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1. 发明专利

JP2014019825A Process for producing olefin polymer 有权
标题翻译：生产烯烃聚合物的方法
公开(公告)号：JP2014019825A
公开(公告)日：2014-02-03
申请号：JP2012161690
申请日：2012-07-20
申请人： Mitsui Chemicals Inc , 三井化学株式会社 , Prime Polymer Co Ltd , 株式会社プライムポリマー
发明人： HARADA YASUYUKI , KIYOSAWA KUNIOMI , MUROTO TOSHIHIRO , SAEKI KAZUAKI , SATO YASUO , BANDO HIDEKI , MATSUMOTO KOTA , HIGUCHI TADASHI
IPC分类号： C08F4/6592 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a process for producing a polyolefin polymer, which can, in production of a polymer intended for introduction of a long-chain branch and widening of a molecular weight distribution, control a composition of the polymer and provide excellent moldability and mechanical strength of the polymer.SOLUTION: There is provided a process for producing an olefin polymer comprising use of a solid catalyst formed by placing two or more transition metal complexes in contact with a catalyst support, wherein a compound having an active proton is supplied into a polymerization system with an amount of no fewer than 1 ppm and no more than 2,000 ppm relative to a yield of the olefin polymer.
摘要翻译：要解决的问题：提供一种制备聚烯烃聚合物的方法，其可以在生产用于引入长链分支的聚合物和扩大分子量分布时控制聚合物的组成并提供优异的成型性和聚合物的机械强度。解决方案：提供了一种制备烯烃聚合物的方法，其包括使用通过将两个或更多个过渡金属络合物与催化剂载体接触而形成的固体催化剂，其中提供具有活性质子的化合物成为相对于烯烃聚合物的收率不少于1ppm且不超过2000ppm的聚合体系。

2. 发明专利

JP2012207154A Propylene resin composition 有权
标题翻译：丙烯树脂组合物
公开(公告)号：JP2012207154A
公开(公告)日：2012-10-25
申请号：JP2011074813
申请日：2011-03-30
申请人： Mitsui Chemicals Inc , Prime Polymer Co Ltd , 三井化学株式会社 , 株式会社プライムポリマー
发明人： IIJIMA KAZUHIRO , ITAKURA KEITA , HIGUCHI TADASHI
IPC分类号： C08L23/10 , C08L23/08 , C08L23/16 , C08L101/00
摘要： PROBLEM TO BE SOLVED: To provide a propylene resin composition excellent in mechanical properties such as elongation, impact resistance and low-temperature impact resistance and flowability.SOLUTION: There is provided the propylene resin composition containing ≥55 pts.mass and ≤98 pts.mass of a propylene polymer (A) satisfying the following requirements [1] to [5] and ≥2 pts.mass and ≤45 pts.mass of an elastomer (B). [1] MFR is ≥100 g/10 min and ≤1,000 g/10 min, [2] the melting point is ≥150°C and ≤165°C, [3] the sum of the position irregular unit based on 2,1-bonds and the position irregular unit based on 1,3-bonds of propylene monomers in total propylene constituent units is ≥0.0% and ≤1.0%, [4] the content of components having a molecular weight of ≤10,000 is ≤7 mass%, and [5] the half-value width of the peak of elution quantity to elution temperature is ≤6.0°C and the peak top temperature is ≥100°C and ≤130°C determined by CFC using o-dichlorobenzene.
摘要翻译：要解决的问题：提供具有伸长率，耐冲击性和耐低温冲击性等的机械性能和流动性优异的丙烯树脂组合物。解决方案：提供含有≥55个聚合物（A）的≥55个聚合物（A）的丙烯树脂组合物，满足以下要求[1]至[5]和≥2个氨基甲酸乙酯和 45磅弹性体（B）。 [1] MFR≥100g / 10 min，≤1,000g / 10 min，[2]熔点≥150°C，≤165°C，[3]基于2的位置不规则单位之和，基于丙烯单体的丙烯单体的1,3-键的位置不规则单元为≥0.0％且≤1.0％，[4]分子量≤10,000的组分的含量≤7质量％％和[5]，洗脱量峰值与洗脱温度的半值宽度为≤6.0℃，峰顶温度≥100℃，通过CFC使用邻二氯苯测定≤130℃。版权所有（C）2013，JPO＆INPIT

