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1. 发明专利

JP2012183534A Adsorbing sheet, adsorbing element, method for manufacturing the same, and use of the same 有权
标题翻译：吸附片，吸附元件，制造方法及其使用方法
公开(公告)号：JP2012183534A
公开(公告)日：2012-09-27
申请号：JP2012092899
申请日：2012-04-16
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： OSHIMA KAZUNORI , TAKEWAKI TAKAHIKO , KAKIUCHI HIROYUKI , HARADA TAKASHI
IPC分类号： B01J20/28 , B01D53/26 , B01J20/08 , B01J20/10 , B01J20/18 , B01J20/20 , B01J20/32 , B32B5/02 , B32B15/08 , F24F3/14
摘要： PROBLEM TO BE SOLVED: To provide an adsorbing sheet which constitutes an adsorbing element of an adsorption unit to be used in an adsorption heat pump or a desiccant system and is excellent in heat-resistant performance and more excellent in adsorption/desorption capacity, to provide the adsorbing element which comprises the adsorbing sheet as a constituent element, is more excellent in heat-resistant performance and adsorption/desorption capacity, and is made compact, and to provide a method for manufacturing the adsorbing element.SOLUTION: The adsorbing sheet 1 is obtained by depositing an adsorbing material on a base material sheet 12 by using a binder and used for the adsorbing element. The adhesive strength of the adsorbing sheet is at least 0.04 MPa after such a durability test is repeated fifty times that the adsorbing sheet is heated to 120°C, the heated adsorbing sheet is immersed in the water of normal temperature and the immersed adsorbing sheet is cooled to -15°C. The adsorbing element of a plate fin type being one embodiment is provided with: a plurality of adsorbing sheets 1 each of which is formed into a plate-like shape and which are arrayed in parallel and side by side; and one heating medium flow passage penetrating each of adsorbing sheets 1.
摘要翻译：要解决的问题：提供一种吸附板，其构成吸附单元的吸附元件，用于吸附热泵或干燥剂系统，并且耐热性能优异，吸附/解吸能力更好为了提供包含吸附性片材的吸附元件作为构成元素，耐热性能和吸附/解吸能力更优异，并且提供了一种制造吸附元件的方法。解决方案：通过使用粘合剂将吸附材料沉积在基材片12上并用于吸附元件而获得吸附片1。吸附片材的粘合强度在耐久性试验重复五十倍于吸附片材加热至120℃之后至少为0.04MPa，加热的吸附片材浸渍在常温水中，浸渍的吸附片材冷却至-15°C。作为一个实施方式的板翅式吸附元件设置有：多个吸附片1，其形成为平板状且并排排列的板状，和一个加热介质流动通道贯穿每个吸附片1.版权所有（C）2012，JPO＆INPIT

2. 发明专利

JP2007245025A Adsorption sheet, adsorbing element, method for manufacturing the same, and application thereof 审中-公开
标题翻译：吸附片，吸附元件，制造方法及其应用
公开(公告)号：JP2007245025A
公开(公告)日：2007-09-27
申请号：JP2006072794
申请日：2006-03-16
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： OSHIMA KAZUNORI , TAKEWAKI TAKAHIKO , KAKIUCHI HIROYUKI , HARADA TAKASHI
IPC分类号： B01D53/26 , B01J20/10 , B01J20/28 , F25B17/08
摘要： PROBLEM TO BE SOLVED: To provide an adsorption sheet which constitutes an adsorbing element of an adsorption apparatus for an adsorbing type heat pump and desiccant system and is exceptionally outstanding in heat resistant performance, adsorption and desorption capability, and an adsorbing element consisting of the adsorption sheet and permitting miniaturization, and a method for manufacturing the same. SOLUTION: The adsorption sheet (1) is obtained by depositing an adsorbent material by a binder on a base material sheet (12). The strength of adhesion after a specific durability test to repeat heating/cooling is ≥0.04 MPa and an initial amount of steam adsorption after the durability test is performed is ≥80%. The binder is a (meth)acrylic resin including a (meth)acrylate ester unit having 3-10C alkyl group. The adsorbing element of a plate fin type of one embodiment is constituted by arraying a plurality of the adsorption sheets (1) formed to a sheet-like form in parallel and juxtaposition. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：提供构成吸附式热泵和干燥剂系统的吸附装置的吸附元件的吸附片，并且在耐热性能，吸附和解吸能力方面特别突出，并且吸附元件组成和允许小型化的方法及其制造方法。解决方案：通过在基材片（12）上通过粘合剂沉积吸附材料来获得吸附片（1）。重复加热/冷却的特定耐久性试验后的粘合强度≥0.04MPa，进行耐久性试验后的蒸汽吸附初始量为≥80％。粘合剂是包含具有3-10C烷基的（甲基）丙烯酸酯单元的（甲基）丙烯酸树脂。一个实施方案的板翅式吸附元件是通过将形成为片状的多个吸附片（1）并列排列并列而构成的。版权所有（C）2007，JPO＆INPIT

