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1. 发明专利

JP2004107537A Polypropylene-based coated molded product 有权
公开(公告)号：JP2004107537A
公开(公告)日：2004-04-08
申请号：JP2002273941
申请日：2002-09-19
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： ONOE MASATO , ASHIHARA TERUAKI , HATA KAZUYUKI , SHIMIZU FUMIHIKO , ZANKA YUKITO , NAKAYAMA KOICHI
IPC分类号： B05D7/02 , B05D7/24 , C08J7/04 , C08K3/04 , C08L23/10 , C09D123/26 , C09D151/06
摘要： PROBLEM TO BE SOLVED: To provide a polypropylene-based coated molded product by coating a crystalline polypropylene molded product containing an electroconductive carbon with a coating component containing a polar group-containing propylene-based polymer. SOLUTION: The polypropylene-based coated molded product is obtained by applying (A) the coating component comprising a polar group-containing propylene-based polymer composed of a main chain composed of the propylene-based polymer having characteristics: (1) a polymer produced by a single site catalyst and (2) ≤1 wt.% insoluble matter when dissolved in a concentration of 10 wt.% in heptane at 98°C and a side chain containing a carboxylic group, a carboxylic acid anhydride group or a carboxylic acid ester group to (B) the base material which is a molded product of a resin composition composed of a crystalline polypropylene and an electroconductive carbon and having ≥30% surface glossiness. The polypropylene-based coated molded product is excellent in adhesion of coated film and balance of physical properties such as rigidity and impact resistance and has high glossiness and conductivity. COPYRIGHT: (C)2004,JPO

2. 发明专利

JP2004025769A Water-resisting agent for inkjet recording material 审中-公开
公开(公告)号：JP2004025769A
公开(公告)日：2004-01-29
申请号：JP2002189039
申请日：2002-06-28
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： FUJIMORI NAOMI , HATA KAZUYUKI
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52 , C08F216/14 , C08F220/10 , C08F220/56 , C08F226/02
摘要： PROBLEM TO BE SOLVED: To provide a water-resisting agent which can increase light fastness without reducing a recording density, coloring property and water-resistance of an inkjet recording material, and the inkjet recording material including the water-resisting agent.
SOLUTION: This water-resisting agent for an inkjet recording material contains a cationic polymer. In this case, the cationic polymer has (a) a monomer unit having a plurality of cationic groups, and (b) a monomer unit having an ultraviolet absorbing structure and/or a monomer unit having a light stability structure as the constituent units.
COPYRIGHT: (C)2004,JPO

3. 发明专利

JP2005060713A Active energy radiation-curable adhesive composition 审中-公开
标题翻译：活性能量辐射可固化粘合剂组合物
公开(公告)号：JP2005060713A
公开(公告)日：2005-03-10
申请号：JP2004298994
申请日：2004-10-13
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： HATA KAZUYUKI , YAMADA KATSUHIKO
IPC分类号： C08F290/06
摘要： PROBLEM TO BE SOLVED: To provide an active energy radiation-curing adhesive composition which yields a coating film showing a good adhesion even to a polyolefin.
SOLUTION: The composition comprises a methacrylic resin and a reaction product of an isocyanate compound having an isocyanate group bonded to a non-aromatic hydrocarbon ring and a (meth)acrylic compound. The isocyanate compound is a trimer of isophorone diisocyanate or its reaction product with an active hydrogen-containing compound. The (meth)acrylic compound has a (meth)acryloyl group and is reactive with an isocyanate group.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种活性能量辐射固化粘合剂组合物，其产生即使对于聚烯烃也显示出良好的附着力的涂膜。解决方案：组合物包含甲基丙烯酸树脂和具有与非芳族烃环键合的异氰酸酯基的异氰酸酯化合物与（甲基）丙烯酸化合物的反应产物。异氰酸酯化合物是异佛尔酮二异氰酸酯的三聚物或其与含活性氢的化合物的反应产物。（甲基）丙烯酸化合物具有（甲基）丙烯酰基，与异氰酸酯基反应。版权所有（C）2005，JPO＆NCIPI

