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    • 3. 发明专利
    • POLYMERIZER
    • JPH08188603A
    • 1996-07-23
    • JP246195
    • 1995-01-11
    • MITSUI TOATSU CHEMICALS
    • ABE KOJIITO HIROSHIKAJITANI SEITAROMORI TAKAFUMI
    • C08F2/00C08G85/00
    • PURPOSE: To perform an adiabatic reaction in good precision even in a polymerization reaction of a high polymerization speed by markedly improving the response speed by filling the outside of the reaction system with an aqueous medium and using high-frequency for heating this medium. CONSTITUTION: This polymerizer is the one for performing an exothermic polymerization reaction and composed of a polymerization tank 10, a jacket 12 for performing the temperature control of the tank 10 and a pump 18 for withdrawing the aqueous medium 2 from the jacket 12 and recirculating the withdrawn medium to the jacket 12 through a heater 20 and a cooler 19, wherein the heater 20 is a high-frequency heater. In this polymerizer, an aqueous medium is used as the medium outside the reaction system, the aqueous medium is heated by high-frequency while it is being recirculated. Therefore, the temperature of the aqueous medium can be raised instantly in response to the temperature inside the reaction system, and the temperature rise can be stopped instantly by breaking the electric source for high-frequency to maintain easily the temperature constant. Therefore, by controlling only the outside temperature, a polymer different in properties such as a molecular weight can be obtained in good reproducibility.