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1. 发明专利

JP2015044166A 有機化合物の酸化分解方法审中-公开
标题翻译：有机化合物的氧化分解方法
公开(公告)号：JP2015044166A
公开(公告)日：2015-03-12
申请号：JP2013177487
申请日：2013-08-29
申请人：三井造船株式会社 , Mitsui Eng & Shipbuild Co Ltd , 三井造船プラントエンジニアリング株式会社 , Mitsui Zosen Plant Engineering Inc , 株式会社ニクス , Nix:Kk
发明人： SENO HIROSHI , MATSUMOTO YASUO , TANIHATA KAZUKI , MURATA TOSHIAKI , TAMAGAWA JUNNOSUKE , HASEGAWA HIROAKI
IPC分类号： C02F1/72 , B01J35/02
摘要：【課題】第1に、処理対象の酸化分解率を考慮し、最適な処理条件算出が実現されると共に、第2に、処理対象の化学物質名と濃度が検出できなかった場合でも、最適な処理条件算出が可能であり、第3に、自動化,制御化,ツール化も実現される、有機化合物の酸化分解方法を提案する。【解決手段】この酸化分解方法では、検査プロセスにおいて、処理対象1について少なくとも化学物質名と濃度が検査される。化学物質名と濃度が検出,入力された場合は、モード1プロセスへと進み、処理対象1の酸化分解に要するOHラジカルのモル数が演算され、OHラジカル酸化促進法全般に適用される。化学物質名と濃度が検出,入力されず、有機物汚濁指標濃度が検出,入力された場合は、モード2プロセスへと進み、処理対象1の酸化分解に要するフェントン法の過酸化水素の添加量が、演算される。【選択図】図1
摘要翻译：要解决的问题：提供一种有机化合物的氧化分解方法，首先通过考虑待处理物体的氧化分解速率来计算最佳处理条件，其次即使当化学物质尚未检测到待处理对象的名称和浓度，并且第三次自动化最佳处理条件的计算，控制其计算，并将其计算成工具。解决方案：在氧化分解方法中，至少在检查过程中检查要处理的物体1的化学物质名称和浓度。当检测并输入化学物质名称和浓度时，进行处理模式1计算待处理物体1的氧化分解所需的OH基团的摩尔数，并应用于OH的氧化加速法一般激进。当没有检测到化学物质名称和浓度并且没有输入，并且检测和输入有机污染指数的浓度时，待处理物体1的氧化分解所需的Fenton法中过氧化氢的添加量是在进行处理模式2时计算。

2. 发明专利

JP2009255078A Treatment device and treatment method for organic phosphorous based pesticide-containing water 有权
标题翻译：有机磷基含磷水处理装置及处理方法
公开(公告)号：JP2009255078A
公开(公告)日：2009-11-05
申请号：JP2009079142
申请日：2009-03-27
申请人： Mitsui Eng & Shipbuild Co Ltd , Mitsui Zosen Plant Engineering Inc , Nix:Kk , 三井造船プラントエンジニアリング株式会社 , 三井造船株式会社 , 株式会社ニクス
发明人： SENO HIROSHI , MURATA TOSHIAKI , TAMAGAWA JUNNOSUKE , WATANABE MASAHIKO , HASEGAWA HIROAKI
IPC分类号： C02F1/72
摘要： PROBLEM TO BE SOLVED: To provide a treatment device and a treatment method for organic phosphorous based pesticide-containing water where, first, OH radicals are efficiently produced, thus an organic phosphorous based pesticide can be securely oxidized and decomposed, and secondary, the above operations can be achieved under excellent running cost, posttreatment cost, easiness of control, stability of treatment, initial cost or the like.
SOLUTION: In the treatment device 2 and the treatment method, an organic phosphorous based pesticide 1 comprised in treatment water 3 is oxidized and decomposed based on a Fenton process. Then, the treatment device 2 is provided with: a treatment tank 4; and a treatment water feeding means 5, a hydrogen peroxide adding means 6, an iron ion adding means 7 and a pH regulating means 8 attached to the treatment tank 4. Regarding the hydrogen peroxide adding means 6, hydrogen peroxide is added to the treatment water 3 in the treatment tank 4, regarding the iron ion adding means 7, bivalent ion ions are added to the treatment water 3, and, regarding the pH regulating means 8, a pH regulator is added to the treatment water 3, and the treatment water 3 is retained to prescribed weak acidity.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种有机磷基农药含水的处理装置和处理方法，其中首先有效地制备OH自由基，因此有机磷农药可以被可靠地氧化分解，二次上述操作可以在优异的运行成本，后处理成本，易于控制，处理稳定性，初始成本等方面实现。解决方案：在处理装置2和处理方法中，基于芬顿方法将包含在处理水3中的基于有机磷的农药1氧化和分解。然后，处理装置2设置有：处理槽4; 处理水供给装置5，过氧化氢添加装置6，铁离子添加装置7和附着在处理槽4上的pH调节装置8.关于过氧化氢添加装置6，向处理水中加入过氧化氢 3处理槽4中，关于铁离子添加机构7，向处理水3中添加二价离子离子，在pH调节单元8中，向处理水3添加pH调节剂，处理水 3保持规定的弱酸性。版权所有（C）2010，JPO＆INPIT

