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    • 1. 发明专利
    • Two-component type diazo photosensitive material
    • 双组分型DIAZO感光材料
    • JPS59126532A
    • 1984-07-21
    • JP119083
    • 1983-01-10
    • Mita Ind Co LtdOosakashi
    • HIRANO MITSUYOSHIISHINO YOSHIOUEDA MITSUOTAKAHASHI KENJI
    • C09B29/34G03C1/58
    • G03C1/58
    • PURPOSE:To obtain a two-component type diazo photosensitive material giving an azo dye image with superior fastness and fixablility even by semidry development by adding a photodegradable diazonium salt, a specified coupling component and an acid stabilizer. CONSTITUTION:A photodegradable diazonium salt (A) such as 4-diazo-2,5-dibutoxy-N,N-diethylaniline is mixed with a coupling component (B) represented by formula I (where R1 is lower alkylene; each of R2, R3 and R4 is lower alkyl; R3 and R4 may bond to each other to form a heterocyclic ring together with N; and X is an anion) and an acid stabilizer (C) such as maleic acid, and the mixture is applied to a substrate to obtain the desired two-component type diazo photosensitive material. The component B is easily prepd. by reacting amine represented by formula II with an alkylating agent such as alkyl iodide or alkyl ester of p-toluenesulfonic acid.
    • 目的:为了获得双组分型重氮感光材料,即使通过添加可光降解的重氮盐,特定的偶联组分和酸稳定剂,即使通过半分开发,给出具有优异的牢度和固定性的偶氮染料图像。 构成:将4-重氮基-2,5-二丁氧基-N,N-二乙基苯胺的光降解重氮盐(A)与由式I表示的偶联组分(B)混合(其中R1是低级亚烷基; R2, R3和R4是低级烷基; R3和R4可以彼此键合,与N一起形成杂环; X 1是阴离子)和酸稳定剂(C)如马来酸,并将该混合物施加 以获得所需的双组分型重氮感光材料。 组分B容易制备。 通过使由式II表示的胺与烷基化剂如烷基碘或对甲苯磺酸的烷基酯反应。
    • 2. 发明专利
    • Diazo photosensitive material
    • DIAZO感光材料
    • JPS5940639A
    • 1984-03-06
    • JP14988982
    • 1982-08-31
    • Mita Ind Co Ltd
    • HIRANO MITSUYOSHITAKAHASHI KENJIMATSUNOBU KENICHIWATANABE YOUICHIROU
    • G03C1/61G03C1/60
    • G03C1/61
    • PURPOSE:To enhance image quality, by incorporating an acid stabilizer, a metallic ion sequestering agent, a water holding agent, and a phytic acid exhibiting a superior action as a color tone stabilizer, etc. in a photosensitive layer contg. a photosensitive diazonium salt, a coupler, etc. CONSTITUTION:0.5-7pts.wt. phytic acid is incorporated in 1pt.wt. photosensitive diazonium salt, such as 4-diazo-N,N-dimethylaniline or 4-diazo-N-ethyl-N-beta-hydroxyethylaniline. When needed, further, a coupler, such as pyrocatechol or resorcinol, a stabilizer adjuvant, and a dye are added, and the mixture is dissolved or dispersed in water or the like solvent to prepare a photosensitive compsn. A base, such as tissue paper or coated paper, is coated with said photosensitive compsn. with a roll, a sprayer, or the like, and dried to obtain the intended diazo photosensitive material.
    • 目的:为了提高图像质量,通过在光敏层中掺入酸稳定剂,金属离子螯合剂,保水剂和表现出优异作用的色调稳定剂等的植酸。 光敏重氮盐,偶联剂等。组成:0.5-7pts.wt。 植酸被掺入1pt.wt. 光敏重氮盐,如4-重氮-N,N-二甲基苯胺或4-重氮-N-乙基-N-β-羟乙基苯胺。 当需要时,加入偶联剂如邻苯二酚或间苯二酚,稳定剂助剂和染料,并将混合物溶解或分散在水等溶剂中以制备光敏组合物。 诸如薄纸或涂布纸的基底涂有所述光敏组合物。 用辊,喷雾器等进行干燥,得到所需的重氮感光材料。