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    • 2. 发明专利
    • Thin-film electrolytic sheet for solid oxide fuel battery
    • 用于固体氧化物燃料电池的薄膜电解质片
    • JP2014191944A
    • 2014-10-06
    • JP2013065400
    • 2013-03-27
    • Nippon Shokubai Co Ltd株式会社日本触媒
    • HATA KAZUO
    • H01M8/02C04B35/48H01B1/06H01M8/12
    • Y02E60/525
    • PROBLEM TO BE SOLVED: To provide a thin-film electrolytic sheet for a solid oxide fuel battery which enables the reduction in occurrence of fracture or crack when a thin-film electrolytic sheet is exposed to oxidative and reducing atmospheres repeatedly or exposed to an oxidative atmosphere abruptly as an electrolyte-support type cell, and which is uniform in thickness in a range of 50-180 μm, and has at least one hole in a sheet plane, and whose crystal structure is mainly of a cubic zirconia, and to provide a cell for a solid oxide fuel battery including such an electrolytic sheet.SOLUTION: An electrolytic sheet for a solid oxide fuel battery has at least one hole in a sheet plane. The electrolytic sheet is uniform in thickness in a range of 50-180 μm. The crystal structure of the sheet is mainly of a cubic zirconia. At least a part of a peripheral portion of the sheet is mainly of a tetragonal zirconia.
    • 要解决的问题:提供一种用于固体氧化物燃料电池的薄膜电解质片,当薄膜电解质片反复暴露于氧化性气氛中时,能够减少发生断裂或裂纹的现象 突然作为电解质支持型电池,其厚度均匀在50-180μm的范围内,并且在片材平面中具有至少一个孔,并且其晶体结构主要是立方氧化锆,并且提供 包括这种电解质片的固体氧化物燃料电池的电池。解决方案:用于固体氧化物燃料电池的电解片在片材平面中具有至少一个孔。 电解质片的厚度在50-180μm的范围内是均匀的。 片材的晶体结构主要是立方氧化锆。 片材的周边部分的至少一部分主要是四方晶氧化锆。
    • 3. 发明专利
    • Metal support type solid oxide fuel battery cell, and solid oxide fuel battery using the same
    • 金属支持型固体氧化物燃料电池和使用其的固体氧化物燃料电池
    • JP2013201038A
    • 2013-10-03
    • JP2012068798
    • 2012-03-26
    • Nippon Shokubai Co Ltd株式会社日本触媒
    • HATA KAZUO
    • H01M8/02H01M8/12
    • Y02E60/525
    • PROBLEM TO BE SOLVED: To provide a metal support type solid oxide fuel battery cell which is excellent in cell strength, has rigidity against torsion and deflection, and can keep the flatness, and a solid oxide fuel battery which hardly causes breakage of an electrolyte or an electrode when the cells are stacked.SOLUTION: The metal support type solid oxide fuel battery cell has, on a support (A) that is formed of a metal partition and has a honeycomb structure provided with a plurality of through-holes, in which the number of the through-holes is in a range of 25-2000/inchand a thickness (t) is 0.01-0.2 cm, a fuel electrode (B), a solid electrolyte (C) and an air electrode (D) arranged in the order of (B), (C) and (D).
    • 要解决的问题:提供一种电池强度优异的金属支撑型固体氧化物型燃料电池单元,具有抵抗扭转和挠曲的刚性并且能够保持平坦度,并且能够容易地导致电解液的破坏的固体氧化物燃料电池 电池堆叠时的电极。解决方案:金属支撑型固体氧化物燃料电池单元在由金属隔板形成的支撑体(A)上具有设置有多个通孔的蜂窝结构体,其中 通孔的数量为25-2000 /英寸,厚度(t)为0.01-0.2cm,燃料电极(B),固体电解质(C)和空气电极(D)布置在 (B),(C)和(D)的顺序。
    • 4. 发明专利
    • Method for manufacturing zirconia-based electrolytic sheet for fuel battery
    • 用于制造用于燃料电池的基于ZIRCONIA的电解质片的方法
    • JP2013140695A
    • 2013-07-18
    • JP2011290262
    • 2011-12-29
    • Nippon Shokubai Co Ltd株式会社日本触媒
    • HATA KAZUO
    • H01M8/02H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing a zirconia-based electrolytic sheet for a fuel battery suitable for reducing an undulation arising in the sheet with a low breakage rate.SOLUTION: The manufacturing method of the invention comprises (1) a process which includes the steps of: alternately laminating ceramic spacers and zirconia-based green sheets to prepare first laminates composed of the ceramic spacers and the green sheets; and then baking the green sheets in the first laminates at a predetermined temperature, and (2) a process which includes the steps of: laminating the baked zirconia-based sheets obtained in the baking step of the process (1) to prepare a second laminate having a peripheral edge portion for providing; and then baking the second laminate while applying a predetermined load to a portion of the second laminate at least partially including a peripheral edge of the second laminate so that a loaded area of the portion subjected to the load application is 5-50% of the sheet area. In the method, the number of the baked zirconia-based sheets forming the second laminate is 5-100.