3. 发明专利

JP2009254964A Treatment device and treatment method for volatile organic compound-containing water 有权
标题翻译：用于挥发性有机化合物水的处理装置和处理方法
公开(公告)号：JP2009254964A
公开(公告)日：2009-11-05
申请号：JP2008106386
申请日：2008-04-16
申请人： Mitsui Eng & Shipbuild Co Ltd , Mitsui Zosen Plant Engineering Inc , Nix:Kk , 三井造船プラントエンジニアリング株式会社 , 三井造船株式会社 , 株式会社ニクス
发明人： SENO HIROSHI , MURATA TOSHIAKI , TAMAGAWA JUNNOSUKE , WATANABE MASAHIKO , HASEGAWA HIROAKI
IPC分类号： C02F1/72
摘要： PROBLEM TO BE SOLVED: To provide a treatment device and a treatment method for volatile organic compound-containing water where, first, OH radicals are efficiently produced, thus a volatile organic compound can be securely oxidized and decomposed, and secondary, the above operations can be achieved under excellent running cost, posttreatment cost, easiness of control, stability of treatment, initial cost or the like.
SOLUTION: In the treatment device 2 and the treatment method, a volatile organic compound 1 comprised in treatment water 3 is oxidized and decomposed based on a Fenton process. Then, the treatment device 2 is provided with: a treatment tank 4; and a treatment water feeding means 5, a hydrogen peroxide adding means 6, an iron ion adding means 7 and a pH regulating means 8 attached to the treatment tank 4. Regarding the hydrogen peroxide adding means 6, hydrogen peroxide is added to the treatment water 3 in the treatment tank 4, regarding the iron ion adding means 7, bivalent iron ions are added to the treatment water 3 in the treatment tank 4, and, regarding the pH regulating means 8, the treatment water 3 in the treatment tank 4 is retained to prescribed weak acidity.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种用于挥发性有机化合物的水的处理装置和处理方法，其中首先有效地制备OH自由基，从而可以可靠地氧化和分解挥发性有机化合物，并且二次上述操作可以在良好的运行成本，后处理成本，易于控制，处理稳定性，初始成本等方面实现。解决方案：在处理装置2和处理方法中，包含在处理水3中的挥发性有机化合物1基于芬顿方法被氧化分解。然后，处理装置2设置有：处理槽4; 处理水供给装置5，过氧化氢添加装置6，铁离子添加装置7和附着在处理槽4上的pH调节装置8.关于过氧化氢添加装置6，向处理水中加入过氧化氢 3处理槽4中，关于铁离子添加机构7，向处理槽4中的处理水3添加二价铁离子，在pH调节单元8中，处理槽4中的处理水3为保留规定的弱酸性。版权所有（C）2010，JPO＆INPIT

