is 1-100; (b) is O-100; (c) is 0 or 1; (d) and (e) are respectively 1-3 and 0-2 and (d)+(e)=3; X is H, a 1-30C hydrocarbon group (A ), a group (A ) or the like of the formula R -OH (R is a 1-6C alkylene), except that X is A when (e) is 1 and except that either one of X is A and the other is A or A when (e) is 2} (e.g. a compound of formula III).

6. 发明专利

JPH1180758A ADDITIVE FOR FUEL OIL, AND FUEL OIL COMPOSITION CONTAINING THE SAME 失效
公开(公告)号：JPH1180758A
公开(公告)日：1999-03-26
申请号：JP26771497
申请日：1997-09-11
申请人： NIPPON OIL CO LTD
发明人： HAJI KATSUHIKO , NAGAO MASAKI , YOSHII TORU , KOMATA TATSUO
IPC分类号： C10L1/234 , C10L1/22 , C10L1/232 , C10L10/04
摘要： PROBLEM TO BE SOLVED: To obtain the subject additive, composed of a specific nitrogen- containing compound, excellent in solubility in fuel oil, particularly excellent in capacity of cleaning engine intake systems and combustion chambers, showing no deterioration in performance while the engine is cool, and forming no sludge. SOLUTION: This additive is composed of a nitrogen-containing compound shown by formula I [R is H, or a 1-30C hydrocarbon; R to R are each H, a 1-10C hydrocarbon, or a group shown by formula II (R and R are each H, a 1-10C hydrocarbon or the like; R is a 2-6C alkylene or the like; R is H or a 1-30C hydrocarbon; and (f) is 0 to 50), wherein at least one of R to R is the group shown by the formula II; R and R are each a 1-6C alkylene; X is H or a 1-30C hydrocarbon, R -OH (R is a 1-6C alkylene) or the like; and (a) is 1 to 100; (b) is 0 to 100, (a+b) is 1 to 200, (c) is 0 or 1, (d) is 1 to 3, (e) is 0 to 2, and (d+e) is 3].

7. 发明专利

JPH09255982A ELECTROVISCOUS FLUID 失效
公开(公告)号：JPH09255982A
公开(公告)日：1997-09-30
申请号：JP9618896
申请日：1996-03-26
申请人： NIPPON OIL CO LTD
发明人： HAJI KATSUHIKO , SASAKI MAKOTO , MATSUNO MITSUO
IPC分类号： C10M149/14 , C10M149/18 , C10M169/04 , C10M171/00 , C10N20/04 , C10N30/02 , C10N40/14
摘要： PROBLEM TO BE SOLVED: To obtain an electroviscous fluid which is a homogeneous system not suffering from the settlement of particles, through which an electric current can hardly pass, has low viscosity before an electric field is applied thereto and undergoes a large change in torque when an electric field is applied thereto by using a specified liquid crystal polymer. SOLUTION: This fluid is obtained by uniformly dissolving 0.5-60wt.% at least one lyotropic liquid crystal polymer having a weight-average molecular weight of 500-1,500,000 and selected from among poly (γ-glutamate), represented by formulas I and II (R1 is a 1-7C alkyl, a 7C aralkyl, a 6 or 7C aryl, a 3-7C cycloalkyl and a mixture containing at least two of these groups; R2 is an alkyl, an aralkyl, an aryl, a cycloalkyl or a mixture containing at least two of these groups, provided that each group has 8-30 carbon atoms; (m) is 1-6,500; (n) is 1-5,000; and n/m is 95/5 to 5/95), polyamino acids and polyisocyanates in a cyclic ketone or a mixed solvent comprising a cyclic ketone and at least one electrical insulation solvent selected from among hydrocarbon oils, ester oils and ether oils.