3. 发明专利

JP2011195662A Propylene-based resin composition and molded article obtained from the same 有权
标题翻译：基于丙烯的树脂组合物和从其获得的成型品
公开(公告)号：JP2011195662A
公开(公告)日：2011-10-06
申请号：JP2010062399
申请日：2010-03-18
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： TSUKAHARA YOSHIAKI , ITAKURA KEITA , MATSUNAGA KAZUHISA , HIGUCHI TADASHI
IPC分类号： C08L53/00 , C08F4/654 , C08F297/08
摘要： PROBLEM TO BE SOLVED: To provide a propylene-based resin composition that is excellent in rigidity and impact resistance, and gives a molded article having little poor appearance.SOLUTION: The resin composition is obtained via a process of producing a propylene polymer and a propylene-ethylene copolymer rubber, and contains a propylene-based block copolymer (A) whose [1A]-[8A] satisfy each specific value and a propylene-based block copolymer (B) whose [1B]-[8B] satisfy each specific value, namely, [1A] the melt flow rate, [2A] decane soluble amount and non-soluble amount, [3A] Mw/Mn value of soluble part, [4A] amount of ethylene of soluble part, [5A] [η] value of soluble part, [6A] Mw/Mn value of non-soluble part, [7A] pentad fraction of non-soluble part, [8A] chain molar fraction of soluble part, [1B] melt flow rate, [2B] decane soluble amount and non-soluble amount, [3B] Mw/Mn value of soluble part, [4B] amount of ethylene content in soluble part, [5B] [η] value of soluble part, [6B] Mw/Mn value of non-soluble part, [7B] pentad fraction of non-soluble part, and [8B] chain molar fraction of soluble part.
摘要翻译：要解决的问题：提供刚性和耐冲击性优异的丙烯类树脂组合物，得到外观差的成型品。溶液：通过制造丙烯聚合物和丙烯的方法得到树脂组合物 - 乙烯共聚物橡胶，并且其[1A] - [8A]满足各自的特定值的丙烯类嵌段共聚物（A）和其[1B] - [8B]满足各特定值的丙烯类嵌段共聚物（B）即[1A]熔体流动速率，[2A]癸烷可溶量和非可溶量，[3A]可溶部分的Mw / Mn值，[4A]可溶部分乙烯量[5A] [η] [6A]不溶性部分的Mw / Mn值，[7A]不溶性部分的五元组分，[8A]可溶部分的链摩尔分数，[1B]熔体流动速率，[2B]癸烷可溶量和不可溶量，[3B]可溶部分的Mw / Mn值，[4B]可溶部分中乙烯含量的量，[5B] [η]可溶部分值，[6 B]不可溶部分的Mw / Mn值，[7B]不溶性部分的五元组分和[8B]可溶部分的链摩尔分数。

4. 发明专利

JP2008045009A Propylenic resin compositioh for packaging material and its use 有权
标题翻译：用于包装材料的丙烯酸树脂组合物及其用途
公开(公告)号：JP2008045009A
公开(公告)日：2008-02-28
申请号：JP2006220682
申请日：2006-08-11
申请人： Mitsui Chemicals Inc , Prime Polymer:Kk , 三井化学株式会社 , 株式会社プライムポリマー
发明人： ITAKURA KEITA , KIMURA TOKUTARO , KAWADA ATSUO , HASHIZUME SATOSHI , HIGUCHI TADASHI , FUNATANI MUNEHITO
IPC分类号： C08L23/10 , C08F297/08 , C08L23/08
摘要： PROBLEM TO BE SOLVED: To provide a propylenic resin composition for packaging materials, excellent in the balance of high transparency, rigidity, low temperature impact resistance and blocking resistance, and to provide a film for retorts and a film for protect, obtained from the same. SOLUTION: This propylenic resin composition for the packaging materials comprises a propylene polymer (A) satisfying specific requirements and propylene-ethylene copolymer (B) satisfying specific requirements, wherein D insol and D sol satisfy specific requirements. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于包装材料的丙烯树脂组合物，其具有优异的高透明度，刚性，低温耐冲击性和耐粘连性的平衡，并且提供了一种用于蒸馏的膜和用于保护的膜从同一个解决方案：用于包装材料的该丙烯类树脂组合物包含满足特定要求的丙烯聚合物（A）和满足特定要求的丙烯 - 乙烯共聚物（B），其中D 不溶物和D sol 满足特定要求。版权所有（C）2008，JPO＆INPIT

