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    • 7. 发明专利
    • SODIUM-SULFUR CELL
    • JPS6288281A
    • 1987-04-22
    • JP22929585
    • 1985-10-15
    • TOKYO ELECTRIC POWER COHITACHI LTD
    • MORI SADAOWATANABE EIJIWADA HAJIME
    • H01M10/39
    • PURPOSE:To increase the charge/discharge capacity and to improve the energy efficiency by making such that at least one of the volume resistivity, the surface area per unit volume or the surface polarization resistance factor will have specific characteristic from the cathode section toward the depth direction of the anode section. CONSTITUTION:It is constituted such that the volume resistivity will decrease from the cathode section toward the depth direction of the anode section while the surface area per unit volume will increase and the surface polarization resistance factor will also increase. In order to set the resistivity of porous electron conductive members 4, 5, for example, the quantity of electrochemical reaction at each section of anode is integrated within a charge/discharge range of cell to determine such that the sulfur mol. ratio in sodium polysulfide will be uniform between completion of discharge and stopping time of charge/ discharge. Consequently, the cell reaction in the anode can be uniformed resulting in improvement of the charge/discharge capacity and the energy efficiency.
    • 8. 发明专利
    • SODIUM-SULFUR CELL
    • JPS61239570A
    • 1986-10-24
    • JP8017885
    • 1985-04-17
    • TOKYO ELECTRIC POWER COHITACHI LTD
    • MORI SADAOOSHIMA KISHIOKUSAKABE KOJIWADA HAJIME
    • H01M10/39
    • PURPOSE:To enable to eliminate non-uniformity in cell reaction caused by the effect of gravity and to prevent the accompanying ineffective use of an active material, by making a porus electrically conductive material to have different electric resistances along the direction of the acceleration of gravity. CONSTITUTION:A positive electrode is made to have different values of electric conductivity at its upper part A and lower part B respectively. That is, the lower part B of the positive electrode includes more molten sulfur than the upper part A of the positive electrode due to the effect of gravity. This is because the molten sulfur fills the voids of the porus electrically conductive material and moves upward because of surface tension. This causes a bias to the branch of current at the onset, resulting lower current density in the upper part of the positive electrode and higher current density in the lower part of the positive electrode. As a result, the difference between x values of the upper and lower parts of the positive electrode approaches zero at the end of discharging, and sodium polysulfide with mole ratio of sulfur to sodium uniform over the entire positive electrode is obtained. In this state, the cell can discharge further and active material can be utilized effectively.
    • 9. 发明专利
    • SODIUM-SULFUR CELL
    • JPS61239569A
    • 1986-10-24
    • JP8017785
    • 1985-04-17
    • TOKYO ELECTRIC POWER COHITACHI LTD
    • MORI SADAOTACHIBANA KEIJIKAWAMOTO HIROYUKI
    • H01M2/34H01M10/39
    • PURPOSE:To prevent vessel melt-down in case solid electrolyte is damaged, by making a collector electrode of a metal of low melting point which is implanted in implanted in sodium negative electrode. CONSTITUTION:A negative electrode 2 is made of a material of low melting point. Due to the thermal conductivity of sodium, which is a metal, higher enough than that of sulfur, most part of heat generated by sodium-sulfur reaction is transmitted to the sodium side. In case a crack is generated in a solid electrolyte 3, the negative electrode 2 made of a material of low melting point immediately metals to be capable of shutting down the circuit between positive and negative electrodes. The material of the negative electrode 2 is required to have good electric conductivity and good corrosion resistance against sodium, as well as low melting point. Appropriate materials which satisfy these requirements are aluminum which has melting point at about 660 deg.C, aluminum- silicon-magnesium alloy which can have melting point lowered as low as near 600 deg.C, and others.