8. 发明专利

JPH07238290A ELECTROVISCOUS FLUID 失效
公开(公告)号：JPH07238290A
公开(公告)日：1995-09-12
申请号：JP5442394
申请日：1994-03-01
申请人： NIPPON OIL CO LTD
发明人： SASAKI MAKOTO , ISHII TAKAFUMI , HAJI KATSUHIKO
IPC分类号： C09K19/38 , C10M107/44 , C10M171/00 , C10N20/06 , C10N40/14
摘要： PURPOSE:To obtain the subject fluid which is a homogeneous system capable of avoiding the sedimentation of particles and greatly changing a torque before and after the application of an electric field by dissolving a lyotropic liquid crystalline polymer such as cellulose at a low concentration without manifesting the liquid crystallinity. CONSTITUTION:This fluid is obtained by dissolving a lyotropic liquid crystalline polymer, having a unit expressed by the formula (R is a l-7C alkyl, an aryl, etc.) and selected from a poly(gamma-glutamate), a polyisocyanate, a polysiloxane ester, an aromatic polyester, poly(beta-aspartate), an aromatic polyamide, cellulose (derivative), a polyamidohydrazine, a polyhydrazine, a polyphosphazene, an amphiphatic block copolymer, ribonucleic acid, deoxyribonucleic acid and a poly(meth)acrylic acid ester at a low concentration without manifesting the liquid crystallinity, preferably 0.1-7wt.% based on a solvent (preferably THF, etc.) in the solvent. Besides, the poly(gamma-glutamate) and polyisocyanate are preferable as the liquid crystalline polymer.

9. 发明专利

JPH0790290A DISPERSING PARTICLE HAVING EFFECTS OF BOTH MAGNETIC AND ELECTRIC VISCOSITY AND FLUID BY USING THE SAME 失效
公开(公告)号：JPH0790290A
公开(公告)日：1995-04-04
申请号：JP25783893
申请日：1993-09-21
申请人： NIPPON OIL CO LTD
发明人： SASAKI MAKOTO , HAJI KATSUHIKO
IPC分类号： C10M169/04 , C10M171/00 , C10N10/00 , C10N20/00 , C10N20/06 , C10N40/14 , H01B3/00 , H01F1/34 , H01F1/44
摘要： PURPOSE:To obtain the dispersing particles useful for the engine mounting, etc., composed of electric conductive ferromagnetic particles of which surfaces are covered by an electric insulating membrane, having a large torque induced by magnetic and electric fields with a quick response. CONSTITUTION:The dispersing particles composed of electric conductive ferromagnetic particles of which electric resistance is 10 OMEGAcm or less, and the surfaces of which are covered by an electric insulating membrane such as PE. Furthermore, a fluid having effects of both magnetic and electric viscosity is obtained by combining 1-90 (wt.) % of the particles with 99-10% of a electric insulating solvent such as alkylnaphthalenes, etc.

10. 发明专利

JPH06330068A ELECTROVISCOUS FLUID 失效
公开(公告)号：JPH06330068A
公开(公告)日：1994-11-29
申请号：JP14125393
申请日：1993-05-21
申请人： NIPPON OIL CO LTD
发明人： SASAKI MAKOTO , HAJI KATSUHIKO
IPC分类号： C10M107/44 , C10M149/18 , C10N30/04 , C10N40/14
摘要： PURPOSE:To provide an electroviscous fluid which comprises a specific poly(gamma- glutamate) and an electric insulation fluid at a specific ratio and is useful in engine mount because it show high torque value, can be controlled in its viscosity by applying electric fields to manifest excellent electroviscous effect. CONSTITUTION:The electroviscous liquid comprises (A) 0.1 to 60wt.% of poly(gamma- glutamate) having the chemical structures of formulas I and II [R1 is 1-7C alkyl, aralkyl, aryl, cycloalkyl; the unit ratio of the components of formula II to formula I (n/m) is 100/0 to 10/90] as essential ingredients, and (B) 40 to 99.9wt.% of an electric insulation liquid such as mineral oil or an alkylbenzene.

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