4. 发明专利

JP2011206626A Oxidative decomposition method of nitrogen-based organic compound 有权
标题翻译：硝基有机化合物的氧化分解方法
公开(公告)号：JP2011206626A
公开(公告)日：2011-10-20
申请号：JP2010074184
申请日：2010-03-29
申请人： Mitsui Eng & Shipbuild Co Ltd , Mitsui Zosen Plant Engineering Inc , Nix:Kk , 三井造船プラントエンジニアリング株式会社 , 三井造船株式会社 , 株式会社ニクス
发明人： SENO HIROSHI , MATSUMOTO YASUO , MURATA TOSHIAKI , TAMAGAWA JUNNOSUKE , HASEGAWA HIROAKI
IPC分类号： C02F1/72
摘要： PROBLEM TO BE SOLVED: To provide an oxidative decomposition method of a nitrogen-based organic compound for establishing a computational algorithm for the required total number of moles of OH radicals or the like, and achieving an automated and controlled computational algorithm tool.SOLUTION: In the oxidative decomposition method, a nitrogen atom-containing component of a hardly decomposable nitrogen-based organic compound is subjected to oxidative decomposition by an OH radical. The oxidative decomposition method includes: a first process where, when an OH group is contained, the OH radical takes a hydrogen atom to cause oxidation of the OH group and to form a double-bonded oxygen atom; a second process where, when a hydrogen atom is contained, the OH radical takes the hydrogen atom to cause oxidation; and a third process where the OH radical is added to an unpaired electron of the atom to produce the OH group. In a fourth process, the OH radical takes the hydrogen atom from a water molecule to cause oxidation, and nascent hydrogen is produced to thereby produce nitric acid by reduction.
摘要翻译：要解决的问题：提供一种氮基有机化合物的氧化分解方法，用于建立所需的OH自由基总摩尔数等的计算算法，并实现自动化和受控的计算算法工具。解决方案：在通过氧化分解法，难以分解的氮类有机化合物的含氮原子的成分被OH基进行氧化分解。氧化分解方法包括：第一方法，当含有OH基时，OH基取代氢原子引起OH基的氧化并形成双键键合的氧原子; 其中当含有氢原子时，OH基取代氢原子引起氧化; 以及第三种方法，其中将OH基添加到原子的不成对电子以产生OH基团。在第四种方法中，OH基取自水分子的氢原子引起氧化，生成新生氢，从而通过还原产生硝酸。

5. 发明专利

JP2009142754A Apparatus and method for treating ethylene glycols 有权
标题翻译：用于处理乙烯甘油的装置和方法
公开(公告)号：JP2009142754A
公开(公告)日：2009-07-02
申请号：JP2007322860
申请日：2007-12-14
申请人： Mitsui Eng & Shipbuild Co Ltd , Mitsui Zosen Plant Engineering Inc , Nix:Kk , 三井造船プラントエンジニアリング株式会社 , 三井造船株式会社 , 株式会社ニクス
发明人： SENO HIROSHI , MURATA TOSHIAKI , TAMAGAWA JUNNOSUKE , WATANABE MASAHIKO , HASEGAWA HIROAKI
IPC分类号： C02F1/72
摘要： PROBLEM TO BE SOLVED: To provide an apparatus and a method for treating ethylene glycols which efficiently generate OH radicals and is excellent in running cost and the like, is excellent in post-treatment cost, facilitate control of the amount of added chemicals, and is excellent in treatment stability, initial cost, and the like.
SOLUTION: In the treatment apparatus 2 and method, a hydrogen peroxide adding means 6 adds the whole of an aqueous solution of hydrogen peroxide to water 3 to be treated in a treatment tank 4 at the beginning of reaction, an iron ion adding means 7 dividedly adds a divalent iron ion solution after the addition of hydrogen peroxide, a pH adjusting means 8 adds a pH adjusting agent before the addition of hydrogen peroxide and every divided addition of the iron ion solution to keep the pH of the water 3 to be treated at about 4. As a result, OH radicals are produced by the main Fenton reaction and the associated chain reaction to oxidize, decompose and mineralize ethylene glycols 1 contained in the water 3 to be treated.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：为了提供一种处理有效产生OH自由基并且运行成本等优异的乙二醇的装置和方法，后处理成本优异，便于控制添加化学品的量，处理稳定性，初始成本等优异。解决方案：在处理装置2和方法中，过氧化氢添加装置6在反应开始时将处理槽4中的过氧化氢水溶液全部添加到待处理的水3中，添加铁离子装置7在加入过氧化氢后分开添加二价铁离子溶液，pH调节装置8在加入过氧化氢之前加入pH调节剂，并每次分一次加入铁离子溶液以保持水的pH 3 在约4℃下处理。结果，通过主要芬顿反应和相关联的链式反应产生OH自由基，以使待处理的水3中所含的乙二醇1氧化，分解和矿化。版权所有（C）2009，JPO＆INPIT