5. 发明专利

JP2008045008A Propylenic resin compositioh for packaging material 有权
标题翻译：用于包装材料的丙烯酸树脂组合物
公开(公告)号：JP2008045008A
公开(公告)日：2008-02-28
申请号：JP2006220679
申请日：2006-08-11
申请人： Mitsui Chemicals Inc , Prime Polymer:Kk , 三井化学株式会社 , 株式会社プライムポリマー
发明人： ITAKURA KEITA , KIMURA TOKUTARO , KAWADA ATSUO , HASHIZUME SATOSHI , HIGUCHI TADASHI , FUNATANI MUNEHITO
IPC分类号： C08L23/10 , C08F297/08 , C08L23/08 , C08L53/00
摘要： PROBLEM TO BE SOLVED: To provide a propylenic resin composition for packaging materials, excellent in the balance of high transparency, rigidity, low temperature impact resistance and blocking resistance, to provide a film for retorts, a film for protect, and a film for packaging medical treatment containers, obtained from the same, and to provide a sheet therefor. SOLUTION: This propylenic resin composition for the packaging materials comprises a propylene polymer (A) satisfying specific requirements and propylene-ethylene copolymer (B) satisfying specific requirements, wherein D insol and D sol satisfy specific requirements. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于包装材料的丙烯树脂组合物，其具有优异的高透明度，刚性，低温耐冲击性和抗粘连性的平衡，以提供用于蒸馏的膜，保护膜和用于包装医疗容器的薄膜，从其获得并提供片材。解决方案：用于包装材料的该丙烯类树脂组合物包含满足特定要求的丙烯聚合物（A）和满足特定要求的丙烯 - 乙烯共聚物（B），其中D 不溶物和D sol 满足特定要求。版权所有（C）2008，JPO＆INPIT

6. 发明专利

JP2011184620A Propylene-based resin composition and molded body obtained therefrom 有权
标题翻译：基于丙烯的树脂组合物和由其获得的成型体
公开(公告)号：JP2011184620A
公开(公告)日：2011-09-22
申请号：JP2010053029
申请日：2010-03-10
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： ITAKURA KEITA , HIGUCHI TADASHI , SEKIGUCHI KATSUMI , MATSUNAGA KAZUHISA
IPC分类号： C08L53/00 , C08F4/654 , C08F297/06 , C08K7/00
摘要： PROBLEM TO BE SOLVED: To provide a propylene-based resin composition excellent in molded appearance, rigidity and impact resistance, and injection moldability, and a molded body. SOLUTION: The resin composition includes a propylene-based block copolymer satisfying [1]-[8], an elastomer, a filler, and a luminous material: [1] having a melt flow rate in a predetermined condition of 5 g/10min to 150 g/10min; [2] composed of a predetermined amount of n-decane-soluble portion (Dsol) and a predetermined amount of n-decane-insoluble portion (Dinsol); [3] having molecular weight distribution of Dsol of 7.0 to 20; [4] having an ethylene content of Dsol of 25 to 45 mol%; [5] having intrinsic viscosity of Dsol of 1.8 to 4.0 dL/g; [6] having molecular weight distribution of Dinsol of 7.0 to 20, and Mz/Mw thereof of 6.0 to 20; [7] having a pentad fraction of Dinsol of 95% or more; and [8] having a predetermined value of a copolymerization index of propylene and ethylene in Dsol. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供成型外观，刚性和耐冲击性以及注射成型性优异的丙烯基树脂组合物和成型体。解决方案：树脂组合物包括满足[1] - [8]的丙烯类嵌段共聚物，弹性体，填料和发光材料：[1]在5g的预定条件下的熔体流动速率 / 10min至150g / 10min; [2]由预定量的正癸烷可溶部分（Dsol）和预定量的正癸烷不溶部分（D insol）构成; [3] Dsol的分子量分布为7.0〜20; [4]具有25〜45摩尔％的Dsol的乙烯含量; [5] Dsol的特性粘度为1.8〜4.0dL / g; [6]具有7.0〜20的Dinsol分子量分布，Mz / Mw为6.0〜20; [7]具有95％以上的Dinsol的五重分数; 和[8]在Dsol中具有丙烯和乙烯的共聚指数的预定值。版权所有（C）2011，JPO＆INPIT

