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1. 发明专利

JP2013018802A Polyester resin composition, method for producing the same, polyester fiber composed of the same, and fiber product of the polyester fiber 有权
标题翻译：聚酯树脂组合物，其制造方法，由其组合的聚酯纤维和聚酯纤维的纤维产品
公开(公告)号：JP2013018802A
公开(公告)日：2013-01-31
申请号：JP2011150677
申请日：2011-07-07
申请人： Mitsubishi Rayon Textile Co Ltd , 三菱レイヨン・テキスタイル株式会社 , Nippon Ester Co Ltd , 日本エステル株式会社
发明人： IMAKITA JUNYA , SAKURAI YOSHIKI , SEIKO HIROMI , YASUHARA SHIGEFUMI , HIDAKA YASUKI , KITABA YOSHIYUKI
IPC分类号： C08L67/03 , C08G63/82 , C08K3/22 , C08K5/098 , C08K5/521 , D01F6/84 , D01F6/92
摘要： PROBLEM TO BE SOLVED: To provide a polyester resin composition capable of obtaining polyester fiber with high quality such as an excellent color tone and excellent glossiness by taking specific measures in a polymerization process to stabilize operability in a fiber spinning and drawing process and following treatment processes.SOLUTION: In the polyester resin composition, a polyester resin having principal repeating units consisting of ethylene terephthalate includes particles, which are formed of an alkaline earth metal carboxylate and a phosphoric acid ester and have an average particle diameter of 0.01-3 μm, and germanium oxide to satisfy following expressions: (a) 100≤M1≤500; (b) 0.5×M1≤P≤1.5×M1; (c) 20≤G≤150 where M1, P and G respectively represent a content (ppm) of alkaline earth metal atoms, a content (ppm) of phosphorus atoms, and a content (ppm) of germanium atoms for the obtained polyester resin composition.
摘要翻译：解决问题：提供一种通过在聚合过程中采取具体措施来获得纤维纺丝和拉伸过程中的可操作性的稳定性，能够获得高质量的聚酯纤维，例如优异的色调和优异的光泽度的聚酯树脂组合物，以下处理过程。解决方案：在聚酯树脂组合物中，具有由对苯二甲酸乙二醇酯组成的主要重复单元的聚酯树脂包括由碱土金属羧酸盐和磷酸酯形成的平均粒径为0.01-3μm的颗粒和氧化锗以满足以下表达式：（a）100≤M1≤500; （b）0.5×M1≤P≤1.5×M1; （c）20≤G≤150其中M1，P和G分别表示所得聚酯树脂中碱土金属原子的含量（ppm），磷原子的含量（ppm）和锗原子的含量（ppm）组成。版权所有（C）2013，JPO＆INPIT

2. 发明专利

JP2007099792A Polyester and fiber obtained by using the same 审中-公开
标题翻译：使用它的聚酯纤维和纤维
公开(公告)号：JP2007099792A
公开(公告)日：2007-04-19
申请号：JP2005287486
申请日：2005-09-30
申请人： Nippon Ester Co Ltd , 日本エステル株式会社
发明人： YASUHARA SHIGEFUMI
IPC分类号： C08G63/85 , D01F6/62
摘要： PROBLEM TO BE SOLVED: To obtain a polyester that is polymerized even without using an antimony compound as a polycondensation catalyst and provides a polyester fiber having improved color tone and excellent color development, and a polyester fiber. SOLUTION: The polyester comprises mainly an ethylene terephthalate unit as a repeating unit and contains 0.005-1.0 mass% of a titanium oxide particle and 30-300ppm of a magnesium compound coated with a titanium compound and satisfies a formula (1): Y>32X+68 (X is titanium oxide particle content (mass%); Y is polyester color tone L value). COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：为了获得即使不使用锑化合物作为缩聚催化剂而聚合的聚酯，并且提供具有改善的色调和优异显色性的聚酯纤维和聚酯纤维。解决方案：聚酯主要包含对苯二甲酸乙二醇酯单元作为重复单元，并且含有0.005-1.0质量％的氧化钛颗粒和30-300ppm的涂覆有钛化合物的镁化合物，并且满足式（1）： Y> 32X + 68（X是氧化钛颗粒含量（质量％）; Y是聚酯色调L值）。版权所有（C）2007，JPO＆INPIT