3. 发明专利

JP2010055855A Electrode material electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery using same 审中-公开
标题翻译：用于非电解电解质二次电池的电极材料电极和使用相同电极的非电解电解质二次电池
公开(公告)号：JP2010055855A
公开(公告)日：2010-03-11
申请号：JP2008217622
申请日：2008-08-27
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： SAITO YOSUKE , TERADA KAORU , HARADA TAKASHI , FUSE TORU
IPC分类号： H01M4/48
CPC分类号： Y02E60/12
摘要： PROBLEM TO BE SOLVED: To provide an electrode material and an electrode for a nonaqueous electrolyte secondary battery, which can achieve a nonaqueous electrolyte secondary battery with a high discharge capacity, excellent rate characteristics and an excellent cycle, and also provide a nonaqueous electrolyte secondary battery using the same.
SOLUTION: The electrode material for a nonaqueous electrolyte secondary battery includes TiO
2 (B) and/or its element substitution product, and the electrode formed by using the material satisfies requirements (α) and/or (β). The requirement (α) is that an X-ray integral intensity ratio X
e ab value of the electrode using the electrode material is 2.3 or less, the X
e ab value being defined by formula (1) X
e ab value=I
e A/I
e BI
e (wherein A expresses an integral intensity of a peak A caused by a plane (003) and I
e B an integral intensity of a peak B caused by a plane (-601)). The requirement (β) is that an X-ray integral intensity ratio X
e ac value of the electrode using the electrode material is 33 or less, the X
e ac value being defined by formula (2) X
e ac value=I
e A/I
e C (wherein I
e A expresses an integral intensity of a peak A caused by a plane (003) and I
e C an integral intensity of a peak C caused by a plane (110)).
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决的问题：提供一种电极材料和非水电解质二次电池用电极，其可以实现具有高放电容量，优异的速率特性和优异的循环的非水电解质二次电池，并且还提供非水电解质电解质二次电池使用相同。解决方案：非水电解质二次电池用电极材料包括TiO（SB）2（SBB）和/或其元素取代产物，使用该材料形成的电极满足要求（α）和/ 或（β）。要求（α）是使用电极材料的电极的X射线积分强度比X e ab值为2.3以下，X e ab值为由式（1）定义：其中A（I）为（A）表示由平面（003）和I e B引起的由平面（-601）引起的峰B的积分强度引起的峰A的积分强度。要求（β）是使用电极材料的电极的X射线积分强度比X e ac值为33以下，X e ac值为由式（2）定义：其中I e A表示由平面（003）和I（SB）e引起的峰值A的积分强度，C是由平面（110）引起的峰值C的积分强度。版权所有（C）2010，JPO＆INPIT

