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    • 1. 发明专利
    • Resin composition for plastic coating material, plastic coating material, and its laminate
    • 塑料涂料用树脂组合物,塑料涂料及其复合材料
    • JP2008291191A
    • 2008-12-04
    • JP2007140963
    • 2007-05-28
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • URA MASATOSHIKOSUGI NAOHIROTAKAGI TAMAEIMABAYASHI NOBORU
    • C09D133/06B32B27/00B32B27/30C09D101/14C09D125/00C09D143/04C09D183/10
    • PROBLEM TO BE SOLVED: To provide a resin composition for a plastic coating material exhibiting good adhesiveness with plastic and excellent compatibility with a coating material blending additive and forming a coating excellent in gloss, smoothness, non-adhesiveness, and alcohol resistance when it is applied to a base material. SOLUTION: The resin composition for a plastic coating material contains 10-50 mass% of a polymer A, which is obtained by polymerizing 20-100 mass% of at least one kind of monomer (a1) selected from an aromatic vinyl monomer and a polymerizable unsaturated monomer having a cycloalkyl group and 0-80 mass% of another copolymerizable unsaturated monomer (a2), and 50-90 mass% of a polymer B, which is obtained by polymerizing 50-100 mass% of alkyl (meth)acrylate (b1) having a 1-4C alkyl group, 0-20 mass% of at least one kind of monomer (b2) selected from an aromatic vinyl monomer and a polymerizable unsaturated monomer having a cycloalkyl group, and 0-50 mass% of another copolymerizable unsaturated monomer (b3). COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种与塑料表现出良好粘合性的塑料涂料的树脂组合物,并且与涂料混合添加剂具有优异的相容性,并形成光泽,光滑度,非粘合性和耐醇性优异的涂层 它被应用于基材。 解决方案:塑料涂料用树脂组合物含有10-50质量%的聚合物A,其通过聚合20-100质量%的至少一种选自芳族乙烯基单体(a1)的单体 和具有环烷基的聚合性不饱和单体和其它可共聚的不饱和单体(a2)的0〜80质量%的聚合性不饱和单体和50〜100质量%的(甲基) 具有1-4C烷基的丙烯酸酯(b1),0-20质量%的选自芳族乙烯基单体和具有环烷基的可聚合不饱和单体的至少一种单体(b2)和0-50质量% 另一种可共聚的不饱和单体(b3)。 版权所有(C)2009,JPO&INPIT
    • 2. 发明专利
    • Resin composition, method for producing the same, coating composition and laminate
    • 树脂组合物,其制造方法,涂料组合物和层压材料
    • JP2009269975A
    • 2009-11-19
    • JP2008120385
    • 2008-05-02
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • URA MASATOSHIIMABAYASHI NOBORU
    • C08F255/00C08F2/44C09D4/02C09D7/12C09D123/28C09D147/00
    • PROBLEM TO BE SOLVED: To provide a resin composition which can form a film excellent in coating film performances such as adhesive property and cosmetic contamination resistance on a plastic base without requiring a step such as pretreatment or primer coating, and which has excellent storage stability though an aromatic organic solvent is not contained, a method for producing the resin composition, a coating composition containing the resin composition, and a laminate obtained using the coating composition.