    • 要解决的问题:提供一种用于制造用于燃料电池的氧化锆基电解质片的方法,所述电解质片适用于以低破损率减少片材中产生的波动。解决方案:本发明的制造方法包括(1) 其包括以下步骤:交替地层叠陶瓷间隔件和基于氧化锆的生片,以制备由陶瓷间隔件和生坯构成的第一层压体; 然后在预定温度下烘烤第一层压板中的生片,和(2)包括以下步骤的步骤:将在工艺(1)的烘烤步骤中获得的焙烧氧化锆基片层压,以制备第二层压体 具有用于提供的外围边缘部分; 然后在对第二层压体的至少部分地包括第二层压体的周边边缘的部分施加预定的载荷的同时烘烤第二层压体,使得经受负荷施加的部分的装载区域为片材的5-50% 区。 在该方法中,形成第二层压体的焙烧氧化锆类片的数量为5-100。
    • 5. 发明专利
    • Metal support type solid oxide fuel battery cell, and solid oxide fuel battery using the same
    • 金属支持型固体氧化物燃料电池和使用其的固体氧化物燃料电池
    • JP2013077450A
    • 2013-04-25
    • JP2011216668
    • 2011-09-30
    • Nippon Shokubai Co Ltd株式会社日本触媒
    • HATA KAZUO
    • H01M8/02H01M4/86H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a metal support type solid oxide fuel battery cell which is excellent in cell strength, has rigidity against torsion and deflection and a degree of freedom in deformation against compression, and is excellent in adhesion of a metal support and an electrode, and for which a fine electrolyte layer is manufactured by a simple manufacturing method, and a solid oxide fuel battery using such a cell further.SOLUTION: For the metal support type solid oxide fuel battery cell according to the present invention, on a support (A) comprising a metal partition and having a honeycomb structure provided with a plurality of through-holes, a fuel electrode (B), a solid electrolyte (C) and an air electrode (D) are arranged in the order of (B), (C) and (D). The number of through-holes of the support (A) is in the range of 25 to 2000/inch2, a height of the support is 100 to 2000 μm, a thickness of the metal partition is in the range of 10 to 1000 μm, and a porous layer is provided on at least one port of the through-holes of the support (A).
    • 要解决的问题:提供一种电池强度优异的金属支撑型固体氧化物燃料电池单元,具有抵抗扭转和挠曲的刚性和抗压缩变形的自由度,并且金属的附着性优异 支撑体和电极,并且通过简单的制造方法制造精细电解质层,以及使用这种电池的固体氧化物燃料电池。 解决方案:对于根据本发明的金属支撑型固体氧化物燃料电池,在包括金属隔板的支撑体(A)上,具有设置有多个通孔的蜂窝结构体,燃料电极(B ),固体电解质(C)和空气电极(D)按照(B),(C)和(D)的顺序排列。 支撑体(A)的通孔的数量在25〜2000 / inch2的范围内,支撑体的高度为100〜2000μm,金属隔板的厚度为10〜1000μm的范围, 并且在支撑体(A)的通孔的至少一个端口上设置多孔层。 版权所有(C)2013,JPO&INPIT
    • 7. 发明专利
    • Zirconia sheet
    • ZIRCONIA表格
    • JP2012087046A
    • 2012-05-10
    • JP2011271095
    • 2011-12-12
    • Nippon Shokubai Co Ltd株式会社日本触媒
    • HATA KAZUOAIKAWA NORIKAZUTAKASAKI KEIJIROSHIMOMURA MASATOSHINISHIKAWA YASUSHI
    • C04B35/48C04B35/64H01M8/02H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To establish a technique to firmly and in high adhesion join printed electrodes and the like with the surface of a zirconia sheet as an object on both surfaces of which printed electrodes and the like are applied like for solid electrolyte membranes.SOLUTION: The zirconia sheet composed of a sheet-like zirconia sintered compact is disclosed, wherein surface roughness of both surfaces of the sheet is 0.3-3 μm in maximum height (Ry) and is 0.02-0.3 μm in arithmetic mean roughness (Ra), and preferably the surface roughness ratio of a surface of one side of this sheet (a surface with the larger Ry and Ra) to a surface of the other side of this sheet (a surface with the smaller Ry and Ra) is 1-5 in terms of the maximum height ratio (Ry ratio) and 1-10 in terms of the arithmetic mean roughness ratio (Ra ratio). A production method for certainly obtaining a sheet with such a kind of surface property is also disclosed.