6. 发明专利

JP2009297708A Apparatus and method for treating estrogen-containing water 有权
标题翻译：用于处理含水原子水的装置和方法
公开(公告)号：JP2009297708A
公开(公告)日：2009-12-24
申请号：JP2009116693
申请日：2009-05-13
申请人： Mitsui Eng & Shipbuild Co Ltd , Mitsui Zosen Plant Engineering Inc , Nix:Kk , 三井造船プラントエンジニアリング株式会社 , 三井造船株式会社 , 株式会社ニクス
发明人： SENO HIROSHI , MURATA TOSHIAKI , TAMAGAWA JUNNOSUKE , WATANABE MASAHIKO , HASEGAWA HIROAKI
IPC分类号： C02F1/72
摘要： PROBLEM TO BE SOLVED: To provide an apparatus and a method for treating estrogen-containing water firstly capable of efficiently and massively producing OH radicals thereby surly oxidizing to decompose estrogen, nevertheless secondly capable of achieving excellent performances in a running cost, an after-treatment cost, control ease, treatment stability, and an initial cost.
SOLUTION: The apparatus 2 and the method for treating oxidize the estrogen 1 contained in treating water 3 by the Fenton method to decompose. The apparatus 2 for treating comprises a treatment vessel 4, and a treating water supplying means 5, a hydrogen peroxide adding means 6, an iron ion adding means 7 and a pH adjusting means 8, attached on the treatment vessel 4 respectively. The hydrogen peroxide adding means 6 adds hydrogen peroxide to the treating water 3 in the treatment vessel 4, the iron ion adding means 7 adds bivalent iron ions to the treating water 3 in the treatment vessel 4, and the pH adjusting means 8 maintains the treating water 3 in the treatment vessel 4 in a predetermined weak acidity.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种治疗含雌激素的水的装置和方法，其首先能够高效且大量地产生OH自由基，从而氧化分解雌激素，但是其次能够在运行成本方面获得优异的性能，治疗后成本，控制容易度，治疗稳定性和初始成本。解决方案：设备2和处理方法通过芬顿方法氧化处理水3中所含的雌激素1来分解。处理装置2包括分别附着在处理容器4上的处理容器4和处理水供给装置5，过氧化氢添加装置6，铁离子添加装置7和pH调节装置8。过氧化氢添加装置6向处理容器4中的处理水3添加过氧化氢，铁离子添加装置7将二价铁离子加入处理容器4中的处理水3，并且pH调节装置8保持处理处理容器4中的水3处于预定的弱酸性。版权所有（C）2010，JPO＆INPIT

7. 发明专利

JP2009082907A Method and apparatus for treating nonyl phenol 有权
标题翻译：用于处理非苯酚的方法和装置
公开(公告)号：JP2009082907A
公开(公告)日：2009-04-23
申请号：JP2008230444
申请日：2008-09-09
申请人： Mitsui Eng & Shipbuild Co Ltd , Mitsui Zosen Plant Engineering Inc , Nix:Kk , 三井造船プラントエンジニアリング株式会社 , 三井造船株式会社 , 株式会社ニクス
发明人： SENO HIROSHI , MURATA TOSHIAKI , TAMAGAWA JUNNOSUKE , WATANABE MASAHIKO , HASEGAWA HIROAKI
IPC分类号： C02F1/72
摘要： PROBLEM TO BE SOLVED: To provide a method and apparatus for treating nonyl phenol, much excellent, first, in a running cost, by, for example, effectively producing an OH radical without loss, second, in a post treatment cost, third, in the simplicity for controlling the amount of chemicals added, and fourth, in the treatment stability, the initial cost, and the space required.
SOLUTION: In this treatment apparatus 2 and treatment method, a hydrogen peroxide adding means 6 adds all the required amount of a hydrogen peroxide aqueous solution to water 3 to be treated in a treatment tank 4 when the reaction is started, then a ferrous ion adding means 7 incrementally adds to the water 3 a ferrous ion aqueous solution after adding the hydrogen peroxide, and a pH control means 8 adds a pH control agent before adding the hydrogen peroxide and every time the ferrous ion aqueous solution is added in order to maintain the pH of the water 3 to be treated around 4. Thus the nonyl phenol 1 in the water 3 to be treated is oxidized and decomposed by the OH radical produced by Fenton's main reaction and its accompanying reaction, subordinate reaction, and chain reaction.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：提供一种非常优异的处理壬基苯酚的方法和装置，首先，在运行成本中，例如通过有效地产生OH基团而不损失;其次，在后处理成本中，第三，在控制化学品添加量的简单性方面，第四，处理稳定性，初始成本和所需的空间。解决方案：在该处理装置2和处理方法中，当反应开始时，过氧化氢添加装置6将所需量的所需量的过氧化氢水溶液加入处理槽4中待处理的水3，亚铁离子加入装置7在加入过氧化氢后逐渐向水中加入亚铁离子水溶液，pH控制装置8在加入过氧化氢之前加入pH调节剂，并且每次依次加入亚铁离子水溶液以维持待处理的水3的pH值4.因此待处理的水3中的壬基苯酚1被通过芬顿主要反应产生的OH自由基及其伴随的反应，从属反应和连锁反应氧化分解。版权所有（C）2009，JPO＆INPIT

