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1. 发明专利

JPS61289004A WEEDING AGENT COMPOSITION 失效
公开(公告)号：JPS61289004A
公开(公告)日：1986-12-19
申请号：JP13076085
申请日：1985-06-18
申请人： MEIJI SEIKA KAISHA , KAO CORP
发明人： KOBAYASHI TOSHIYUKI , IZAWA HIROSHI , TACHIBANA KUNITAKA , MATSUMOTO KUNIOMI , SAKURAI SHINJI , SATO ATSUYUKI , IWASAKI TETSUHARU , KATABE KENICHI
IPC分类号： A01N57/20 , A01N25/30
摘要： PURPOSE:A weeding agent composition, containing a weeding compound substance SF-1293, sulfate based or sulfonate based anionic surfactant, etc. and a polyoxyalkylene based nonionic surfactant in a specific proportion and having enhanced effect. CONSTITUTION:A weeding agent composition containing (A) a weeding substance SF-1293 or a salt thereof, (B) a sulfate based or sulfonate based or carboxylyc acid based anionic surfactant and (C) a polypoxyalkylene based nonionic surfactant at 1:0.5-20 weight ratio of the components (A) to (B) and 1:0.1-20 weight ratio of the components (A) to (C). The above-mentioned composition is capable of enhancing the weeding effect of the component (A), and can be prepared in the form of a water-soluble solid formulation, etc., which cannot be conventionally prepared. The solid component (A) has an advantage in that it has more improved stability with time than that of the liquid formulation.

2. 发明专利

JP2000109865A ANTIBACTERIAL AGENT-CONTAINING METAL WORKING OIL 失效
公开(公告)号：JP2000109865A
公开(公告)日：2000-04-18
申请号：JP28503798
申请日：1998-10-07
申请人： MEIJI SEIKA KAISHA
发明人： SAKANAKA OSAMU , IGARI UKO , MATSUMOTO KUNIOMI , IINUMA KATSUHARU
IPC分类号： A01N59/12 , A01N63/02 , C10M131/12 , C10M133/38 , C10M173/00 , C10N30/16 , C10N40/22
摘要： PROBLEM TO BE SOLVED: To obtain a metal working oil for preventing proliferation of a wide range of bacteria over a long period of time by adding an iodoacetic acid ester or an amino glycoside to a water-soluble metal working oil which is used in cutting working or the like. SOLUTION: An iodoacetic acid ester or an amino glycoside are added to a water-soluble metal working oil which is used in cutting working to prevent both putrefaction and generation of off-ordor of the metal working oil. As the iodoacetic acid ester benzyl, cinnamyl, iodoacetate, phenyliodoacetate, benzyliodoacetate or the like is cited. As the amino glycoside, gentamicins, ribostamycin, kanamycins or the like is cited. The concentration of the antibacterial agent used is preferably about 1-200 μg/ml. The addition of the antibacterial agent may be mixed with at least two components. The time of the addition of antibacterial agent to the metal working oil is allowed to be any time of the manufacturing of the metal working oil, right after the unsealing, before the use and during the use.

3. 发明专利

JPS58185598A Novel antibiotic substance sf-2185, its preparation and plant blight controlling agent 失效
标题翻译：新型抗生素SF-2185，其制备和植物防治剂
公开(公告)号：JPS58185598A
公开(公告)日：1983-10-29
申请号：JP6732382
申请日：1982-04-23
申请人： Meiji Seika Kaisha Ltd
发明人： MATSUMOTO KUNIOMI , SHIYOUMURA TAKASHI , SHIMURA MASARU , WATANABE TETSUO , ITOU TATSUO
IPC分类号： C07G11/00 , A01N63/02 , C12P1/02 , C12P1/06 , C12R1/01
摘要： NEW MATERIAL:An antiobiotic substance SF-2185 having the following properties and a salt thereof: Molecular formula: C
5 H
7 NO
3 . Elementary analysis (%): C, 46.29; H, 5.22; N, 10.67; O, 37.82. Molecular weight: 129. Melting point: 111W112°C. Soluble in water, methanol, ethyl acetate, etc. Positive to the Greig-Leaback reaction, and negative to the ninhydrin, sulfuric acid, permanganic acid reactions, etc. Acidic. Stable to basicWneutral condition. Colorless needlelike crystals.
USE: A plant blight controlling agent.
PROCESS: A microorganism, belonging to the genus Dactylosporangium, and capable of producing the substance SF-2185, e.g. Dactylosporangium sp. SF-2185 strain (FRRM-P No.6308), is cultivated aerobically at 20W35°C.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：新材料具有以下性质的抗生素SF-2185及其盐：分子式：C5H7NO3。元素分析（％）：C，46.29; H，5.22; N，10.67; O，37.82。分子量：129.熔点：111-121℃ 可溶于水，甲醇，乙酸乙酯等。对于Greig-Leaback反应，对于茚三酮，硫酸，高锰酸反应等都是阳性的。稳定到基本中立状态。无色针状晶体。使用：植物枯萎病控制剂。方法：属于Dactylosporangium属的微生物，能够生产物质SF-2185，例如，细菌孢子藻 SF-2185菌株（FRRM-P No.6308）在20-35℃有氧培养。