3. 发明专利

JP2006037014A Coating composition 审中-公开
标题翻译：涂料组合物
公开(公告)号：JP2006037014A
公开(公告)日：2006-02-09
申请号：JP2004221944
申请日：2004-07-29
申请人： Nippon Ester Co Ltd , 日本エステル株式会社
发明人： YASUHARA SHIGEFUMI
IPC分类号： C09D167/02
摘要： PROBLEM TO BE SOLVED: To provide a coating composition for coating metal can for food and beverage, and provide a coating film having excellent processability, adhesiveness, retort resistance, and flavored properties.
SOLUTION: The coating composition comprises two kinds of polyester resins (A) and (B), in which the polyester resins (A) is composed of 80-100 mol% aromatic dicarboxylic acid component as the dicarboxylic acid component and 40-90 mol% 2-methyl-1,3-propanediol and 10-60 mol% 1,2-propanediol as the glycol component and has ≥0.45 of limiting viscosity and ≥50°C of glass transition temperature, and the polyester resins (B) is composed of 60-100 mol% aromatic dicarboxylic acid component as the dicarboxylic acid component and 50-100 mol% aliphatic glycol having a side chain as the glycol component and has ≥0.60 of limiting viscosity number and less than 20°C of glass transition temperature, and the mixed ratio of the polyester resins (A) to (B) by mass may be (A)/(B)=90-50/10-50.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种用于食品和饮料的金属罐涂覆用涂料组合物，并提供具有优异的加工性，粘合性，耐蒸煮性和调味性的涂膜。溶液：涂料组合物包含两种聚酯树脂（A）和（B），其中聚酯树脂（A）由80-100mol％的芳族二羧酸组分作为二羧酸组分和40- 90摩尔％2-甲基-1,3-丙二醇和10-60摩尔％1,2-丙二醇作为二醇成分，特性粘度≥0.45，玻璃化转变温度≥50℃，聚酯树脂（B ）由作为二羧酸成分的60〜100摩尔％的芳族二羧酸成分和作为二元醇成分的侧链的50〜100摩尔脂肪族二醇组成，特性粘度数≥0.60，玻璃的小于20℃ 转化温度，聚酯树脂（A）与（B）的混合比例可以为（A）/（B）= 90〜50/10〜50。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2006037013A Method for producing polyester resin, polyester resin for adhesive given by using the same, adhesive, and laminated product 审中-公开
标题翻译：用于生产聚酯树脂的方法，使用它们的胶粘剂的聚酯树脂，粘合和层压产品
公开(公告)号：JP2006037013A
公开(公告)日：2006-02-09
申请号：JP2004221943
申请日：2004-07-29
申请人： Nippon Ester Co Ltd , 日本エステル株式会社
发明人： YASUHARA SHIGEFUMI
IPC分类号： C08G63/66 , B32B15/09 , C09J167/02
摘要： PROBLEM TO BE SOLVED: To provide a polyester resin for an adhesive, excellent in heat resistance, resistance to moisture heat, and transparency, and to provide a method for producing the same.
SOLUTION: In this method for producing the polyester resin from a dicarboxylic acid and a glycol through processes of esterification reaction and polycondensation reaction, the esterification reaction or the polycondensation reaction is conducted so that a polyalkylene glycol ether having a molecular weight of ≥1500 and a number of carbon atoms in a repeating unit of ≥3 is added as a glycol component in such an amount that the obtained polyester resin contains the polyalkylene glycol ether in an amount of 1-10 mol% based on the total glycol component and a mol ratio of the glycol component to a carboxylic acid component is made to be 1.8 or more. The polyester resin for the adhesive is obtained by the method. Further, the adhesive and a laminated product are obtained, respectively.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种用于粘合剂的聚酯树脂，耐热性，耐湿热性和透明性优异，并提供其制造方法。解决方案：在通过酯化反应和缩聚反应的方法由二羧酸和二醇生产聚酯树脂的方法中，进行酯化反应或缩聚反应，使得分子量≥ 1500，重复单位≥3的碳原子数为二醇成分，其量使得所得聚酯树脂含有相对于总二醇成分为1-10摩尔％的聚亚烷基二醇醚，二醇成分与羧酸成分的摩尔比为1.8以上。通过该方法获得粘合剂用聚酯树脂。此外，分别获得粘合剂和层压产品。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2005220310A Polyester resin for adhesive, adhesive and laminate using the same 审中-公开
标题翻译：用于粘合，粘合和层压的聚酯树脂
公开(公告)号：JP2005220310A
公开(公告)日：2005-08-18
申请号：JP2004032070
申请日：2004-02-09
申请人： Nippon Ester Co Ltd , 日本エステル株式会社
发明人： YASUHARA SHIGEFUMI
IPC分类号： B32B15/09 , B32B15/08 , C08G63/12 , C09J167/02
摘要： PROBLEM TO BE SOLVED: To provide a polyester resin for an adhesive excellent in heat resistance and moist heat resistance.
SOLUTION: This polyester resin for the adhesive consists of 50-100 mol % aromatic dicarboxylic acid as a dicarboxylic acid component constituting the polyester resin, 1-15 mol % polypropylene glycol having ≥50 % rate of primary form of terminal hydroxy groups and 50-99 mol % 2-5C alkylene glycol other than the polypropylene glycol as a glycol component, and has 0-40°C glass transition temperature, 60-120°C softening temperature and ≥0.60 intrinsic viscosity.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供耐热性和耐湿热性优异的粘合剂用聚酯树脂。解决方案：该粘合剂用聚酯树脂由构成聚酯树脂的二羧酸成分的50-100摩尔％芳族二羧酸组成，具有≥50％初始形式的末端羟基的1-15摩尔％聚丙二醇和作为二醇成分的聚丙二醇以外的50-99摩尔％的2-5C亚烷基二醇，具有0-40℃玻璃化转变温度，60-120℃软化温度和≥0.60特性粘度。版权所有（C）2005，JPO＆NCIPI

