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    • 6. 发明专利
    • Hydrogen storage alloy and electrode for nickel-hydrogen battery using the same
    • 使用镍氢电池的氢存储合金和电极
    • JP2004285406A
    • 2004-10-14
    • JP2003078677
    • 2003-03-20
    • Mitsui Mining & Smelting Co Ltd三井金属鉱業株式会社
    • HIRAYAMA SHIGEONUMATA KOICHIKAGEI SHINYAINOUE HIDETOSHISAKAI MINORUOKIFUJI TAKASHI
    • C22C19/00H01M4/24
    • Y02E60/124
    • PROBLEM TO BE SOLVED: To provide a hydrogen storage alloy which imparts a uniform performance to a battery and shows a high activity at the initial stage, and a nickel-hydrogen secondary battery using the same.
      SOLUTION: The AB
      5 -type hydrogen storage alloy has a CaCu
      5 crystal structure, a composition represented by the formula: MmNi
      a Mn
      b Al
      c Co
      d M
      e (wherein Mm is a misch metal; M is one chosen from Cu, Ti, V, Cr and Zn; and a-e each represents a mole number against 1 molar Mm and satisfies 4.8≤a+b+c+d≤5.4, 3.5≤a≤4.5, 0.2≤b≤0.7, 0.1≤c≤0.4, 0.1≤d≤0.8, 0≤e≤0.2 and 4.80≤a+b+c+d+s≤5.40), a carbon content of the alloy of ≤300 ppm and an iron content of ≤0.5 wt.%. The hydrogen storage alloy thus obtained shows a high activity at the initial stage and is suitably used as a negative electrode of the nickel secondary battery.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种赋予电池均匀性能并且在初始阶段显示高活性的储氢合金和使用该储氢合金的镍氢二次电池。 解决方案:AB 5 型储氢合金具有CaCu 5 晶体结构,由下式表示的组成:MmNi a (其中Mm是稀土金属; M是从Cu中选出的一种) ,Ti,V,Cr和Zn; ae分别代表1摩尔Mm的摩尔数,满足4.8≤a+ b + c +d≤5.4,3.5≤a≤4.5,0.2≤b≤0.7,0.1≤c≤ 0.4,0.1≤d≤0.8,0≤e≤0.2和4.80≤a+ b + c + d +s≤5.40),合金的碳含量≤300ppm,铁含量≤0.5重量%。 由此得到的储氢合金在初期显示高活性,适合用作镍二次电池的负极。 版权所有(C)2005,JPO&NCIPI