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    • 2. 发明专利
    • PRODUCTION OF GYPSUM THIN-FORMED BOARD
    • JPH1192207A
    • 1999-04-06
    • JP24839897
    • 1997-09-12
    • MITSUI CHEMICALS INC
    • NAGAI HIROYOSHIDOI KIYOTOABE KOJIYOSHINO TADASHI
    • C04B11/26B28B1/52C04B28/14C04B103/12C04B103/22C04B111/20
    • PROBLEM TO BE SOLVED: To obtain an inexpensive thin-formed board high in mechanical strength by incorporating α-gypsum hemihydrate as a byproduct from the wet phosphoric acid production process with a fibrous material, water, and, as necessary, an admixture and a setting regulator to prepare a mixed slurry at a specific temperature which, in turn, is subjected to filtration and drying. SOLUTION: This gypsum thin-formed board is obtained through the following process: first, α-gypsum hemihydrate 15-35 wt.% in adhered water content produced as a byproduct in manufacturing wet phosphoric acid by decomposing igneous phosphate rock with sulfuric acid is dried and ground; next, the resulting α-gypsum hemihydrate is incorporated with a fibrous material (e.g. pulp fiber), hot water, and, as necessary, an admixture (e.g. wollastonite powder) and a setting regulator (an alkaline substance such as NaOH or a hardenable alkaline inorganic matter like cement) to prepare a slurry at a temp. of 40-80 deg.C; wherein the setting regulator is intended for the pH adjustment of the resulting slurry, its amount to be added being 0.1-5 pts.wt. based on 100 pts.wt. of the α-gypsum hemihydrate; the resultant slurry is then dehydrated using a vacuum filter, molded and then dried.
    • 3. 发明专利
    • GYPSUM BOARD FOR INTERIOR WALL AND ITS PRODUCTION
    • JPH1112019A
    • 1999-01-19
    • JP16427297
    • 1997-06-20
    • MITSUI CHEMICALS INC
    • NAGAI HIROYOSHIDOI KIYOTOYOSHINO TADASHIMAEDA KOICHI
    • C04B28/04C04B111/40
    • PROBLEM TO BE SOLVED: To obtain the subject board with improved surface accuracy and moisture absorbing/releasing characteristics by including gypsum, cement, inorganic powder, a fibrous material and moisture absorbing/releasing material. SOLUTION: This board comprises gypsum, cement, inorganic powder, a fibrous material and moisture absorbing/releasing material. The gypsum may be natural or synthetic one or the like, preferably α-hemihydrate gypsum produced as the by-product by the wet process that produces phosphoric acid from phosphorus ore and sulfuric acid, more preferably α-hemihydrate gypsum dried and incorporated with an inorganic alkali. The cement may be various types of Portland cement, Portland blast-furnace cement, fly ash cement or the like, used preferably at 30 to 0 pts.wt. per 70 to 100 pts.wt. of the gypsum. The inorganic powder is a light aggregate or the like, e.g. fly ashes, sirasu balloons or pearlite, its grain size being 20 to 500 μm. The fibrous material may be natural or synthetic, e.g. fibers from pulp of a vegetable, needle-leaved tree or the like, or glass fibers. The moisture absorbing/releasing material includes inorganic one, e.g. zeolite or attapulgite, or organic one, e.g. poval, CMC or thermosetting resin.
    • 6. 发明专利
    • AQUEOUS COMPOSITION FOR SELF LEVELING
    • JPH10120457A
    • 1998-05-12
    • JP27950196
    • 1996-10-22
    • MITSUI CHEMICALS INC
    • NAGAI HIROYOSHIDOI KIYOTOYOSHINO TADASHIYOSHIDA HIROTAKA
    • C04B28/14
    • PROBLEM TO BE SOLVED: To obtain an aqueous composition stable without being concerned with the temperature change, capable of maintaining high fluidity for a long time, manifesting a sufficient strength after being hardened and having good operability by using a mixture of an α-hemihydrate gypsum with a cement as a substrate, and blending a fluidizing agent, a retarder and an accelerator with the substrate. SOLUTION: This self leveling material comprises α-hemihydrate gypsum obtained as a byproduct when producing phosphoric acid by using a phosphate rock and sulfuric acid by a wet phosphoric acid production method, a cement, a fluidizing agent, a retarder and an accelerator. The α-hemihydrate gypsum is preferably the one obtained by adding an alkali after being dried. The α- hemihydrate gypsum of 99-50 pts.wt. and the cement of 1-50 pts.wt. are preferably used based on 100 pts.wt. of the total of the α-hemihydrate gypsum and the cement. The fluidizing agent is preferably an oxycarboxylic acid based one and/or polycarboxylic acid-based one. A hydroxycarboxylic acid and/or salts thereof is used as the retarder, and an alkali metal carbonate and/or an alkali metal bicarbonate is used as the accelerator.