6. 发明专利

JP2004161890A Polyester resin for adhesive, adhesive, and laminated body 审中-公开
公开(公告)号：JP2004161890A
公开(公告)日：2004-06-10
申请号：JP2002329576
申请日：2002-11-13
申请人： Nippon Ester Co Ltd , 日本エステル株式会社
发明人： YASUHARA SHIGEFUMI
IPC分类号： C08G63/692 , C09J167/02 , H01B7/08
摘要： PROBLEM TO BE SOLVED: To provide a polyester resin for adhesives that solves the problems inherent in flame resistant polyester adhesives, particularly has excellent heat resistance, wet heat resistance and adhesivity with metals and a reduced load on the environment.
SOLUTION: The polyester resin for adhesives is a copolyester comprising one or more kinds of dicarboxylic acid components and one or more kinds of glycol components. At least one kind of the glycol components is a polytetramethyleneoxide glycol with a molecular weight of ≥ 500 or a polyalkyleneoxide adduct of a bisphenol compound. The polyester resin has a glass transition temperature of -30 to 40°C and contains a specific organophosphrous compound in an amount corresponding to 5,000-50,000 ppm of phosphor atoms, a hindered phenolic compound and a sulfur compound. The adhesive and the laminate using the polyester resin are presented.
COPYRIGHT: (C)2004,JPO

7. 发明专利

JP2007246814A Polyester resin and fiber comprising the same 审中-公开
标题翻译：聚酯树脂和包含该树脂的纤维
公开(公告)号：JP2007246814A
公开(公告)日：2007-09-27
申请号：JP2006074600
申请日：2006-03-17
申请人： Nippon Ester Co Ltd , 日本エステル株式会社
发明人： YASUHARA SHIGEFUMI
IPC分类号： C08L67/03 , C08G63/85 , D01F6/62
摘要： PROBLEM TO BE SOLVED: To provide a polyester resin, which can be prepared by the polymerization without using an antimony compound as a polymerization condensation catalyst, and from which a polyester fiber having fine color tone and excellent chromogenic characteristics can be formed; and also to provide a polyester fiber. SOLUTION: The polyester resin comprises an ethylene terephthalate unit as a repeating unit constituting the polyester, 0.005-1.0 mass% of titanium oxide particles, and 30-200 ppm of a compound which is a solid solution consisting of an aluminum compound and a magnesium compound with a surface having a coating layer comprising titanic acid. The polyester resin satisfies formula (1), Y>32X+68, where X is the amount of titanium oxide particles contained (mass%); and Y is a color tone value L. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供可以通过聚合制备而不使用锑化合物作为聚合缩合催化剂的聚酯树脂，并且可以形成具有优良色调和优异显色特性的聚酯纤维; 并提供聚酯纤维。解决方案：聚酯树脂包括作为构成聚酯的重复单元的对苯二甲酸乙二醇酯单元，0.005-1.0质量％的氧化钛颗粒和30-200ppm的由铝化合物和具有表面的镁化合物具有包含钛酸的涂层。聚酯树脂满足式（1），Y> 32X + 68，其中X是包含的氧化钛颗粒的量（质量％）; Y是色调色调值L.版权所有（C）2007，JPO＆INPIT