      SOLUTION: The method for producing the resin composition includes a step 1 of preparing a uniform solution by adding to an organic solvent a chlorinated polyolefin (A) and 40-280 pts.mass, based on 100 pts.mass of the chlorinated polyolefin (A), of an unsaturated monomer (B) represented by formula (b1) (wherein R
      1 represents H or methyl; and R
      2 represents methyl or ethyl) and dissolving the chlorinated polyolefin (A), and a step 2 of adding the unsaturated monomer (B) and/or an unsaturated monomer (C) and a radical polymerization initiator (D) to the solution and carrying out polymerization.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种树脂组合物,其可以在不需要预处理或底漆涂布的步骤的情况下,在塑料基材上形成涂膜性能如粘合性能和耐化妆品污染性优异的膜,并且具有优异的 不含芳香族有机溶剂的保存稳定性,树脂组合物的制造方法,含有树脂组合物的涂料组合物和使用该涂料组合物得到的层压体。 解决方案:用于制备树脂组合物的方法包括步骤1,其通过向有机溶剂中加入氯化聚烯烃(A)和40-280重量份,基于100重量份的氯化物 由式(b1)表示的不饱和单体(B)的聚烯烃(A)(其中R SP 1表示H或甲基; R SP 2表示甲基或乙基),和 溶解氯化聚烯烃(A)和将不饱和单体(B)和/或不饱和单体(C)和自由基聚合引发剂(D)加入到溶液中并进行聚合的步骤2。 版权所有(C)2010,JPO&INPIT
    • 3. 发明专利
    • Resin composition and method for producing the same, coating composition and laminate
    • 树脂组合物及其制造方法,涂料组合物和层压材料
    • JP2009298944A
    • 2009-12-24
    • JP2008155908
    • 2008-06-13
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • URA MASATOSHIIMABAYASHI NOBORU
    • C08F255/00B32B27/32C08F2/44C09D123/34C09D151/06
    • PROBLEM TO BE SOLVED: To provide a resin composition which can form a coated film, on a plastic substrate, excellent in coated film performance such as adherability and resistance to staining by cosmetic, and has excellent storage stability even not containing an aromatic organic solvent; its production method; a coating composition containing the resin composition; and a laminate obtained by using the coating composition.
      SOLUTION: The method for producing the resin composition includes a process 1 for polymerizing a monomer (B) having two or more polymerizable unsaturated double bonds by using a radical polymerization initiator (C1) in an organic solvent in which a chlorinated polyolefin (A) and the monomer (B) are dissolved; and a process 2 for adding another monomer (D) and a radical polymerization initiator (C2) to the solution obtained in the process 1, and polymerizing the other monomer (D).
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供一种能够形成涂膜的树脂组合物,在塑料基材上,涂膜性能如粘合性和耐化妆品的抗性优异,并且具有优异的储存稳定性,甚至不含芳香族 有机溶剂; 其生产方式; 含有该树脂组合物的涂料组合物; 和通过使用该涂料组合物获得的层压体。 解决方案:用于制备树脂组合物的方法包括:在有机溶剂中使用自由基聚合引发剂(C1)使具有两个或多个可聚合不饱和双键的单体(B)聚合的方法1,其中氯化聚烯烃 A)和单体(B)溶解; 以及将其它单体(D)和自由基聚合引发剂(C2)添加到工序1中得到的溶液,聚合其它单体(D)的工序2。 版权所有(C)2010,JPO&INPIT
    • 4. 发明专利
    • Resin composition for plastic coating, coating for plastic and laminate body thereof
    • 用于塑料涂料的树脂组合物,其用于塑料和层压体的涂料
    • JP2014055300A
    • 2014-03-27
    • JP2013220390
    • 2013-10-23
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • URA MASATOSHIKOSUGI NAOHIROTAKAGI TAMAEIMABAYASHI NOBORU
    • C09D133/06B32B27/00C09D101/14C09D125/00
    • PROBLEM TO BE SOLVED: To provide a coating resin composition good in compatibility with additives for coating composition and which a coated film obtained by coating on a base material is excellent in glossiness, smoothness, non adhesive property and alcohol resistance.SOLUTION: A resin composition for coating contains 10 to 50 mass% of (A) a polymer obtained by polymerizing 20 to 100 mass% of an aromatic vinyl monomer (a1) and 0 to 80 mass% of another copolymerizable unsaturated monomer (a2) and having a weight average molecular weight of 500 to 3500, and 50 to 90 mass% of (B) a polymer obtained by copolymerizing 50 to 100 mass% of alkyl (meth)acrylate having an alkyl group having 1 to 4 carbon atoms (b1), 50 to 100 mass% of at least one kind of monomer (b2) selected from an aromatic vinyl polymer and one kind of polymerizable unsaturated monomers selected from cyclohexyl (meth)acrylate, methylcyclohexyl (meth)acrylate and the like, and 0 to 50 mass% of another copolymerizable unsaturated monomer (b3) and having the weight average molecular weight of 20000 to 20000.