8. 发明专利

JP2011078875A Method for oxidatively decomposing organic compound 有权
标题翻译：氧化有机化合物的方法
公开(公告)号：JP2011078875A
公开(公告)日：2011-04-21
申请号：JP2009231611
申请日：2009-10-05
申请人： Mitsui Eng & Shipbuild Co Ltd , Mitsui Zosen Plant Engineering Inc , Nix:Kk , 三井造船プラントエンジニアリング株式会社 , 三井造船株式会社 , 株式会社ニクス
发明人： SENO HIROSHI , MURATA TOSHIAKI , TANIHATA KAZUKI , TAMAGAWA JUNNOSUKE , MATSUMOTO YASUO , HASEGAWA HIROAKI
IPC分类号： C02F1/72 , B01J27/053 , B01J27/128
摘要： PROBLEM TO BE SOLVED: To provide a method for oxidatively decomposing an organic compound by which computational algorithm of necessary total mole number of OH radical or the like is established firstly and especially automation, controlling and tooling thereof are achieved secondarily. SOLUTION: In the method for oxidatively decomposing the organic compound, a first step in the case of having a hydroxyl group, a second step in the case of having a hydrogen atom attached to a carbon atom or an oxygen atom and then a third step where the hydroxyl group is regenerated are repeated under participation of an OH radical to a hardly decomposable organic compound which is an object 1. Furthermore, if necessary, a fourth step of a reduction pattern by nascent hydrogen produced under participation of the OH radical is also added. By repeating each of these steps, the organic compound which is the object 1 is subjected to oxidative decomposition and is turned to inorganic substances such as water, gaseous carbon dioxide, oxygen molecules. A controller 11 such as a microcomputer 14 where these steps are programmed can be also utilized. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于氧化分解有机化合物的方法，其中首先建立必要的OH基等摩尔数的计算算法，特别是自动化，其次要地进行其控制和加工。解决方案：在氧化分解有机化合物的方法中，在具有羟基的情况下的第一步骤，在连接到碳原子或氧原子上的氢原子的情况下的第二步，然后是第三步，其中羟基被再生，在参与OH基的情况下重复到作为对象1的难以分解的有机化合物。此外，如果需要，在OH基团的参与下产生的新生氢还原模式的第四步骤也被添加。通过重复这些步骤，将作为对象1的有机化合物进行氧化分解，并转化为无机物质如水，气态二氧化碳，氧分子。也可以利用诸如微计算机14的这些步骤被编程的控制器11。版权所有（C）2011，JPO＆INPIT

