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    • 4. 发明专利
    • Preventive method for warpage of indium phosphide wafer
    • 预防磷化氢波形的预防方法
    • JPS5934637A
    • 1984-02-25
    • JP14438982
    • 1982-08-20
    • Mitsubishi Metal Corp
    • MIYAIRI HIROOTAKAHASHI AKIOKISHIMOTO MIKIO
    • C23F1/30H01L21/02H01L21/306
    • H01L21/306
    • PURPOSE:To reduce th warpage by removing a surface damage layer through etching prior to mirror polishing regarding the wafer after cutting. CONSTITUTION:A crystal of indium phosphide after cutting is etched by using an etchent of a nitric acid-hydrochloric acid group solution or a 3% bromine- methanol solution in order to remove the surface damage layer on cutting prior to the mirror polishing of the indium phosphide wafer. A ratio of water : nitric acid : hydrochloric acid is kept within a range of 12:7:1-3:1:1 in the nitric acid- hydrochloric acid group solution, a range of a heating temperature is kept at 70- 80 deg.C and etching time is kept for 5-7min as the conditions of the etchent, and the crystal is etched with extremely excellent uniformity. When hydrochloric acid is used in quantity more than said ratio or more to nitric acid, a phosphorus element starts its decomposition at approximately 50 deg.C. Etching is too strong on heating when a ratio of nitric acid is high, and in that case, an etching rate is difficult to be controlled.
    • 目的:通过在切割之后的晶片抛光之前通过蚀刻去除表面损伤层来减少翘曲。 构成:通过使用硝酸 - 盐酸组溶液或3%溴 - 甲醇溶液等来蚀刻切割后的磷化铟晶体,以便在对铟进行镜面抛光之前去除切割时的表面损伤层 磷化晶片。 在硝酸 - 盐酸溶液中,水:硝酸:盐酸的比例保持在12:7:1-3:1:1的范围内,加热温度范围保持在70-80度 蚀刻时间保持为5-7分钟,作为等离子体的条件,并且以非常优异的均匀性蚀刻晶体。 当盐酸的使用量超过硝酸比例时,磷元素在约50℃开始分解。 当硝酸的比例高时,在加热时蚀刻过强,在这种情况下,难以控制蚀刻速率。