8. 发明专利

JP2006182983A Production method for coating polyester resin, and coating polyester resin 有权
标题翻译：涂料聚酯树脂和涂料聚酯树脂的生产方法
公开(公告)号：JP2006182983A
公开(公告)日：2006-07-13
申请号：JP2004380485
申请日：2004-12-28
申请人： Nippon Ester Co Ltd , 日本エステル株式会社
发明人： YASUHARA SHIGEFUMI , TANEDA YUJI
IPC分类号： C08G63/78 , C09D167/00
摘要： PROBLEM TO BE SOLVED: To provide a production method for a coating polyester resin which method can stably produce a high acid value polyester resin without causing gelation; a coating resin composition which is especially excellent in adhesion to a metal surface and has high-degree processability and satisfactory corrosion resistance; and a coated metal plate.
SOLUTION: The production method of a coating polyester resin comprises polycondensation of a dicarboxylic acid and/or its derivative with a diol and/or its derivative and depolymerization by the addition of a compound of which each of at least four adjacent carbon atoms has a carboxyl group. The coating polyester resin produced by the method is provided. The coating resin composition is prepared by compounding the coating polyester resin with a curing agent. The coated metal plate is prepared by coating a metal plate with the coating resin composition.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：提供一种可以稳定地生产高酸值聚酯树脂而不引起凝胶化的涂料聚酯树脂的制备方法; 特别是对金属表面的附着力优异且加工性好，耐腐蚀性良好的涂料树脂组合物; 和镀金属板。解决方案：涂料聚酯树脂的制备方法包括二羧酸和/或其衍生物与二醇和/或其衍生物的缩聚和通过加入其中至少四个相邻碳原子的化合物进行解聚具有羧基。提供通过该方法制备的涂料聚酯树脂。通过将涂布聚酯树脂与固化剂混合来制备涂料树脂组合物。通过用涂覆树脂组合物涂覆金属板来制备涂覆的金属板。版权所有（C）2006，JPO＆NCIPI

9. 发明专利

JP2006037015A Polyester resin for powder coating material, composition, and powder coating obtained by using the same 审中-公开
标题翻译：用于粉末涂料的组合物，组合物和粉末涂料的聚酯树脂
公开(公告)号：JP2006037015A
公开(公告)日：2006-02-09
申请号：JP2004221945
申请日：2004-07-29
申请人： Nippon Ester Co Ltd , 日本エステル株式会社
发明人： SATO YASUHISA , YASUHARA SHIGEFUMI
IPC分类号： C08G63/88 , C09D5/03 , C09D167/02
摘要： PROBLEM TO BE SOLVED: To obtain a polyester resin and a polyester resin composition for a powder coating material, capable of being formed into the powder coating material which gives excellent weather resistance and smoothness to a film and has excellent curability at a low temperature, and to provide the powder coating material obtained by using the same.
SOLUTION: The polyester resin for the powder coating material is formed by depolymerizing a polyester resin which is composed of main constituents comprising isophthalic acid as an acid component and neopentyl glycol as a glycol component with isophthalic acid and/or a small amount of an aromatic tricarboxylic acid anhydride, wherein the polyester resin contains the isophthalic acid and the neopentyl glycol in an amount of 80-100 mol% in total based on the amount of total components and has an acid value of 20-50 mgKOH/g and a melt viscosity at 160°C of 100-800 dPas.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：为了获得能够形成粉末涂料的聚酯树脂和聚酯树脂组合物，其对薄膜具有优异的耐候性和平滑性，并且在低温下具有优异的固化性温度，并提供通过使用它得到的粉末涂料。解决方案：用于粉末涂料的聚酯树脂通过使由间苯二甲酸作为酸成分的主要成分和作为二醇成分的新戊二醇由间苯二甲酸和/或少量的芳族三羧酸酐，其中聚酯树脂含有基于总组分量的总共80-100摩尔％的间苯二甲酸和新戊二醇，并且酸值为20-50mgKOH / g，和在160℃下的熔融粘度为100-800dPas。版权所有（C）2006，JPO＆NCIPI

10. 发明专利

JP2004250484A Polyester resin for adhesive, adhesive, and laminate 审中-公开
公开(公告)号：JP2004250484A
公开(公告)日：2004-09-09
申请号：JP2003039730
申请日：2003-02-18
申请人： Nippon Ester Co Ltd , 日本エステル株式会社
发明人： YASUHARA SHIGEFUMI
IPC分类号： B32B15/09 , B32B15/08 , C08G63/181 , C09J167/02 , H01B7/08
摘要： PROBLEM TO BE SOLVED: To obtain a polyester resin for an adhesive which solves various problems of a polyester adhesive, excels particularly in wet heat resistance, adhesion to a metal, and blocking resistance, and improves the productivity in producing laminates. SOLUTION: The polyester resin is prepared from a dicarboxylic acid component containing 50-100 mol.% aromatic dicarboxylic acid and a glycol component containing 50-90 mol.% 1,2-propylene glycol and 1-15 mol.% tetramethtylene glycol and has an intrinsic viscosity of ≥0.4. An adhesive comprising the polyester resin is provided, which is used for forming a laminate of a PET (polyethylene telephthalate) film or sheet and a metal plate. COPYRIGHT: (C)2004,JPO&NCIPI

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