4. 发明专利

JPS54147921A Agricultural and horticultural pesticide 失效
标题翻译：农业和农业农药
公开(公告)号：JPS54147921A
公开(公告)日：1979-11-19
申请号：JP5487278
申请日：1978-05-08
申请人： Hokko Chem Ind Co Ltd , Meiji Seika Kaisha Ltd
发明人： NISHIMURA TAMIO , OOYAMA HIROSHI , YAMAMURA HIROSHI , MORITA TAKESHI , MATSUMOTO KUNIOMI , WATANABE TETSUO
IPC分类号： A01N43/56 , C07D403/04
摘要： PURPOSE: An agriculatural and horticultural pesticide effective to rice blast, helminthosporium leaf spot of rice plant, powdery mildew of cucumber, etc., free from phytotoxicity, and harmless to man, beast and fish, containing a specific pyrazolylpyrimidine derivative as an effective component.
CONSTITUTION: A composition containing a pyrazolylpyrimidine derivative of formula [R
1 is lower alkyl, phenyl; R
2 is alkyl, cyclohexyl, phenyl (which may be substituted by lower alkyl or halogen); R
3 is H, alkyl; R
2 and R
3 may together with adjacent N atom form a heterocyclic ring]. For example, a compound wherein all of the R
1-3 are methyl, or a compound where in all of the R
1-3 are methyl, or a compound wherein R
1 is phenyl, R
2 is ethyl, and R
3 is H.
COPYRIGHT: (C)1979,JPO&Japio
摘要翻译：目的：一种对稻瘟病有效的农作物和园艺农药，水稻螟虫斑点，黄瓜白粉病等，无植物毒性，对人体，野兽和鱼类无害，含有特异性吡唑嘧啶衍生物作为有效成分。组成：含有式[R 1的吡唑基嘧啶衍生物的组合物是低级烷基，苯基; R2是烷基，环己基，苯基（其可以被低级烷基或卤素取代）; R3是H，烷基; R2和R3可以与相邻的N原子一起形成杂环]。例如，其中所有R1-3为甲基的化合物，或其中R1-3全部为甲基的化合物或其中R 1为苯基，R 2为乙基且R 3为H的化合物。

5. 发明专利

JPS6471843A NOVEL SUBSTITUTED BENZOIC ACID ANILIDE DERIVATIVE AND PLANT DISEASE INJURY CONTROLLING AGENT CONTAINING SAID DERIVATIVE AS ACTIVE INGREDIENT 失效
公开(公告)号：JPS6471843A
公开(公告)日：1989-03-16
申请号：JP22937187
申请日：1987-09-11
申请人： MEIJI SEIKA KAISHA
发明人： KURIHARA HIROSHI , SHIBAHARA MASASHI , NISHIHATA TAKESHI , IWATA MICHIAKI , MATSUMOTO KUNIOMI , IMAMURA KEIICHI , KONDO SHINICHI
IPC分类号： A01N37/22 , A01N37/24 , C07C67/00 , C07C231/00 , C07C233/65
摘要： NEW MATERIAL:A substituted benzoic acid anilide expressed by formula I [X is H, halogen or lower alkyl; Y is lower alkyl or nitro (excluding when X is H and Y is lower alkyl or 2-nitro); Z is H, lower alkyl, 1-13C alkoxyl or halogen benzyloxy]. EXAMPLE:3'-Isopropoxy-2-methyl-3-nitrobenzanilide. USE:Useful as plant disease injury controlling agent, e.g. capable of remarkably controlling rice neck rot, Bacterial leaf light, etc. PREPARATION:For example, as shown in the reaction formula, substituted benzoic acid expressed by formula II is reacted with a substituted anilide expressed by formula III in a solvent such as dimethylformamide, etc., at ambient temperature for 30min-48hr to provide the compound expressed by formula I.