    • 7. 发明专利
    • LATENT CURING AGENT
    • JPH11255856A
    • 1999-09-21
    • JP5506898
    • 1998-03-06
    • MITSUI CHEMICALS INC
    • KOTOU NOBUHIKODOI KIYOTOUEDA KYOICHITANAKA KOICHISHIMODA MANABU
    • C08G12/02
    • PROBLEM TO BE SOLVED: To resolve delay in cure caused by the decrease of formaldehyde and to improve the economic efficiency by the acceleration of cure by employing a specific amount of persulfates, peroxides or azo compounds as a curing accelerator of an amino resin with its molar ratio of formaldehyde to amino groups adjusted in a specific range. SOLUTION: The molar ratio of formaldehyde to amino groups in an amino resin comprising an oligomer and/or a polymer which is a reaction product of one or more of urea, thiourea and melamine and the like with formaldehyde is adjusted between 0.4 and 1.8. A latent curing accelerator comprising one or more of persulfates of ammonium, potassium, sodium, barium and the like, peroxides such as ketone peroxides and the like and azo compounds such as 2,2'-azobis(isobutyronitrile) is added to the amino resin for an adhesive composition in an amount of 0.05-20.0 pts.wt. relative to 100 pts.wt. of the amino resin to effect cure at a specified temperature. And an ammonium salt can be jointly used as a curing agent.
    • 8. 发明专利
    • CEMENT ADMIXTURE
    • JPH11130503A
    • 1999-05-18
    • JP30034397
    • 1997-10-31
    • MITSUI CHEMICALS INC
    • HATSUJI HISAKAZUDOI KIYOTOMAEHAMA MITSUHIROTOMITA YOSHIHIKO
    • C04B24/22C04B24/30C04B40/00C04B103/32C08G65/08
    • PROBLEM TO BE SOLVED: To obtain a cement admixture hardly causing retardation of hardening, manifesting excellent dispersing activities and slump-maintaining activities, and having extreme separating resistance of a material by subjecting a polyoxyalkylene (derivative) to a cocondensation with a monomer the formaldehyde addition-condensation of which can be carried out with the polyoxyalkylene, a compound forming sulfone group and the formaldehyde. SOLUTION: This cement admixture is obtained by subjecting a polyoxyalkylene (derivative) of formula I R1 is a 1-5C alkyl; Z1 is a 1-5C alkoxy, NH2 or NH-Z2 [Z2 is formula II (R2 to R5 are each H, a 1-5C alkyl, a 1-5C alkoxy or an aromatic compound)]; AO and BO are each a block or random 2-5C oxyalkylene; (m) and (n) are each 0-300 [300>=(m)+(n)>=2] to a cocondensation with a monomer a formaldehyde addition-condensation of which can be carried out with the polyoxyalkylene, a compound forming sulfone group and the formaldehyde. Melamine, phenol, urea, aminobenzenesulfonic acid, etc., are cited as the monomer the formaldehyde addition-condensation of which can be carried out. A sulfonating agent is used as the compound forming sulfone group.
    • 9. 发明专利
    • ELECTRICAL INSULATING MATERIAL FOR SHEATH HEATER
    • JPH118048A
    • 1999-01-12
    • JP15847697
    • 1997-06-16
    • MITSUI CHEMICALS INC
    • TAKAHASHI YUKIODOI KIYOTOHATSUDA NOBORU
    • H05B3/48
    • PROBLEM TO BE SOLVED: To provide a sheath heater in which drop in insulating resistance caused by moisture absorption is prevented by burying a heater wire in a metal pipe and filling an electrical insulating material of aluminum tertiary phosphate between them. SOLUTION: For a metal pipe, iron, stainless steel, aluminum, titanium or copper is used. Various sizes of pipes are used according to applications. A coil-shaped heater wire to which a terminal is connected is inserted in the center of the metal pipe, an electrical insulating material is filled between the metal pipe and the coil-shaped heater wire, compression for diameter reduction and heat treatment are applied, then the end of the metal pipe is sealed before use. As the electrical insulating material filled between the metal pipe and the coil-shaped heater wire, aluminum tertiary phosphate is used. Commercially available aluminum tertiary phosphate can be used, but by using aluminum tertiary phosphate prepared by reacting phosphoric acid with a hydroxide or oxide of aluminum in the existence of an organic solvent, electrical insulating effect is furthermore enhanced.