4. 发明专利

JP2004115712A Polypropylene-based composite composition of aqueous emulsion 有权
公开(公告)号：JP2004115712A
公开(公告)日：2004-04-15
申请号：JP2002283376
申请日：2002-09-27
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： ASHIHARA TERUAKI , HATA KAZUYUKI
IPC分类号： C08L53/00 , C08K5/00 , C08L23/10 , C08L23/26 , C08L101/00 , C09D5/02 , C09D11/00 , C09D123/10 , C09D123/14 , C09D123/16 , C09D123/20 , C09D123/26 , C09D133/00 , C09D151/06 , C09D163/00 , C09D171/00 , C09D175/04 , C09J123/10 , C09J123/14 , C09J123/16 , C09J123/20 , C09J123/26 , C09J133/00 , C09J151/06 , C09J163/00 , C09J171/00 , C09J175/04
摘要： PROBLEM TO BE SOLVED: To provide a polypropylene-based composite composition of an aqueous emulsion that has good dispersion stability and is excellent in smoothness of a coating film and adhesion to a substrate and that is capable for forming a coating film good in water resistance/gasohol resistance on a polyolefin base material. SOLUTION: The composite composition of the aqueous emulsion comprises an aqueous dispersion comprising components (a)-(d) and if required, a component (e) as follows: the component (a) is 100 pts.wt. propylene-based polymer and/or modified propylene-based polymer each having an average particle diameter as dispersed particles of 0.5 μm or less and having a stereoblock structure; the component (b) is 1-5,000 pts.wt. polymers other than the propylene-based polymer and the modified propylene-based polymer; the component (c) is 1-100 pts.wt. total of two or more kinds of nonionic surfactants; the component (d) is 100-1,000 pts.wt. water; and the component (e) is 0.01-100 pts.wt. basic substance. COPYRIGHT: (C)2004,JPO

5. 发明专利

JP2004083686A Polypropylene-based coated molded form 有权
公开(公告)号：JP2004083686A
公开(公告)日：2004-03-18
申请号：JP2002244666
申请日：2002-08-26
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： ONOE MASATO , ASHIHARA TERUAKI , HATA KAZUYUKI , SHIMIZU FUMIHIKO , ZANKA YUKITO
IPC分类号： C08J7/04 , C08K3/00 , C08K7/02 , C08L23/08 , C08L23/10 , C08L25/00 , C08L53/00 , C08L101/00 , C09D123/26 , C09D151/06
摘要： PROBLEM TO BE SOLVED: To provide a polypropylene-based coated molded form obtained by coating an elastomer-containing crystalline polypropylene molded form with a coating component comprising a polar group-containing propylene-based polymer. SOLUTION: The propylene-based coated molded form is obtained by coating a substrate(B) with a coating component(A). In this molded form, the coating component(A) comprises the polar group-containing propylene-based polymer composed of the main chain consisting of a propylene-based polymer having the characteristics(1) and (2) described below and side chains containing carboxy groups, carboxylic anhydride groups or carboxylic ester groups: (1) produced using a single-site catalyst and (2) ≤1 wt.% in insolubles when dissolved at 10 wt.% concentration in heptane at 98°C; and the substrate(B) is a molded form of a resin composition comprising a crystalline polypropylene and an elastomer component. COPYRIGHT: (C)2004,JPO