6. 发明专利

JPS60190773A 1,5-benzoazepin derivative, its preparation and agent for combating plant diseases containing the same as an active ingredient 失效
标题翻译： 1,5-BENZOAZEPIN衍生物，其制备和用于将含有该成分的植物性疾病作为活性成分
公开(公告)号：JPS60190773A
公开(公告)日：1985-09-28
申请号：JP4531684
申请日：1984-03-09
申请人： Meiji Seika Kaisha Ltd
发明人： SAITOU TOSHINORI , NISHIHATA KEN , FUKATSU SHIYUNZOU , MATSUMOTO KUNIOMI , WATANABE TETSUO
IPC分类号： A01N43/72 , C07D281/10
摘要： NEW MATERIAL:A compound of formula I (R
1 is H, 1W5C alkyl, substituted or unsubstituted aryl, substituted or unsubstituted aralkyl; R
2 is H, 1W3C alkyl; R
3 is H, halogen, 1W3C alkyl; the above substituent is 1W3C alkyl, alkoxy, nitro, halogen).
EXAMPLE: 2-Isopropyl-2,3-dihydro-1,5-benzothiazepine-4(5H)-thione.
USE: An agent for combating plant diseases: it shows powerfully fungicidal effect against microorganisms causing plant disease, especially high fungicidal effect against rice blast. It is used by applying it directly to the crops which is desirably kept from diseases, or, when needed, scattering on the growing environment of the crops such as water or soil surface or by mixing it with the soil.
PREPARATION: For example, the raction of 1,5-benzoazepine derivative of formula II with phosphorus pentasulfide is carried out in a solvent such as pyridine at 20W115°C for 10minW24hr to give a compound of formula I .
COPYRIGHT: (C)1985,JPO&Japio
摘要翻译：新材料：式I化合物（R 1是H，1-5C烷基，取代或未取代的芳基，取代或未取代的芳烷基; R 2是H，1-3C烷基; R 3是H，卤素，1-3C烷基;上述取代基是1-3C烷基，烷氧基，硝基，卤素）。实施例：2-异丙基-2,3-二氢-1,5-苯并硫氮杂-4（5H） - 硫酮。用途：防治植物病害的药剂，对造成植物病害的微生物具有强大的杀真菌作用，特别是对稻瘟病的杀真菌效果。将其直接施用于希望从疾病中保存的作物，或者在需要时分散在诸如水或土壤表面的作物的生长环境上或通过与土壤混合的作物。制备例如，式Ⅱ的1,5-苯并吖庚因衍生物与五硫化二磷的反应在溶剂如吡啶中在20-115℃下进行10分钟-24小时，得到式I的化合物。

7. 发明专利

JPS63284104A PLANT BLIGHT CONTROLLER OF BENZOTHIAZOLE TYPE 失效
公开(公告)号：JPS63284104A
公开(公告)日：1988-11-21
申请号：JP11749587
申请日：1987-05-14
申请人： MEIJI SEIKA KAISHA
发明人： MIYAZAWA TAKEO , YASUFUKU KAZUE , NISHIHATA TAKESHI , IMAMURA KEIICHI , MATSUMOTO KUNIOMI , WATANABE TETSUO
IPC分类号： A01N43/78
摘要： PURPOSE:To obtain a safe plant blight controller having excellent blight controlling effects, comprising at least one benzothiazole derivative such as 2-[2'-(5'- methyl-1',3',4'-thiadiazolyl)thio]benzothiazole as an active ingredient. CONSTITUTION:A plant growth controller containing at least one benzothiazole derivative shown by formula I (R is 1-8C alkyl, cycloalkyl, aralkyl, aryl or heterocyclic; n is 0-2) as an active ingredient. The benzothiazole derivative has high fungicidal action and shows strongly controlling effects especially on blast of rice plant with a low concentration. The plant blight controller can be used alone and more effectively used together with an agricultural chemical such as another fungicide or insecticide and a fertilizer and aimed controlling operation can be attained with reduced labor. The compound shown by formula I such as a compound wherein n is 0 in the formula I is obtained by reacting a compound shown by formula II with a strong base and then with 2- chlorobenzothiazole.