4. 发明专利

JP2009117259A Electrode material and electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery using them 有权
标题翻译：非电解电解质二次电池的电极材料和电极，以及使用它们的非电解电解质二次电池
公开(公告)号：JP2009117259A
公开(公告)日：2009-05-28
申请号：JP2007291216
申请日：2007-11-08
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： SAITO YOSUKE , HARADA TAKASHI , FUSE TORU
IPC分类号： H01M4/485
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide an electrode material for nonaqueous electrolyte secondary battery, which can stably and efficiently achieve a high-performance nonaqueous electrolyte secondary battery with high discharge capacity and excellent rate characteristics. SOLUTION: The electrode material for nonaqueous electrolyte secondary battery is a titanium oxide electrode material containing alkaline metal element, and satisfies the following requirements (1) and (2). (1) The atomic ratio M/Ti of Ti element contained in the titanium oxide and the alkaline metal element (element M) excluding Li is ≥0.01 and ≤0.3. (2) The X-ray intensity ratio, Xab value, of the titanium oxide defined by the formula: Xab value=IA/IB (IA: peak intensity close to 2θ=25.3 degrees in X-ray diffraction measurement, and IB: peak intensity existing within a range of 2θ=10 to 15 degrees in X-ray diffraction measurement) is ≤10. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：解决的问题：提供一种可以稳定有效地实现高放电容量和优异的速率特性的高性能非水电解质二次电池的非水电解质二次电池用电极材料。解决方案：非水电解质二次电池用电极材料是含有碱金属元素的氧化钛电极材料，满足下述（1）和（2）的要求。（1）氧化钛中所含的Ti元素和不含Li的碱金属元素（元素M）的原子比M / Ti为≥0.01且≤0.3。（2）Xab值= IA / IB（IA：X射线衍射测定中接近2θ= 25.3度的峰强度，IB：峰值）的氧化钛的X射线强度比Xab值存在于X射线衍射测定中的2θ= 10〜15度的范围内的强度）≤10。版权所有（C）2009，JPO＆INPIT

5. 发明专利

JP2009026491A Metal foil and its manufacturing method, secondary battery current collector, electrode for secondary battery, and nonaqueous secondary battery 有权
标题翻译：金属箔及其制造方法，二次电池电流收集器，二次电池用电极和非等级二次电池
公开(公告)号：JP2009026491A
公开(公告)日：2009-02-05
申请号：JP2007185697
申请日：2007-07-17
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： HARADA TAKASHI , FUSE TORU
IPC分类号： H01M4/66 , H01B5/02 , H01M4/13 , H01M4/134 , H01M4/38
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide a metal foil with good adhesion with a lamination film and of low cost and its manufacturing method, and provide the metal foil as a current collector for secondary battery capable of supplying efficiently and stably a nonaqueous electrolyte secondary battery of low cost having a high discharge capacity and excellent cycle characteristics with high performance. SOLUTION: The metal foil 10 has a metal film 2 which is made by coagulating and precipitating metal particulates by heating a film under an inert atmosphere after coating a dispersant in which the metal particulates are dispersed in non-coagulation state on a base foil. The metal film 2 of the metal foil 10 is made of a nearly crest shape in which projected particulates 4 having peak portions 3 are connected and the maximum particulate size of the projected particulates 4 is 100 μm or less and the 10 point-average roughness Rz by JIS B 0601-1994 of the metal film 2 is ≥0.4 μm and ≤10 μm. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：为了提供具有与层压膜的良好粘合性并且成本低的金属箔及其制造方法，并且提供作为二次电池集电体的金属箔，能够高效稳定地提供非水电解质低成本的二次电池具有高放电容量和优异的循环特性和高性能。解决方案：金属箔10具有金属膜2，金属膜2通过在将金属微粒分散在非凝固状态的分散剂涂覆在基底上之后，在惰性气氛下加热薄膜而使金属颗粒凝结和沉淀而制成挫败。金属箔10的金属膜2由具有峰部3的投影微粒4连接并且投影微粒4的最大粒径为100μm以下的几乎波峰形状，并且10点平均粗糙度Rz 通过JIS B 0601-1994，金属膜2的厚度≥0.4μm，≤10μm。版权所有（C）2009，JPO＆INPIT