    • 要解决的问题:为了建立牢固且高粘合性的技术,将印刷电极等与作为对象的氧化锆片的表面一起施加印刷电极等,用于固体电解质 膜。 解决方案:公开了由片状氧化锆烧结体构成的氧化锆片,其中片材两面的表面粗糙度在最大高度(Ry)为0.3-3μm,算术平均粗糙度为0.02-0.3μm (Ra),优选该片的一面(具有较大的Ry和Ra的表面)与该片的另一侧的表面(具有较小的Ry和Ra的表面)的表面的表面粗糙度比为 1-5的最大高度比(Ry比),以算术平均粗糙度比(Ra比)计算为1-10。 还公开了一种确保获得具有这种表面性质的片材的制造方法。 版权所有(C)2012,JPO&INPIT
    • 8. 发明专利
    • Zirconia containing green sheet calcinating porous sheet for solid oxide fuel cell electrolyte and manufacturing method thereof
    • 包含绿板的ZIRCONIA固体氧化物电池电解质的多孔板及其制造方法
    • JP2012069369A
    • 2012-04-05
    • JP2010212969
    • 2010-09-24
    • Nippon Shokubai Co Ltd株式会社日本触媒
    • HATA KAZUO
    • H01M8/02C04B38/00C04B41/85H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a ceramic porous sheet having porous property which has sufficient strength to accept mechanization of a calcination preprocess and alleviate a peripheral part drooping phenomenon and can also sufficiently and evenly diffuse decomposed gas occurring at green sheet calcination time, and a method for manufacturing the same.SOLUTION: A ceramic porous sheet 3 is used as a spacer in a process where a zirconia green sheet 2 is calcined, the end faces of the ceramic porous sheet 3 having a lower porosity than at a middle part on the upper surface thereof. The porosity at end faces of the ceramic porous sheet 3 is 2% and over to and including 20% and that at a middle part on the upper surface thereof is 30% and over to and including 85%, by which strength is increased. Also, a manufacturing method for the ceramic porous sheet 3 involves immersing end faces of the ceramic porous sheet 3 having a porosity of 30% and over to and including 85% in a slurry, with a viscosity of 1 Pa-s and over to and including 20 Pa-s, which contains at least one kind selected from the group of alumina, zirconia, and mullite, before being dried and calcined.
    • 要解决的问题:提供一种具有多孔性能的陶瓷多孔质片,其具有足够的强度以接受煅烧预处理的机械化并减轻周边部分下垂现象,并且还可以充分均匀地扩散在生坯片煅烧时间产生的分解气体 及其制造方法。 解决方案:在氧化锆生片2被煅烧的过程中,使用陶瓷多孔片3作为间隔物,陶瓷多孔片3的孔隙率低于其上表面的中间部分的端面 。 陶瓷多孔片材3的端面的孔隙率为2%以上且20%以上,上表面的中间部分为30%以上且85%以上,强度提高。 此外,陶瓷多孔片材3的制造方法包括将具有30%以上孔隙率的陶瓷多孔片材3的端面浸入浆料中并且包含85%的粘度为1Pa·s的粘合剂的端面, 包括20Pa·s,其在干燥和煅烧之前含有选自氧化铝,氧化锆和莫来石中的至少一种。 版权所有(C)2012,JPO&INPIT
    • 10. 发明专利
    • Fuel electrode material for solid oxide fuel cell, and its manufacturing method
    • 用于固体氧化物燃料电池的燃料电极材料及其制造方法
    • JP2009140730A
    • 2009-06-25
    • JP2007315511
    • 2007-12-06
    • Nippon Shokubai Co Ltd株式会社日本触媒
    • HATA KAZUO
    • H01M4/88H01M8/02H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a material of a fuel electrode for a solid oxide fuel cell for carrying out a far higher power generating performance over a long period, a high-performance fuel electrode using the fuel electrode material, and a cell for the fuel cell. SOLUTION: This material for the solid oxide fuel cell is composed of nickel oxide powder of which the average particle diameter is 0.3 to 3 μm and the specific surface area is 0.1 to 1 m 2 /g and stabilized zirconia powder and/or dope ceria powder, or mixed nickel oxide powder composed of the nickel oxide powder and nickel oxide powder of which the average particle diameter is 0.3 to 3 μm and the specific surface area is 2 to 60 m 2 /g, and the stabilized zirconia powder and/or the dope ceria powder. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供用于固体氧化物燃料电池的燃料电极的材料,用于长期实现更高的发电性能,使用燃料电极材料的高性能燃料电极和 燃料电池单元。 解决方案:该固体氧化物燃料电池用材料由平均粒径为0.3〜3μm,比表面积为0.1〜1μm的氧化镍粉末构成, 稳定的氧化锆粉末和/或掺杂二氧化铈粉末,或由氧化镍粉末和氧化镍粉末组成的混合氧化镍粉末,其平均粒径为0.3〜3μm,比表面积为2〜60μm 2,稳定的氧化锆粉末和/或掺杂二氧化铈粉末。 版权所有(C)2009,JPO&INPIT