9. 发明专利

JP2009255077A TREATMENT DEVICE AND TREATMENT METHOD FOR β LACTAM BASED ANTIBIOTICS-CONTAINING WATER 有权
标题翻译：用于基于β乳酸酶的含抗生物水的处理装置和处理方法
公开(公告)号：JP2009255077A
公开(公告)日：2009-11-05
申请号：JP2009079090
申请日：2009-03-27
申请人： Mitsui Eng & Shipbuild Co Ltd , Mitsui Zosen Plant Engineering Inc , Nix:Kk , 三井造船プラントエンジニアリング株式会社 , 三井造船株式会社 , 株式会社ニクス
发明人： SENO HIROSHI , HONMA NORIYUKI , MURATA TOSHIAKI , TAMAGAWA JUNNOSUKE , WATANABE MASAHIKO , HASEGAWA HIROAKI
IPC分类号： C02F1/72
摘要： PROBLEM TO BE SOLVED: To provide a treatment device and a treatment method for β lactam based antibiotics-containing water where, first, OH radicals are efficiently produced, thus β lactam based antibiotics can be securely oxidized and decomposed, and secondary, the above operations can be achieved under excellent running cost, posttreatment cost, easiness of control, stability of treatment, initial cost or the like. SOLUTION: In the treatment device 2 and the treatment method, β lactam based antibiotics 1 comprised in treatment water 3 are oxidized and decomposed based on a Fenton process. Then, the treatment device 2 is provided with: a treatment tank 4; and a treatment water feeding means 5, a hydrogen peroxide adding means 6, an iron ion adding means 7 and a pH regulating means 8 attached to the treatment tank 4. Regarding the hydrogen peroxide adding means 6, hydrogen peroxide is added to the treatment water 3 in the treatment tank 4, regarding the iron ion adding means 7, bivalent iron ions are added to the treatment water 3 in the treatment tank 4, and, regarding the pH regulating means 8, the treatment water 3 in the treatment tank 4 is retained to prescribed weak acidity. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：为了提供一种含有β-内酰胺基抗生素的水的处理装置和处理方法，其中首先有效地制备OH自由基，从而可以将β-内酰胺类抗生素可靠地氧化分解，上述操作可以在良好的运行成本，后处理成本，易于控制，处理稳定性，初始成本等方面实现。解决方案：在处理装置2和处理方法中，包含在处理水3中的β-内酰胺类抗生素1基于芬顿方法被氧化分解。然后，处理装置2设置有：处理槽4; 处理水供给装置5，过氧化氢添加装置6，铁离子添加装置7和附着在处理槽4上的pH调节装置8.关于过氧化氢添加装置6，向处理水中加入过氧化氢 3处理槽4中，关于铁离子添加机构7，向处理槽4中的处理水3添加二价铁离子，在pH调节单元8中，处理槽4中的处理水3为保留规定的弱酸性。版权所有（C）2010，JPO＆INPIT

10. 发明专利

JP2009011982A Treatment apparatus and treatment method of low-concentration polychlorinated biphenyl 审中-公开
标题翻译：低浓度聚氯乙烯的处理装置及处理方法
公开(公告)号：JP2009011982A
公开(公告)日：2009-01-22
申请号：JP2007179245
申请日：2007-07-09
申请人： Mitsui Eng & Shipbuild Co Ltd , Mitsui Zosen Plant Engineering Inc , Nix:Kk , 三井造船プラントエンジニアリング株式会社 , 三井造船株式会社 , 株式会社ニクス
发明人： SENO HIROSHI , MURATA TOSHIAKI , TAMAGAWA JUNNOSUKE , WATANABE MASAHIKO , HASEGAWA HIROAKI
IPC分类号： C02F1/72
摘要： PROBLEM TO BE SOLVED: To provide a treatment apparatus and a treatment method of low concentration polychlorinated biphenyl which have advantages such as firstly freedom from wasting of hydrogen peroxide, high efficiency, freedom from uselessness, and excellent running cost, secondly excellent post-treatment cost, thirdly easy control of dose of chemicals, and fourthly excellent treatment stability, initial cost, space and the like.
SOLUTION: In this treatment apparatus 2 and treatment method, low-concentration polychlorinated biphenyl 1 contained in an object treatment water 3 is oxidized and decomposed by a Fenton method. The whole amount of an aqueous hydrogen peroxide solution is added by a hydrogen peroxide addition means 6 to the treatment water 3 supplied to a treatment tank 4 in an early stage of the reaction. An iron ion addition means 7 adds a divalent iron ion solution to the object treatment water 3, contained in the treatment tank 4, in divisions. Every time when the iron ion solution is added in divisions to the object treatment water 3 to be supplied and the supplied object treatment water 3, a pH adjustment means 8 adds a pH adjustor to maintain the object treatment water 3 at a pH value of about 4.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种低浓度多氯联苯的处理装置和处理方法，其具有以下优点：首先免除过氧化氢的浪费，高效率，免于无用性和优异的运行成本，其次优良的柱处理成本，第三，容易控制化学品的剂量，第四，优良的处理稳定性，初始成本，空间等。解决方案：在该处理装置2和处理方法中，包含在对象处理水3中的低浓度多氯联苯1被Fenton法氧化分解。过氧化氢添加装置6将全部量的过氧化氢水溶液加入到反应初期供给到处理槽4的处理水3中。铁离子添加装置7将二价铁离子溶液加入到处理槽4中包含的物体处理水3中。每当将铁离子溶液分配到待供给的对象处理水3和供给的对象处理水3时，pH调节装置8添加pH调节剂以将对象处理水3保持在约pH值 4.版权所有（C）2009，JPO＆INPIT

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