8. 发明专利

JPS63152355A N'-(FLUOROPHENYL)BENZOHYDRAZIDE DERIVATIVE AND NON-MEDICAL MICROBICIDE 失效
公开(公告)号：JPS63152355A
公开(公告)日：1988-06-24
申请号：JP19275687
申请日：1987-08-03
申请人： MEIJI SEIKA KAISHA
发明人： NISHIMURA TAMIO , WATANABE TETSUO , MATSUMOTO KUNIOMI
IPC分类号： A01N37/28 , C07C67/00 , C07C241/00 , C07C243/38
摘要： NEW MATERIAL:The compound of formula I (X is halogen, nitro, lower alkanoylamino, lower alkyl or lower alkoxy; m is 0-2; n is 1 or 2; when m is 0, Fn is not F of 2-position). USE:A non-medical microbicide and fungicide. Useful as an agricultural and horticultural fungicide safely applicable without giving phytotoxicity to plants. It is useful in industrial field and environmental hygienic field, etc. PREPARATION:The compound of formula I can be produced by reacting fluorophenylhydrazine hydrochloride of formula II with benzoyl chlorides of formula III in anhydrous pyridine at room temperature or under heating.

9. 发明专利

JPS61254502A FUNGICIDAL COMPOSITION CONTAINING TRIIODOALLYL ALCOHOL 失效
公开(公告)号：JPS61254502A
公开(公告)日：1986-11-12
申请号：JP9375485
申请日：1985-05-02
申请人： MEIJI SEIKA KAISHA
发明人： SUNATSUKA KENSUKE , MATSUMOTO KUNIOMI , TOYAMA KATSUMI , KOBAYASHI TOSHIYUKI , WATANABE TETSUO , WATANABE TADAO
IPC分类号： C07C29/94 , A01N25/04 , A01N25/30 , A01N31/02 , A61K31/045 , A61P31/04 , C07C27/00 , C07C33/42 , C07C67/00
摘要： PURPOSE:To fungicide that is obtained by dispersing fine solid particles of 2,3,3,-triiodoallyl alcohol in an aqueous medium in the presence of an anionic surface active agent whereby the allyl alcohol is stabilized and the dispersibility in the aqueous medium is improved without coloring to increase fungicidal action. CONSTITUTION:Solid fine paraticles of 2,3,3-triiodoallyl alcohol are dispersed in an aqueous medium containing at least one selected from anionic surface active agents thereby the particles are stabilized. The content of the ally alcohol is 0.1-40wt%, preferably 1-25wt% and the size of the fine particles is less than 5mum, preferably 3mum on the average. The anionic surfactants are, e.g., alkyl sulfates and alkylbenzenesulfonates and the amount of the surfactant is 0.1-20wt%, preferably 1-10wt%.

10. 发明专利

JPS6183176A 1,4-thiazepine derivative, its preparation and plant disease-combating agent containing same as active ingredient 失效
标题翻译： 1,4-噻吩衍生物，其制备和植物病原体包含相同作用的活性成分
公开(公告)号：JPS6183176A
公开(公告)日：1986-04-26
申请号：JP20601584
申请日：1984-10-01
申请人： Meiji Seika Kaisha Ltd
发明人： NISHIHATA TAKESHI , SAITO TOSHINORI , YASUFUKU KAZUE , FUKATSU SHUNZO , MATSUMOTO KUNIOMI , WATANABE TETSUO
IPC分类号： A01N43/72 , C07D281/06
摘要： NEW MATERIAL:1,4-Thiazepin derivative of formula I (R
1 ,, R
2 are H, 1W5C alkyl, aryl which may be substituted, aralkyl which mat be substituted where the substituents are selected from 1W3C alkyl, 1W3C alkoxy, nitro and halogen).
EXAMPLE: 7-Isopropyl-tetrahydro-1,4-thiazepin.
USE: It is used to combat plant diseases. It has powerful fungicidal action, especially against rice blast.
PREPARATION: The compound of formula I is obtained by reacteion of 1,4- thazepin derivative of formula II with phosphorus pentasulfide or reaction between 1,4-thiazepin derivative of formula II and 2,4-bis(4-methoxyphenyl)-1,3- dithia-2,4-diphosphethane-2,4-disulfide.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新材料：式I的（R 1，R 2）的1,4-噻吩并
因衍生物是H，1-5C烷基，可被取代的芳基，其中取代基选自1- 3C烷基，1-3C烷氧基，硝基和卤素）。实例：7-异丙基 - 四氢-1,4-硫氮杂。用途：用于防治植物病害。它具有强大的杀真菌作用，特别是抗稻瘟病。制备：式Ⅰ化合物是通过将式Ⅱ的1,4-噻替in嗪衍生物与五硫化二磷或式Ⅱ的1,4-硫氮杂衍生物与2,4-双（4-甲氧基苯基） 3-二硫杂-2,4-二磷杂环戊烷-2,4-二硫化物。

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