6. 发明专利

JP2007245018A Adsorption sheet, adsorbing element, method for manufacturing the same, and application thereof 审中-公开
标题翻译：吸附片，吸附元件，制造方法及其应用
公开(公告)号：JP2007245018A
公开(公告)日：2007-09-27
申请号：JP2006072641
申请日：2006-03-16
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： OSHIMA KAZUNORI , TAKEWAKI TAKAHIKO , KAKIUCHI HIROYUKI , HARADA TAKASHI
IPC分类号： B01D53/26 , B01J20/10 , F25B17/08 , F28F1/30
摘要： PROBLEM TO BE SOLVED: To provide an adsorption sheet which constitutes an adsorbing element of an adsorption apparatus for an adsorbing type heat pump and desiccant system and is exceptionally outstanding in heat resistance performance, adsorption and desorption capability, and an adsorbing element consisting of the adsorption sheet and permitting miniaturization, and a method for manufacturing the same. SOLUTION: The adsorption sheet (1) is obtained by depositing an adsorbent material by a binder on a base material sheet (12). The strength of adhesion after a specific durability test to repeat heating/cooling is ≥0.04 MPa and an initial amount of steam adsorption after the durability test is performed is ≥80%. The binder is a (meth)acrylic resin including a (meth)acrylate ester unit having 3-10C alkyl group. The adsorbing element of a plate fin type of one embodiment is constituted by arraying a plurality of the adsorption sheets (1) formed to a sheet-like form in parallel and juxtaposition. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：提供构成吸附型热泵和干燥剂系统的吸附装置的吸附元件的吸附片，并且在耐热性能，吸附和解吸能力方面特别突出，并且吸附元件组成和允许小型化的方法及其制造方法。解决方案：通过在基材片（12）上通过粘合剂沉积吸附材料来获得吸附片（1）。重复加热/冷却的特定耐久性试验后的粘合强度≥0.04MPa，进行耐久性试验后的蒸汽吸附初始量为≥80％。粘合剂是包含具有3-10C烷基的（甲基）丙烯酸酯单元的（甲基）丙烯酸树脂。一个实施方案的板翅式吸附元件是通过将形成为片状的多个吸附片（1）并列排列并列而构成的。版权所有（C）2007，JPO＆INPIT

7. 发明专利

JP2015028856A 酸化物固体電解質材料および電池审中-公开
标题翻译：氧化物固体电解质材料和电池
公开(公告)号：JP2015028856A
公开(公告)日：2015-02-12
申请号：JP2013157644
申请日：2013-07-30
申请人：三菱化学株式会社 , Mitsubishi Chemicals Corp
发明人： HARADA TAKASHI
IPC分类号： H01M10/0562
摘要：【課題】イオン伝導性が良好な酸化物固体電解質材料を提供すること。【解決手段】下記一般式(1)で表される酸化物固体電解質材料:K2−xM1a+xLi14−(a−1)x−(b−4)yZr3−yM2b+yO14・・・(1)(ここで、M1,M2はそれぞれドーパント元素を表し、指数xは0以上2以下の数であり、指数yは0以上3以下の数であり、aは2又は3であり、bは2、3又は5である。)。【選択図】なし
摘要翻译：要解决的问题：提供离子传导性良好的氧化物固体电解质材料。解决方案：氧化物固体电解质材料由以下通式（1）表示：KMLiZrMO ...（1）（其中，Mand Mrepresent a 掺杂元素，指数x为0以上且2以下的数，指数y为0以上且3以下的数，（a）为2或3，b为2,3或5。）。

8. 发明专利

JP2012234772A Lithium-transition metal-based compound powder for lithium secondary battery positive electrode material, and manufacturing method thereof, positive electrode for lithium secondary battery using the same, and lithium secondary battery 审中-公开
标题翻译：用于锂二次电池正极电极材料的钛酸转移金属化合物粉末及其制造方法，使用其的锂二次电池的正电极和锂二次电池
公开(公告)号：JP2012234772A
公开(公告)日：2012-11-29
申请号：JP2011104378
申请日：2011-05-09
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： HARADA TAKASHI , WATANABE NOBU
IPC分类号： H01M4/525 , C01G53/00 , H01M4/131 , H01M4/505
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide a lithium-transition metal-based compound powder which makes it possible to provide a lithium secondary battery which has a high initial efficiency and a good rate characteristic when used as a lithium secondary battery positive electrode material.SOLUTION: The lithium-transition metal-based compound powder for lithium secondary battery positive electrode material comprises an oxide expressed by the general formula (1). The powder has Li holes and oxygen holes in a crystal structure, and a root mean square (RMS) of surface roughnesses of primary particles of the powder is 1.5 nm or less, which conforms to JIS B 0601:2001. xLiMO(1-x)LiNO(1), where x meets 0
摘要翻译：解决的问题：提供一种锂 - 过渡金属类化合物粉末，其可以提供当用作锂二次电池正极材料时具有高初始效率和良好率特性的锂二次电池。解决方案：用于锂二次电池正极材料的锂 - 过渡金属类化合物粉末包含由通式（1）表示的氧化物。粉末具有晶体结构的Li孔和氧空穴，粉末的一次粒子的表面粗糙度的均方根（RMS）为1.5nm以下，符合JIS B 0601：2001。（1）xLi 2 MO 3 （1-x），其中x满足0 + 。版权所有（C）2013，JPO＆INPIT