7. 发明专利

JP2006057010A Propylene random copolymer and use thereof 有权
标题翻译：丙烯随机共聚物及其用途
公开(公告)号：JP2006057010A
公开(公告)日：2006-03-02
申请号：JP2004241066
申请日：2004-08-20
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： MATSUMURA HIDEJI , HASHIZUME SATOSHI , SASAKI YOSHIO , HIGUCHI TADASHI , ITAKURA KEITA , NISHIKAWA HIROSHI , KADOSAKA AYAKO
IPC分类号： C08F210/06 , C08F4/64 , C08F4/659 , C08F210/16 , C08J5/18
CPC分类号： C08J5/18 , C08F4/65912 , C08F4/65916 , C08F210/06 , C08F210/16 , C08J2323/14 , Y10S526/943 , Y10T428/2998 , C08F4/65927 , C08F2500/12 , C08F2500/17 , C08F2500/03 , C08F210/08
摘要： PROBLEM TO BE SOLVED: To provide a propylene random copolymer having a low melting point, high molecular weight and low normal decane-soluble content and molded articles such as a film obtained from the copolymer. SOLUTION: The present invention relates to a propylene random copolymer satisfying all of the following requirements [1] to [4] and various useful articles molded from the copolymer: [1] the concentration (Pa, % by mole) of a skeleton constituent (a) derived from propylene in the propylene random copolymer and the concentration (Px, % by mole) of a skeleton constituent derived from at least one olefin selected from among ethylene (b) and 4-20C α-olefins (c) therein satisfy relationships (Eq-1) to (Eq-3); [2] the concentration (Pa, % by mole) of a skeleton constituent (a) derived from propylene in the propylene random copolymer and the melting point (Tm) as determined with a differential scanning colorimeter satisfy relationship (Eq-4); [3] the total content of 2,1- and 1,3-bonded nonstereoregular portions is ≤0.2% by mole and [4] the content of matter soluble in n-decane (nC 10 ) is ≤2.0 wt.%. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供具有低熔点，高分子量和低正癸烷可溶物含量的丙烯无规共聚物以及由共聚物获得的成型制品。解决方案：本发明涉及满足以下所有要求[1]至[4]的所有丙烯无规共聚物和由共聚物模制的各种有用物质：[1] a的浓度（Pa，摩尔％）丙烯无规共聚物中的丙烯衍生的骨架成分（a）和选自乙烯（b）和4-20Cα-烯烃（c）中的至少一种烯烃的骨架成分的浓度（P x，摩尔％），其中满足关系式（Eq-1）至（Eq-3）; [2]丙烯无规共聚物中由丙烯衍生的骨架成分（a）的浓度（Pa，摩尔％）和用差示扫描色度计测定的熔点（Tm）满足关系式（Eq-4）。 [3] 2,1-和1,3-键合的非构造部分的总含量≤0.2摩尔％[4]可溶于正癸烷（nC 10 ）的物质含量为 ≤2.0重量％。版权所有（C）2006，JPO＆NCIPI