    • 要解决的问题:提供与涂料组合物添加剂相容性良好的涂料树脂组合物,并且通过在基材上涂布得到的涂膜具有优异的光泽度,光滑度,非粘合性和耐醇性。溶解性:树脂组合物 涂布含有10〜50质量%的(A)通过将20〜100质量%的芳香族乙烯基单体(a1)和0〜80质量%的其他可共聚的不饱和单体(a2)聚合而得到的聚合物,其重均分子量 (B)通过共聚合50〜100质量%的具有碳原子数1〜4的烷基(b1)的(甲基)丙烯酸烷基酯(b1)得到的聚合物的50〜90质量% 至少一种选自芳族乙烯基聚合物和选自(甲基)丙烯酸环己酯,(甲基)丙烯酸甲基环己酯等)的一种可聚合不饱和单体和至少一种选自芳族乙烯基聚合物的单体(b2)和0〜50质量% unsatur (b3),重均分子量为20000〜20000。
    • 5. 发明专利
    • Production of polyester
    • 生产聚酯
    • JPS6134022A
    • 1986-02-18
    • JP15541184
    • 1984-07-27
    • Mitsubishi Rayon Co Ltd
    • ISHII KIMIYOSHIKOBAYASHI YUKIOIMABAYASHI NOBORUSEIKO HIROMI
    • C08G63/00C08G63/181C08G63/46C08G63/68C08G63/688
    • PURPOSE: To obtain a polyester which can be dyed with a basic or disperse dye at normal temperature and has excellent fastness to light, by reacting specified compounds including 5-sodiosulfoisophthalic acid and adipic acid with each other at a specified reactant ratio in specified order.
      CONSTITUTION: In synthesizing a polyester from a dicarboxylic acid component comprising terephthalic acid (TPA), 5-sodiosulfoisophthalic acid (NSIPA) and adipic acid (AA) and a diol component mainly comprises ethylene glycol (EG), the polycondensation is performed as follows: (a) the amount of NSIPA component is 2W3mol%, based on the total dicarboxylic acid component, and the amount of AA component is 3W6mol%, on the same base, (b) NSIPA component is added in the form of a dimethyl ester before the start of ester interchange and (c) AA component as a product prepared by reacting by heating an EG/AA mixture at a molar ratio of 3.5W5 and having a degree of esterification ≥90%, and a conversion of AA into adipate ≥80% is added after completion of the ester interchange and before the molar ratio EG/(TPA+NSIPA) reaches 1.1.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过使特定的化合物(包括5-亚硫基间苯二甲酸和己二酸)以规定的反应物比例以规定的顺序反应,得到在常温下可用碱性或分散染料染色并具有优异的耐光性的聚酯。 构成:在由对苯二甲酸(TPA),5-硫代磺基间苯二甲酸(NSIPA)和己二酸(AA)和二醇成分的二羧酸成分合成聚酯中,主要包括乙二醇(EG),缩聚如下进行: (a)基于总二羧酸成分,NSIPA成分的量为2-3mol%,AA成分的量在3-6mol%的同一基础上,(b)NSIPA成分以 在酯交换开始之前的二甲酯和(c)作为产物制备的AA成分,其通过以3.5-5的摩尔比加热EG / AA混合物并且酯化度> = 90%,并且转化率 在酯交换完成后,在EG /(TPA + NSIPA)摩尔比达到1.1之前加入AA至己二酸酯= 80%。