9. 发明专利

JP2008210564A Current collector for nonaqueous electrolyte secondary battery, electrode for nonaqueous electrolyte secondary battery and its manufactueing method, and nonaqueous electrolyte secondary battery 有权
标题翻译：用于非水电解质二次电池的电流收集器，非电解电解质二次电池的电极及其制造方法和非电解电解质二次电池
公开(公告)号：JP2008210564A
公开(公告)日：2008-09-11
申请号：JP2007044079
申请日：2007-02-23
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： FUSE TORU , HARADA TAKASHI
IPC分类号： H01M4/70 , H01M4/134 , H01M4/136 , H01M4/1395 , H01M4/1397 , H01M4/38 , H01M4/58 , H01M10/05
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide an electrode for a nonaqueous electrolyte secondary battery which has high discharge capacity, high charge and discharge efficiency, and excellent cycle characteristics and which is inexpensive, and to provide the nonaqueous electrolyte secondary battery using the electrode. SOLUTION: A current collector for the nonaqueous electrolyte secondary battery is formed by etching a metal foil of which the Cpd value and the Cp value of the average crystal grain size of the surface range at least from 0.2 to 1.0, and has an average surface roughness Ra of unevenness formed on the surface of 0.20 to 0.55 μm. In the electrode for the nonaqueous electrolyte secondary battery, an active material capable of storing and releasing lithium is formed on this current collector. A method of manufacturing the electrode for the nonaqueous electrolyte secondary battery includes a process of chemically etching the metal foil of which the Cpd value and the Cp value of the average crystal grain size of the surface range at least from 0.2 to 1.0 to the average surface roughness Ra of 0.20 to 0.55 μm, and a process of growing the active material on the current collector in the vapor phase. The nonaqueous electrolyte secondary battery using this electrode is also provided. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决的问题：提供一种具有高放电容量，高充放电效率和优异的循环特性并且便宜的非水电解质二次电池用电极，并且提供使用该电极的非水电解质二次电池。解决方案：用于非水电解质二次电池的集电器通过蚀刻其表面距离的平均晶粒尺寸的Cpd值和Cp值至少为0.2至1.0的金属箔而形成，并且具有表面上形成的凹凸的平均表面粗糙度Ra为0.20〜0.55μm。在非水电解质二次电池用电极中，在该集电体上形成能够储存和释放锂的活性物质。一种制造非水电解质二次电池用电极的方法包括以下步骤：对所述金属箔进行化学蚀刻，其中所述金属箔的表面距离的平均晶粒尺寸的Cpd值和Cp值相对于平均表面至少为0.2至1.0 粗糙度Ra为0.20〜0.55μm，以及在气相中在集电体上生长活性物质的工序。还提供了使用该电极的非水电解质二次电池。版权所有（C）2008，JPO＆INPIT

10. 发明专利

JP2007246386A Afi type iron aluminophosphate and method for manufacturing the same 有权
标题翻译： AFI型铁铝磷酸盐及其制造方法
公开(公告)号：JP2007246386A
公开(公告)日：2007-09-27
申请号：JP2006353855
申请日：2006-12-28
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： HARADA TAKASHI , TANIGAWA YUICHI , TAKEWAKI TAKAHIKO , TERADA HIDE , KURAMOTO RIYOUKO
IPC分类号： C01B37/06
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing FAPO-5 of particulates useful as a catalyst and an adsorbent material, and the FAPO-5 of the particulates manufacturable on an industrial level. SOLUTION: The AFI type aluminophosphate is composed of the particulates obtained without mechanical grinding, and the mean particle diameter thereof is ≤l5 microns. The method for manufacturing the AFI type aluminophosphate is the method for manufacturing the AFI type aluminophosphate of the particulates, in which at the time of performing hydrothermal synthesis of aqueous starting raw materials including a P source, an Al source, an Fe source, and a template, the raw materials are stirred at a stirring line speed of ≥0.05 m/s. COPYRIGHT: (C)2007,JPO&INPIT

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