8. 发明专利

JP2013136765A Molding 有权
标题翻译：模具
公开(公告)号：JP2013136765A
公开(公告)日：2013-07-11
申请号：JP2013025351
申请日：2013-02-13
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： OKAMOTO KATSUHIKO , MORI RYOJI , NAKAGAWA TAKASHI , DOI YASUSHI , YAMAGUCHI TOSHIHIRO , HIGUCHI TADASHI , ICHIKI YASUO
IPC分类号： C08F10/06 , B32B27/32 , C08J5/00 , D04H1/4291
摘要： PROBLEM TO BE SOLVED: To provide a molding obtained from a syndiotactic propylene polymer and balancedly excellent in heat resistance, transparency, mechanical properties and strength.SOLUTION: The molding contains 90 mol% to 100 mol% of propylene and 0 mol% to 10 mol% of a 2-20C-olefin (except for propylene), and is obtained from a propylenic polymer satisfying the following requirement. [1] The syndiotactic pentad fraction (rrrr fraction) measured byC-NMR is ≥85%. [2] The melting point (Tm) determined by a differential scanning calorimeter (DSC) is ≥156°C, and the heat of fusion (ΔH) is ≥55 mJ/mg. [3] If the isothermal crystallization temperature determined by a differential scanning calorimeter is represented by T, and the semicrystallization time at the isothermal crystallization temperature Tis represented by t, the expression (Eq-1) is satisfied in the range of 110≤T≤150(°C).
摘要翻译：要解决的问题：提供由间同立构丙烯聚合物得到的成型体，其耐热性，透明性，机械性能和强度平衡优异。成型体含有90摩尔％〜100摩尔％丙烯，0摩尔％〜10摩尔％的2-20C-烯烃（丙烯除外），由满足以下要求的丙烯类聚合物得到。 [1]通过C-NMR测定的间同立构五单元组分数（rrrr分数）≥85％。 [2]通过差示扫描量热计（DSC）测定的熔点（Tm）≥156℃，熔解热（＆Dgr; H）≥55mJ/ mg。 [3]如果由差示扫描量热计测定的等温结晶温度由T表示，并且在t表示的等温结晶温度T s下的半结晶时间，则表示式（Eq-1）在110≤T≤ 150（℃）。

9. 发明专利

JP2007023154A Olefin based polymer particle and method for producing olefin based polymer particle 有权
标题翻译：基于OLEFIN的聚合物颗粒和生产基于烯烃的聚合物颗粒的方法
公开(公告)号：JP2007023154A
公开(公告)日：2007-02-01
申请号：JP2005207071
申请日：2005-07-15
申请人： Mitsui Chemicals Inc , Prime Polymer:Kk , 三井化学株式会社 , 株式会社プライムポリマー
发明人： MATSUMURA HIDEJI , ICHIKI YASUO , HIGUCHI TADASHI
IPC分类号： C08F6/12 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide olefin based polymer particles with high stereoregularity, high melting point, high molecular weight and reduced ash content, and to provide a method for producing the same. SOLUTION: The olefin based polymer particles satisfy following requirements at the same time. (1) The polymer has less than 4.0 of molecular weight distribution (Mw/Mn) measured by GPC, (2) The polymer particles have minimum particle diameter of ≥3 μm and average particle diameter of ≥20 μm, (3) The polymer particles have ash contents of ≤2000 wt.ppm, (4) The polymer particles have ≤10 wt.ppm, of Si content and (5) The polymer particles contain a contact product of an aluminoxane and a diol compound. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供具有高立构规整性，高熔点，高分子量和降低的灰分含量的烯烃基聚合物颗粒，并提供其制备方法。解决方案：烯烃基聚合物颗粒同时满足以下要求。（1）聚合物通过GPC测定的分子量分布（Mw / Mn）小于4.0，（2）聚合物粒子的最小粒径≥3μm，平均粒径≥20μm，（3）聚合物颗粒的灰分含量≤2000重量ppm，（4）聚合物颗粒的Si含量≤10重量ppm;（5）聚合物颗粒含有铝氧烷和二醇化合物的接触产物。版权所有（C）2007，JPO＆INPIT

10. 发明专利

JP2006036983A Propylene polymer 审中-公开
标题翻译：丙烯聚合物
公开(公告)号：JP2006036983A
公开(公告)日：2006-02-09
申请号：JP2004220656
申请日：2004-07-28
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： HIGUCHI TADASHI , MATSUMURA HIDEJI , SASAKI YOSHIO , MORITA KIYOMI , HASHIZUME SATOSHI
IPC分类号： C08F10/06
摘要： PROBLEM TO BE SOLVED: To provide an olefin polymer having high stereoregularity and a low molecular weight (high fluidity). SOLUTION: The propylene polymer has an MFR (230°C and 2.16 kg load) of ≥500 g/10 min and a fraction of ≥97.3% regarding the methyl groups configuration, mmmm (dd or ll is indicated by m), of five sequential propylene monomer units, measured by 13 C-NMR. The propylene polymer also has the content of magnesium oxide of ≤12 ppm by weight, measured by an incineration method. COPYRIGHT: (C)2006,JPO&NCIPI

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