6. 发明专利

JP2004002842A Polypropylene-based aqueous dispersion 有权
公开(公告)号：JP2004002842A
公开(公告)日：2004-01-08
申请号：JP2003122184
申请日：2003-04-25
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： ASHIHARA TERUAKI , ONOE MASATO , HATA KAZUYUKI , SHIMIZU FUMIHIKO , SATO NAOMASA
IPC分类号： C08L23/10 , C08F10/06 , C08K5/00 , C08L23/26
摘要： PROBLEM TO BE SOLVED: To provide a polypropylene-based aqueous dispersion having a small particle diameter and good dispersion stability and capable of forming such a coating on a polyolefin base material as to have good smoothness, adhesion, and water resistance. SOLUTION: This polypropylene-based aqueous dispersion contains (a) a polypropylene-based polymer and/or a modified polypropylene-based polymer in an amount of 100 pts.wt., (b) a surfactant in an amount of 1-100 pts.wt., and (c) water in an amount of 100-1000 pts.wt., wherein main chains of the the component (a) has the following characteristics (1): S 1 /S is in a range of 10-60 % and (4+2S 1 /S 2 ) > 5 (S is a total area of a peak appearing in a range of 18.9-22.1 ppm, when a peak brought about by a carbon atom of a methyl in a chain part of a head-tail bonding propylene unit is measured by 13 C-NMR and a chemical shift of the peak top of a peak attributed to a pentad expressed by mmmm is defined as 21.8 ppm; S 1 is an area of a peak of which the peak top appears at 21.8 ppm; and S 2 is an area of a peak (mmmr) of which the peak top appears at 21.5-21.6 ppm) and (2): a molar ratio of the component (a) to the component (b) is in the range of 100:0 to 90:10, and dispersed particles of the dispersion have an average particle diameter of ≤0.5 μm. COPYRIGHT: (C)2004,JPO

7. 发明专利

JP2004107539A Polypropylene-based resin coated molded product 审中-公开
公开(公告)号：JP2004107539A
公开(公告)日：2004-04-08
申请号：JP2002273972
申请日：2002-09-19
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： ONOE MASATO , ASHIHARA TERUAKI , HATA KAZUYUKI , SHIMIZU FUMIHIKO , ZANKA YUKITO , NAKAYAMA KOICHI
IPC分类号： C08J7/04 , C08K3/04 , C08L23/12 , C09D5/00 , C09D7/12 , C09D123/10 , C09D123/26
摘要： PROBLEM TO BE SOLVED: To provide a polypropylene-based resin coated molded product by using a polypropylene-based water-based dispersion excellent in dispersion stability and capable of forming a coated film excellent in water resistance and adhesion to a polypropylene base material comprising an electroconductive carbon as a coating component and applying the coating component to a molded product of the base material. SOLUTION: The polypropylene-based coated molded product is obtained by applying a coating comprising (a) 100 pts. wt. polypropylene-based water-based dispersion having ≤0.5 μm average particle diameter of dispersed particles in which (1) a stereoblock structure containing both of the isotactic block and the noncrystalline block is formed and (2) a content ratio (molar ratio) of a propylene unit to other olefin unit is 100:0 to 90:10, (b) 1-100 pts. wt. at least two kinds of nonionic surfactants and (c) 100-1,000 pts. wt. water to a molded product of an electroconductive polypropylene-based resin composition comprising the crystalline polypropylene and the electroconductive carbon. The polypropylene-based resin coated molded product is excellent in adhesion to coated film and appearance (smoothness) of the coated film and has a balance of physical properties excellent in stiffness and impact resistance. COPYRIGHT: (C)2004,JPO

8. 发明专利

JP2004083685A Polypropylene-based coated molded form 有权
公开(公告)号：JP2004083685A
公开(公告)日：2004-03-18
申请号：JP2002244621
申请日：2002-08-26
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： ONOE MASATO , ASHIHARA TERUAKI , HATA KAZUYUKI , SHIMIZU FUMIHIKO , ZANKA YUKITO
IPC分类号： C08J7/04 , C08K3/00 , C08K7/02 , C08L23/10 , C08L53/00 , C09D123/10
摘要： PROBLEM TO BE SOLVED: To provide a polypropylene-based coated molded form obtained by coating a filler-containing crystalline polypropylene molded form with a coating component comprising a polar group-containing propylene-based polymer. SOLUTION: The polypropylene-based coated molded form is obtained by coating a substrate(B) with a coating component(A). In this molded form, the coating component(A) comprises the polar group-containing propylene-based polymer composed of the main chain consisting of a propylene-based polymer having the characteristics(1) and (2) described below and side chains containing carboxy groups, carboxylic anhydride groups or carboxylic ester groups: (1) produced using a single-site catalyst and (2) ≤1 wt.% in insolubles when dissolved at 10 wt.% concentration in heptane at 98°C; and the substrate(B) is a molded form of a resin composition comprising a crystalline polypropylene and an inorganic filler component. This coated molded form is excellent in coating film adhesion and has well-balanced physical properties with high rigidity and impact resistance. COPYRIGHT: (C)2004,JPO

9. 发明专利

JP2004083683A Polypropylene-based coated molded form 有权
标题翻译：基于聚丙烯的涂层成型
公开(公告)号：JP2004083683A
公开(公告)日：2004-03-18
申请号：JP2002244542
申请日：2002-08-26
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： ONOE MASATO , ASHIHARA TERUAKI , HATA KAZUYUKI , SHIMIZU FUMIHIKO , ZANKA YUKITO
IPC分类号： C08J7/04 , C09D123/14
摘要： PROBLEM TO BE SOLVED: To provide a polypropylene-based coated molded form obtained by coating a crystalline polypropylene molded form with a coating component comprising a polar group-containing propylene-based polymer. SOLUTION: The polypropylene-based coated molded form is obtained by coating a substrate(B) with a coating component(A). In this molded form, the coating component(A) comprises the polar group-containing propylene-based polymer composed of the main chain consisting of a propylene-based polymer having the characteristics(1) and (2) described below and side chains containing carboxy groups, carboxylic anhydride groups or carboxylic ester groups: (1) produced using a single-site catalyst and (2) ≤1 wt.% in insolubles when dissolved at 10 wt.% concentration in heptane at 98°C; and the substrate(B) is a crystalline polypropylene molded form. This coated molded form is excellent in coating film adhesion and has well-balanced physical properties with high rigidity and impact resistance, furthermore being not only helpful to global environmental protection because of using no halogens harmful to the global environment but also high in long-term stability because of drastically mitigating the adverse effects of halogens on its weatherability or the like, resulting in extending its lifecycle. COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供通过用包含极性基团的丙烯类聚合物的涂层组分涂覆结晶聚丙烯模制形式获得的聚丙烯基涂覆模制形式。解决方案：通过用涂料组分（A）涂布基材（B）来获得聚丙烯基涂覆的模制形式。在该模塑形式中，涂料组分（A）包含由具有下述特征（1）和（2）的丙烯类聚合物构成的主链和含有羧基的侧链构成的含极性基团的丙烯类聚合物基团，羧酸酐基团或羧酸酯基团：（1）使用单中心催化剂制备，和（2）当在98℃下在庚烷中以10重量％浓度溶解时，不溶物中≤1重量％并且基材（B）是结晶聚丙烯成型体。该涂布成型体的涂膜密合性优异，具有高刚性和耐冲击性的良好平衡的物理性能，不仅有助于全球环境保护，因为不使用对全球环境有害的卤素，而且长期的高因为大大减轻了卤素对其耐候性等的不良影响，从而延长了其生命周期。版权所有（C）2004，JPO

10. 发明专利

JP2004107538A Polypropylene-based resin coated molded product 审中-公开
公开(公告)号：JP2004107538A
公开(公告)日：2004-04-08
申请号：JP2002273960
申请日：2002-09-19
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： ONOE MASATO , ASHIHARA TERUAKI , HATA KAZUYUKI , SHIMIZU FUMIHIKO , ZANKA YUKITO
IPC分类号： C08J7/04 , C08K3/00 , C08L23/12 , C08L53/00 , C09D5/00 , C09D123/10 , C09D171/00
摘要： PROBLEM TO BE SOLVED: To provide a polypropylene-based resin coated molded product by using a polypropylene-based water-based dispersion excellent in disperse stability and capable of forming coated film excellent in adhesion to a polypropylene base material and water resistance as a coating component and applying the coating component to a crystalline polypropylene molded product. SOLUTION: The polypropylene-based coated molded product is obtained by applying (A) the coating component which is a polypropylene-based water-based dispersion having ≤0.5 μm average particle diameter of dispersed particles and comprising (a) 100 pts. wt. modified propylene-based polymer in which the main chain has characteristics: (1) a stereoblock structure containing both of the isotactic block and the noncrystalline block and (2)(100:0) to (90:10) content ratio of a propylene unit to other olefin unit, (b) 1-100 pts. wt. at least two kinds of nonionic surfactants and (c) 100-1,000 pts. wt. water to (B) a base material which is the molded product of the crystalline polypropylene. COPYRIGHT: (C)2004,JPO

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